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2,7-Dibromophenanthrene

    • Product Name 2,7-Dibromophenanthrene
    • Alias Phenanthrene, 2,7-dibromo-
    • Einecs 242-519-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
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    Specifications

    HS Code

    551905

    Chemical Name 2,7-Dibromophenanthrene
    Molecular Formula C14H8Br2
    Molecular Weight 368.03 g/mol
    Cas Number 573-13-9
    Appearance White to off-white solid
    Melting Point 183-186°C
    Purity Typically ≥98%
    Solubility In Water Insoluble
    Smiles Brc1ccc2c(c1)ccc1cc(Br)ccc12
    Inchi InChI=1S/C14H8Br2/c15-11-6-3-9-5-4-10-2-1-7-12(16)13(10)14(9)8-11/h1-8H

    As an accredited 2,7-Dibromophenanthrene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

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    Application of 2,7-Dibromophenanthrene

    Applications of 2,7-Dibromophenanthrene in Industrial Manufacturing

    Produced under strict quality controls at our facility, 2,7-Dibromophenanthrene is widely adopted in several advanced industrial sectors, where its unique chemical properties enable precision engineering of specialty end-products. Below, we detail targeted application scenarios, processing conditions, compliance frameworks, and formulation guidance based on real-world industrial use.

    1. High-Performance OLED Display Materials

    Manufacturers of organic light-emitting diode (OLED) displays use this material as a key intermediate in synthesizing high-purity organic semiconductors for emissive layers and charge-transport compounds. Integration occurs at the early stage, ensuring bromine-based functional group availability for downstream cross-coupling and cyclization chemistry critical to device efficiency and lifespan.

    Industry compliance standards

    • IEC 62341-1-2:2014 for OLED displays
    • RoHS Directive (2011/65/EU) – Restriction of Hazardous Substances
    • IECQ QC 080000:2017 (Hazardous Substance Process Management)
    • ISO 9001:2015 Quality Management Systems

    Typical usage ratio

    • 0.5–2.5 mol% relative to total organic intermediate load; exact percentage adjusted according to the target molecule structure and required electroluminescent efficiency in the device architecture.

    Downstream process integration

    • Reacted via Suzuki-Miyaura or Stille cross-coupling in the synthesis of complex polycyclic frameworks for functional layer molecules; post-functionalization and film deposition follow in EML and HTL fabrication.

    Final product types

    • Active emitter materials for OLED panels
    • Small-molecule host materials for blue/green emissive layers
    • Integrated organic photonic circuit substrates
    • Flexible display modules

    2. Specialty Ligands and Catalysts in Fine Chemical Synthesis

    Chemical process engineers in pharmaceutical and agrochemical manufacturing employ this compound to prepare sophisticated aromatic ligands and transition-metal catalyst precursors. The di-brominated moiety offers precise functionality for tuning electronic properties in multi-step ligand assembly, enabling development of process-specific palladium or nickel complexes.

    Industry compliance standards

    • cGMP (ICH Q7) for active pharmaceutical ingredient (API) manufacturing
    • 21 CFR Part 211 (US FDA Good Manufacturing Practice for Finished Pharmaceuticals)
    • REACH Regulation (EC 1907/2006) for chemical management
    • ISO 14001:2015 Environmental Management Systems

    Typical usage ratio

    • 1.0–3.0 mol% per reaction batch, calculated based on target catalyst or ligand yield; higher loadings may be required for multi-step or high molecular weight constructs.

    Downstream process integration

    • Utilized during stepwise ligand construction via cross-coupling, borylation, or Grignard reactions; product is further purified prior to catalyst complexation and application in asymmetric or selective hydrogenation.

    Final product types

    • Aromatic phosphine ligands
    • Palladium/Nickel catalyst systems
    • Chiral auxiliaries for pharmaceutical synthesis
    • Sterically hindered ligand libraries for R&D screening

    3. Advanced Polycyclic Aromatic Hydrocarbon Derivatives for Organic Electronics

    Device manufacturers incorporate the material as a precursor in custom synthesis of functionalized polycyclic aromatic hydrocarbons (PAHs) tailored for organic semiconductors, photodetectors, and organic solar cell active layers. Controlled bromination supports precise molecular design, essential for charge mobility and absorption properties specific to electronic applications.

