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1,3-Dibromo-5,5-Dimethylhydantoin

    • Product Name 1,3-Dibromo-5,5-Dimethylhydantoin
    • Alias DBDMH
    • Einecs 221-967-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    697060

    Name 1,3-Dibromo-5,5-Dimethylhydantoin
    Cas Number 77-48-5
    Molecular Formula C5H6Br2N2O2
    Molar Mass 285.93 g/mol
    Appearance White to off-white crystalline powder
    Melting Point 198-201 °C
    Solubility In Water Slightly soluble
    Density 2.26 g/cm³
    Chemical Structure BrN(C(=O)NC(C)(C)C(=O))Br
    Boiling Point Decomposes before boiling
    Storage Conditions Store in a cool, dry, well-ventilated area
    Uses Disinfectant, brominating agent, water treatment

    As an accredited 1,3-Dibromo-5,5-Dimethylhydantoin factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,3-Dibromo-5,5-Dimethylhydantoin is supplied in a 500g white HDPE bottle with a secure screw cap and hazard labeling.
    Shipping **Shipping Description:** 1,3-Dibromo-5,5-Dimethylhydantoin should be shipped in tightly sealed containers, protected from moisture and direct sunlight. It is classified as a hazardous material (oxidizer, UN 3085), requiring compliance with applicable transport regulations. Appropriate hazard labeling and documentation must accompany the package during ground or air transport to ensure safe, regulated delivery.
    Storage 1,3-Dibromo-5,5-dimethylhydantoin should be stored in a cool, dry, well-ventilated area, away from heat, sparks, open flame, and incompatible materials such as strong acids and bases. Keep the container tightly closed and protected from moisture. Store in a corrosive-resistant container with a resistant inner liner. Avoid direct sunlight and sources of ignition to prevent decomposition and hazardous fumes.
    Application of 1,3-Dibromo-5,5-Dimethylhydantoin

    Applications of 1,3-Dibromo-5,5-Dimethylhydantoin in Industrial Manufacturing

    1,3-Dibromo-5,5-Dimethylhydantoin (DBDMH) serves as a critical brominating and sanitizing agent across multiple industrial sectors. Its controlled release of active bromine and stability in diverse conditions make it a material of choice for manufacturers demanding effective disinfection, oxidation, and bromination in production workflows.

    1. Industrial Water Treatment and Recirculating Cooling Systems

    Operators in power plants, steelworks, petrochemical complexes, and district cooling installations incorporate DBDMH as an effective microbiocide and algicide. Its stable bromine release provides rapid control of Legionella, biofouling, and organic contamination, particularly where water quality varies or residual chlorine alone is insufficient. Companies depend on its low by-product profile and its effectiveness even in alkaline or high-temperature environments. Integration aligns with continuous water quality monitoring and automatic fed dosing control for compliance assurance.

    Industry compliance standards

    • US EPA NPDES Permit discharge requirements
    • EU Biocidal Products Regulation (BPR, Regulation (EU) 528/2012)
    • ASME PCC-1 water system cleanliness guidelines
    • GB/T 50050-2017 (China) for industrial recirculating water treatment

    Typical usage ratio

    • Recommended dosing: 2–10 ppm active bromine based on system water volume
    • Initial shock dosing may reach 20 ppm active bromine
    • Dosing adjusts with microbial load, organic contamination, and water flow rate

    Downstream process integration

    • Automated feeders introduce granules or tablets to circulating water reservoirs
    • Continuous online monitoring dictates real-time dosing adjustment
    • Integration with water pretreatment (filtration, demineralization) and downstream clarifiers

    Final product types

    • Treated cooling tower recirculating water
    • Microbiologically controlled process or chiller water
    • Legionella-controlled makeup water for air conditioning
    • Industrial process water with minimized biofilm risks

    2. Swimming Pool and Spa Disinfection

    Commercial aquatic centers, pool chemical blenders, and spa water maintenance operators use DBDMH for broad-spectrum, stable bromine-based sanitation. It reacts quickly with bacteria and organic matter, maintains disinfectant residuals even in elevated temperatures, and leaves low halogenated by-product content. Manufacturers rely on tablet or granular formulations to deliver consistent dosing in circulation systems or floating dispensers, supporting sustained swimmer protection and regulatory water quality testing.

