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2-Heptanone: Looking Closer at Its Safety and Handling

Identification

Chemical Name: 2-Heptanone
Other Names: Methyl n-amyl ketone, Heptan-2-one
CAS Number: 110-43-0
Physical Form: Clear, colorless liquid
Odor: Sharp, fruity, banana-like scent
Common Uses: Solvent in manufacturing, flavor and fragrance industry, extraction processes

Hazard Identification

Classification: Flammable liquid, irritant
Main Hazards: Vapors can form explosive mixtures with air, inhalation may irritate respiratory system, contact can cause eye and skin irritation, ingestion may harm central nervous system
Symptoms After Exposure: Dizziness, headache, nausea, skin redness, burning sensation in eyes

Composition / Information on Ingredients

Chemical Formula: C7H14O
Purity: Typically high for industrial applications
Ingredient: 2-Heptanone, no significant impurities noted in standard grades

First Aid Measures

Inhalation: Move person to fresh air, support breathing if symptoms like coughing or shortness of breath appear
Skin Contact: Wash affected area thoroughly with soap and water
Eye Contact: Rinse eyes gently with water for at least 15 minutes, remove contact lenses if present
Ingestion: Seek medical attention, rinse mouth with water if conscious, do not induce vomiting unless directed by healthcare professional

Fire-Fighting Measures

Suitable Extinguishing Methods: Carbon dioxide, foam, dry chemical powder
Special Hazards: Vapors heavier than air, can travel to ignition sources, combustion generates toxic gases including carbon monoxide
Advice For Firefighters: Wear self-contained breathing apparatus, use water spray to cool exposed containers, avoid inhalation of smoke or fumes

Accidental Release Measures

Personal Precautions: Evacuate area of unnecessary personnel, ventilate area, avoid breathing vapor
Environmental Precautions: Prevent spill from entering drains or waterways, contain spill with sand or earth
Methods For Cleanup: Use non-sparking tools to collect liquid, absorb with inert material, dispose of collected material according to legal requirements

Handling and Storage

Handling: Use only in areas with adequate ventilation, keep away from heat sources and flames, avoid contact with skin and eyes
Storage: Store in tightly closed containers in a cool, dry, well-ventilated place, keep away from incompatible materials such as oxidizing agents

Exposure Controls and Personal Protection

Occupational Limits: 50 ppm (ACGIH TWA)
Engineering Controls: Local exhaust ventilation to limit vapor buildup
Personal Protective Equipment: Chemical-resistant gloves, splash goggles, protective clothing for skin exposure, respirators in situations where exposure may exceed guidelines

Physical and Chemical Properties

Appearance: Clear, colorless liquid
Odor: Fruity, reminds some people of bananas
Boiling Point: Around 151°C
Melting Point: About -35°C
Flash Point: Approximately 41°C
Solubility: Slightly soluble in water, miscible with many organic solvents
Vapor Pressure: Around 3 mm Hg at 25°C
Density: About 0.81 g/cm³ at 20°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Incompatible Materials: Strong oxidizers, strong acids
Hazardous Reactions: May form explosive mixtures with air
Decomposition Products: Carbon monoxide, carbon dioxide, smoke if burned

Toxicological Information

Likely Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Effects: Respiratory irritation, headache, dizziness, skin and eye irritation
Chronic Effects: High or repeated doses have harmed nervous system and liver in lab animals
Additional Data: Not classified as a confirmed human carcinogen

Ecological Information

Aquatic Toxicity: Harmful to aquatic life in concentrated spills
Persistence and Degradability: Biodegrades in the presence of microbes
Bioaccumulation: Low potential for buildup in organisms
Other Details: Runoff from spills can enter waterways, putting fish and invertebrates at risk

Disposal Considerations

Waste Treatment Methods: Incinerate in approved facility or coordinate with hazardous waste disposal professionals
Avoid: Pouring down drains or mixing with ordinary trash
Empty Containers: Can contain residual vapors, rinse thoroughly before recycling or disposal

Transport Information

UN Proper Shipping Name: Heptanones
Hazard Class: 3 (Flammable Liquids)
Packing Group: III (for moderate hazard)
Environmental Hazards: Not a marine pollutant in small quantities, larger releases warrant spill response

Regulatory Information

OSHA Status: Listed among hazardous chemicals due to flammable and irritant properties
TSCA: Included on chemical inventory
SARA: Subject to reporting for certain releases under Emergency Planning and Community Right-to-Know Act
WHMIS Classification: B2 (Flammable), D2B (Toxic)