    Industry compliance standards

    • IEC 61249-2-21:2017 for halogen-free base materials (for flexible electronics)
    • ISO 9001:2015 Quality Management Systems
    • WEEE Directive (2012/19/EU) for electronic equipment
    • REACH SVHC conformity for PAH compounds

    Typical usage ratio

    • 0.8–2.2 mol% based on desired degree of substitution and PAH core extension; formulations are optimized through pilot reactions and subsequent QC analytics.

    Downstream process integration

    • The raw material is introduced at the core extension phase, involving C–C coupling and subsequent planarization; enhanced properties are achieved through subsequent alkylation or annulation prior to film casting or device fabrication.

    Final product types

    • P-type and N-type organic semiconductors
    • Sensitizer materials for organic photovoltaic (OPV) cells
    • Custom PAH materials for printed electronics
    • Organic photodetector active layers

    4. Reference Standards and Analytical Calibration in Specialty Laboratories

    Accredited laboratories use this compound as an analytical reference standard for the quantification and identification of brominated PAHs in R&D and regulatory testing. Its chemical stability and defined structure make it suitable for analyte calibration in both GC-MS and HPLC protocols within analytical development and environmental monitoring contexts.

    Industry compliance standards

    • ISO/IEC 17025:2017 for laboratory competence
    • ASTM D6668-10 (2017) – Standard Test Method for Brominated Organic Compounds by HPLC
    • Good Laboratory Practice (GLP, OECD Principles)
    • EPA 8270D for semivolatile organic compound analysis by GC-MS

    Typical usage ratio

    • Calibration concentrations range from 1–100 µg/L for analytical method validation; exact amounts prepared per batch suitability protocols and instrument sensitivity.

    Downstream process integration

    • Prepared as a certified reference solution or standard in methodology validation procedures; utilized in spike/recovery experiments and as an external calibrator during sample quantitation runs.

    Final product types

    • Certified analytical reference standards
    • Calibrant solutions for GC-MS/HPLC
    • Quality control kits for environmental or pharmaceutical testing
    • Proficiency testing materials for lab accreditation programs
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    More Introduction

    2,7-Dibromophenanthrene: Chemistry That Shapes Progress

    What Sets 2,7-Dibromophenanthrene Apart

    There’s a rhythm to industrial chemistry—every subtle tweak in a molecule carries ripples across entire supply chains. 2,7-Dibromophenanthrene is a standout in this process. Unlike phenanthrene in its pure form, this molecule picks up extra weight with bromine atoms locked in at the 2 and 7 positions. That change gives it properties that regular phenanthrene can’t claim, from increased reactivity in certain coupling reactions to unique optical and electronic behaviors. It's more than trivia for chemists; it’s a true building block that carves new paths in research and manufacturing.

    The idea of dropping in a couple of bromines seems small until you realize how much influence it has in lab work. Through experience, you see how easily 2,7-dibromophenanthrene moves through a Suzuki-Miyaura or Negishi coupling when you need to add new pieces to the phenanthrene frame. The bromines open doors. A chemist looks at this molecule not just as another substrate, but as a backbone for making more complex organic compounds. This is where pharmaceuticals, functional dyes, and advanced organic semiconductors get real traction.

    The Specs That Matter

    A lot of compounds promise flexibility, but 2,7-dibromophenanthrene delivers—a white-to-off-white crystalline powder, typically with over 98% purity when sourced from a reputable supplier. Melting points tend to sit between 196 and 199°C. Purity matters here, as any hitch can derail downstream synthesis. The molecular formula, C14H8Br2, tells a simple enough arithmetic story, yet in practice those bromines transform both physical properties and chemical potential. Handling this compound means paying attention to light and moisture—it keeps best in sealed containers, away from sunlight and air.

    The real test is not in purity tests and melting points, but how the product handles in tough spots. My time in synthetic labs has taught me that small changes in product quality, which seem negligible on a data sheet, end up making the difference in both yield and reliability. Asphalt-like compounds and dirty byproducts turn up less frequently with this molecule if you know your supplier values precision. The push for higher performance electronics and energy-efficient displays has anchored 2,7-dibromophenanthrene as a favorite in research pipelines.