    Industry compliance standards

    • NSF/ANSI Standard 50 equipment and chemicals for swimming pools
    • US CDC Model Aquatic Health Code (MAHC)
    • EN 15032 for swimming pool water chemicals in the EU
    • GB 9677-1988 (China) standard for pool water disinfectants

    Typical usage ratio

    • Recommended level: 2–6 ppm total bromine residual in pool or spa water
    • Shock treatment: up to 10 ppm, depending on organic loading
    • Adjustments made for bather load and temperature

    Downstream process integration

    • Direct tableting or granulation into pool disinfectant products
    • Compatibility with in-line or floating dosing systems
    • Integrated within standard pool water chemical test and balancing cycles

    Final product types

    • Bromine tablets and sticks for public and private pools
    • Spa and hot tub sanitizing granules
    • Automatic bromine feeder refills
    • Combined pH and halogen control pool chemical packs

    3. Food Industry Equipment and Process Water Sanitation

    Food processing plants employ hydantoin-based brominating agents in equipment, surface, and pipeline sanitization due to the compound’s rapid microbial kill and minimal taste or odor residue. Dosed in water-wash systems, DBDMH effectively reduces pathogens on food contact surfaces, conveyors, and bottling lines. Controlled dosing and strict compliance monitoring assure both hygiene and non-contamination of food products, aligning with HACCP-driven practices for international supply chains.

    Industry compliance standards

    • US FDA 21 CFR 173.315 for chemicals used in washing fruits and vegetables
    • USDA Food Safety and Inspection Service Sanitation SOPs
    • Global Food Safety Initiative (GFSI) manufacturing site requirements
    • ISO 22000 Food Safety Management Systems

    Typical usage ratio

    • Concentration: 10–30 ppm active bromine for sanitation rinse
    • Sporicidal treatments may use up to 50 ppm with subsequent potable water rinse
    • Precise dosing by automated dilution systems according to food contact type

    Downstream process integration

    • Direct dosing into CIP (clean-in-place) water cycles
    • Application in conveyer belt and equipment washdown protocols
    • Integration with real-time titration or colorimetric monitoring of residual bromine

    Final product types

    • Sanitized process water for produce washing
    • CIP-disinfected filling and packaging lines
    • Ready-to-eat salad and vegetable wash water
    • Assured safe ice production in food-grade facilities

    4. Pulp and Paper Industry Slimicide

    Pulp mills and papermakers introduce DBDMH as a broad-spectrum biocide targeting slime-forming bacteria and algae in white water circuits, stock chests, and machine wire sections. Its persistent, non-chlorinated action prevents microbial-induced process upsets, quality losses due to spots or holes, and unscheduled equipment downtime. Manufacturers benefit from dose control systems tuned to ensure maximum paper brightness and minimal biocide carryover into final product sheets or effluent streams.

    Industry compliance standards

    • CEPI (Confederation of European Paper Industries) chemical management guidelines
    • US EPA FIFRA requirements for industrial biocides
    • China GB 4806.8-2016 for food contact paper and board
    • ISO 9706 for permanence of paper in archives, requiring limited biocide residue

    Typical usage ratio

    • Dosing range: 5–15 ppm active bromine, based on mill white water volume
    • Short-term shock treatments up to 30 ppm, decreasing as system stabilizes
    • Adjustments per microbial count and pulp furnish type

    Downstream process integration

    • Addition to circulation water or wet-end chemical dosing stations
    • Dosage control linked to automated microbial monitoring
    • Compatibility with retention aids and sizing compounds in papermaking slurry

    Final product types

    • Bright white office/copy paper
    • Food packaging grades with controlled biocide residual
    • Specialty papers with high cleanliness requirements
    • Coated and uncoated magazine papers

    5. Bromination Intermediate in Fine Chemical Synthesis

    Industrial chemical synthesis plants use DBDMH as a selective brominating reagent for active hydrogen substitution on aromatic rings and heterocycles. The material serves as a controlled-release bromine source in APIs, agrochemicals, flame retardants, and photographic intermediates. Chemists prefer its solid-state handling, milder conditions, and high conversion yields over liquid bromine or Br2-containing mixtures, particularly when purity and stoichiometric accuracy are critical. Downstream quality testing validates freedom from side reactions and unreacted halogen residue in the finished compounds.

    Industry compliance standards

    • ISO 9001 Quality Management Certification
    • cGMP (current Good Manufacturing Practices) for pharma ingredients
    • REACH Registration, Evaluation, Authorization and Restriction of Chemicals (EU)
    • ICH Q7 guidelines for API manufacturing

    Typical usage ratio

    • Stoichiometric ratios from 1.0 to 1.5 equivalents based on target functional group
    • Adjustment by substrate reactivity and required bromination selectivity
    • Optimized to minimize over-bromination and by-product formation

    Downstream process integration

    • Charger addition to batch reactors under inert atmosphere
    • Controlled temperature and solvent systems for selectivity
    • Integrated filtration and neutralization for product purification

    Final product types

    • Brominated API intermediates
    • Bromine-containing agrochemical precursors
    • Specialty flame-retardant monomers
    • High-purity photographic chemicals
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    Certification & Compliance
    More Introduction

    Understanding 1,3-Dibromo-5,5-Dimethylhydantoin: A Straightforward Look

    A Reliable Choice in Water Treatment and Disinfection

    Chemical maintenance of water has become a focus across pool operators, industrial plants, and even municipal water services. Among a range of treatment solutions, 1,3-Dibromo-5,5-Dimethylhydantoin—often abbreviated as DBDMH—has carved out a role for itself. As someone who’s had experience with pool maintenance and worked beside operators in various commercial setups, I’ve seen firsthand what it means to find a sanitizer that delivers consistent results. In a crowded landscape of disinfectants, DBDMH doesn’t rely on novelty. Instead, it works with a sort of quiet dependability that end-users appreciate when safety and convenience both matter.

    Specifications and Key Features

    This compound, with a formula of C5H6Br2N2O2, stands apart through its solid, tablet, or granular form. The physical state may sound technical, but the meaning is clear—a user will likely scoop, pour, or add this product without dealing with messy liquids or unstable powders. Most batches come as tasteless, white or off-white solids, helping handlers avoid excessive dust or spillage, which I’ve found makes a big difference, especially in fast-paced environments.

    DBDMH’s melting point sits around 200°C, yet no one actually melts it on purpose. This stability tells us something important: it won’t degrade easily on the shelf or under most storage conditions. Manufacturers often standardize the bromine content. High bromine output is a given, often more than 50% by weight, giving it the punch needed for disinfection without requiring huge application volumes.

    How It Gets Used in the Real World

    The main calling card of DBDMH is water sanitation. I’ve watched municipal systems and Olympic-sized pools tackle the never-ending challenge of bacteria and algae. Chlorine-based disinfectants dominate the discussion, but DBDMH breaks into the conversation with its bromine base. In swimming pools and spas, DBDMH releases bromine steadily, especially when water stays warm or contaminants appear quickly. The release is measured, not explosive, letting facility managers keep closer tabs on sanitation. There’s no need for powered equipment to deliver a measured dose, just add tablets or granules into skimmers or floating dispensers and let normal circulation do the work.

    People who manage cooling towers and closed-loop systems look to DBDMH for another reason—biofilm control. Industrial cooling systems can become petri dishes for bacteria and slime, fouling heat exchangers and pipes. By providing reliable, on-the-go bromine dosing, DBDMH helps keep these systems on the right side of regulations and efficiency.