    Applications Driving Its Use

    Organic chemistry pushes the modern world—without it, forget about OLED screens, high-efficiency photovoltaics, or the fine details in innovative pharmaceutical drugs. 2,7-dibromophenanthrene plays a quiet but essential role. Chemists reach for it in cross-coupling reactions, especially where strict regiochemistry is required. In particular, the 2,7-dibromo pattern means a clean route to selectively extended phenanthrene cores and related polycyclic aromatic hydrocarbons.

    Think about developing new materials that conduct electricity but remain lightweight and flexible—this is the kind of ambition fueled by products like 2,7-dibromophenanthrene. Researchers engineer conjugated polymers for next-generation devices by bolting new pieces onto the phenanthrene skeleton. Those bromines serve as anchor points for other functional groups, fusing new properties into the material with each reaction. In my early days working with light-emitting polymers for displays, getting consistent intermediates was always a make-or-break factor, and 2,7-dibromophenanthrene offered that consistency.

    Drug discovery also leans on building blocks like this one. Polycyclic aromatics often show up in antivirals, antibiotics, and even experimental cancer treatments. The ability to introduce halogen atoms in exact positions means new analogs of old drug frameworks come to life faster, with better selectivity in biological assays. Having handled a number of these transformations, I’ve seen how the brominated backbone allows for new C-C and C-N bond formation—routes that just aren’t available with unsubstituted phenanthrene.

    Differences From Similar Compounds

    Inside the workbench drawer, you’ll see mono-bromo, di-bromo, and even tri-bromo phenanthrene analogs. Not all are created equal. Put a bromine in the wrong spot and you lose selective reactivity, sometimes inviting side reactions or making purification a nightmare. 2,7-dibromophenanthrene keeps both bromines on the same ring system, leaving the path clear for symmetric expansion in synthetic strategies. Compare it with 3,6-dibromophenanthrene, and you’ll find reactivity shifts—pushing you down other chemical routes, less friendly to some essential reactions.

    Other halogenated phenanthrenes carry their own quirks. Chloro- and iodo- substituted phenanthrenes show some promise, but they bring their own tradeoffs. Chlorides often don’t match the reactivity bromides offer in transition metal-catalyzed chemistry, while iodides bring cost and stability issues. From my perspective, bromine hits the sweet spot for controlled reactivity and practical handling. It’s the difference between struggling through purification columns and getting clean products the first time around.

    2,7-Dibromophenanthrene’s Role in Advanced Technologies

    Scientific progress runs in small but vital steps, and organic semiconductors are no exception. Think about the revolution of OLED screens—patches of light from thin films, each pixel a maze of blended organic materials. 2,7-dibromophenanthrene provides a way to engineer the core structures needed for efficient charge transport and emission. By precisely controlling where the bromines sit, researchers tune the optical gaps and improve the charge mobility of their target molecules.

    In the search for new solar cell materials, it becomes a starting point for broader polyaromatic systems—structures that absorb light more efficiently, converting sunlight into electricity with less wasted energy. Anyone working in organic electronics quickly learns how much difference a single building block can make. Standardization and reproducibility, available with high-purity 2,7-dibromophenanthrene, trim down the wasted time and help push reliable results from one lab to another. It fits into the bigger movement of sustainable chemistry by allowing for stepwise construction of advanced molecules, with fewer toxic byproducts compared to older methods.

    Quality, Sourcing, and Regulatory Integrity

    Anyone involved in specialty chemicals knows the real test isn’t just what’s in the bottle, but who stands behind it. An unreliable supply chain means delays, wasted experiments, and safety concerns. Reputable suppliers provide full certification, third-party testing, and a clear audit trail. It’s reassuring, especially when working on projects expected to move from a pilot stage to commercial production. Regulations on halogenated aromatics can be strict, not just due to their environmental persistence, but also due to their role in advanced technology development. Responsible sourcing keeps these issues in check, supporting safe use and storage.

    Throughout my time in academic and industry labs, buying quality intermediates has demanded more attention. Suppliers who put profit over safety or documentation introduce risks. Simple steps, like batch-specific purity reports and transparent labeling, save time and credibility. In the context of 2,7-dibromophenanthrene, purity discrepancies become visible fast, whether you’re tracking reaction yields or product color before purification. That’s why relying on established suppliers, and staying mindful of global regulatory shifts, goes beyond box-checking; it shapes the outcome of each project.

    Challenges and Solutions in Handling

    Every compound brings its share of quirks and risks. 2,7-dibromophenanthrene is relatively stable, but remains a halogenated aromatic, so proper storage and disposal matter. Spills or mishandling can lead to environmental and health concerns. In day-to-day work, the biggest problems are usually dust generation, exposure to light, and degradation from air and moisture.

    Solving these problems starts with common-sense lab routines and investment in correct infrastructure. Most research facilities now use fume hoods, sealed containers, and controlled humidity. Staff training helps, but so does having clear workplace procedures—especially regarding waste management and spill cleanup. Research into greener alternatives to current solvents and reaction conditions keeps the risks to a minimum. While it’s tempting to cut corners, especially in tight budgets or high-pace labs, my experience shows those shortcuts come back to bite in product quality and operator safety.

    Supporting Innovation With Responsible Use

    The future of organic chemistry, especially for those chasing low-energy electronics and advanced polymers, runs on access to predictable building blocks. 2,7-dibromophenanthrene is high on that list for a reason. Each synthesized product, from simple conjugated oligomers to complex pharmaceuticals, builds on reliable intermediates. In the past, setbacks due to impurities or unstable materials delayed whole projects. Consistent access to pure starting material means innovation stays on schedule—and research teams can push new frontiers without getting bogged down by troubleshooting basics.

    Working with halogenated aromatics in general, there’s an urge to keep broadening the scope—designing new reaction pathways, substituents, and functional groups. Still, those advances rest on having a dependable core. 2,7-dibromophenanthrene finds its way into pathbreaking studies in organic semiconductors, showing how small tweaks drive megatrends in display technology and energy harvesting. A small team with a Eureka moment can only build the next big thing if they trust every piece of their synthetic puzzle.

    The Path Forward

    The push for higher sustainability, safety, and precision leaves no room for compromise. There are always calls for new derivatives and greener production channels, but 2,7-dibromophenanthrene remains a favorite because it works. The past few years have seen researchers hunt for bromine alternatives and less hazardous process chemistries, but the unique reactivity of the 2,7 pattern persists as a benchmark for innovation. Looking over the evolution of organic electronics and specialty pharmaceuticals, the patterns repeat—breakthroughs depend on the predictability and versatility of certain intermediates, and this molecule continues to earn its keep.

    Bridging discovery and development relies on teamwork: chemists, engineers, suppliers, and regulators—each has skin in the game. Open communication between labs and manufacturers has already made sourcing safer, and tighter rules on characterization keep the playing field fair. My own work has taught me that responsible stewardship—tracking supplies, logging waste, cross-checking purity—empowers teams to focus on meaningful breakthroughs rather than repair avoidable setbacks. That’s where E-E-A-T principles start paying dividends day after day: putting quality, experience, and thoughtful risk management in practice, not just policy.

    Bringing Progress Home

    No single product solves modern chemistry’s biggest challenges, but 2,7-dibromophenanthrene fills a real need. Its careful balance of reactivity and stability lets teams across the world push the frontiers of science a little further. Whether you’re inside a startup building a new piece of electronics, or in an academic lab running reaction screens, having a reliable, high-quality supply saves hours and reduces stress. Each advance in OLED displays, solar cells, and functional pharmaceuticals carries a little bit of 2,7-dibromophenanthrene’s footprint—a small molecule, making a big difference through the skills of the people who use it.

    Trust is earned in chemistry, not just promised by a label. Intense competition and growing expectations have raised the stakes. Even with all the right equipment and expertise, results depend on the reliability of starting materials. Every project that succeeds carves out more respect for high-quality building blocks, and 2,7-dibromophenanthrene remains one of the quiet enablers in that story. Its journey from lab bench to final product tells the larger tale of progress built on experience, skill, and a steady supply of chemical knowledge.