    What Sets DBDMH Apart from Other Disinfectants

    Years of working with small pool owners, plant engineers, and chemical suppliers have taught me a few things about practical decision-making. The simplest chemical doesn't always win out; reliability in use and minimal side effects often tip the balance.

    Traditional chlorine compounds like calcium hypochlorite or sodium hypochlorite have a long-standing presence. They deliver powerful sanitizing, but they bring issues—harsh odors, eye irritation, and the familiar faded swimsuit after a summer of swimming. DBDMH flips the script by producing bromine rather than chlorine, leading to a gentler experience for the skin and eyes. Bromine remains stable at higher temperatures, making it well-suited for spas, where chlorine can gas off too quickly, leaving users under-protected.

    Another difference crops up in terms of byproducts. Chlorinated systems, when mixed with organic matter, often form chloramines. These lead to that sharp, uncomfortable “pool smell” and can drive users away from indoor pools. DBDMH, releasing bromine, results in bromamines. While not altogether harmless, these compounds have less of an odor and typically irritate less.

    From an operations standpoint, DBDMH wins for ease of use and handling. It’s non-dusting and can be applied directly, saving time for staff and reducing the risk of spills or inhalation exposure. I’ve seen operators reach for DBDMH when they wanted a break from complicated mixing duties often associated with liquid bleach or chlorine tablets.

    Longevity and Storage

    Storage and shelf life are overlooked, but they matter. Let’s face it: a chemical that degrades easily becomes a logistical headache. DBDMH stores well in a dry, cool environment, resistant to casual moisture and heat. This means operators can stock up for the busy season without facing significant product loss. The packaging—usually tightly sealed HDPE drums or lined fiber containers—keeps moisture out and product integrity in.

    From my perspective, peace of mind springs from knowing sanitizing chemicals won’t surprise you with a sudden loss in strength or unexpected odors during storage. DBDMH just does its job quietly.

    Safety and Environmental Perspective

    Ask anyone who handles disinfectants about safety, and the stories come quickly. Burns, inhalation, and strange allergic reactions all surface. DBDMH does bring hazards to the table—there’s no such thing as a risk-free oxidizer. But its solid, tablet-based form reduces scatter and airborne dust, cutting down the most common workplace exposure routes.

    Running through environmental impact, DBDMH edges out some competitors. Bromine-based systems work at wider pH ranges, reducing the need for follow-up chemical adjustments. Plus, bromine dissipates more slowly in the open air, reducing the need for constant re-dosing in hot tubs and outdoor pools. Still, DBDMH breaks down eventually, and its waste stream requires thoughtful handling. Local regulations may restrict discharge, recognizing that while bromine is less troubling than some persistent chlorinated compounds, it still forms organobromine residues that stick around longer than water managers would like.

    I haven’t seen a disinfectant yet that lets people turn a blind eye to runoff or accidental spills. Best practice usually means collecting rinse waters, bunding chemical stores, and updating staff on appropriate PPE and first aid, all of which minimize risk. DBDMH falls into that broad category of “handle with respect, and it works well.”

    Efficiency in Application

    An overlooked difference in DBDMH comes from its efficiency. Users generally find that a steady dose does the job, reducing wild swings in sanitation levels. While hyperchlorination works quickly, it also vanishes faster, forcing frequent top-ups. DBDMH settles into a routine, delivering long-lasting dosing especially noticeable in stagnant or slow-circulation water. In systems prone to heavy contamination, I’ve seen operators rely on DBDMH to maintain compliance even at times of peak load, such as event-based pool use or during the arrival of warmer weather.

    Cost Factors and Accessibility

    Along with safety and performance, cost matters. While DBDMH carries a higher upfront price than standard chlorine, users often find value over time in reduced consumption and fewer corrective treatments. Bromine is not dirt-cheap, but its benefits—including less downtime for pH balancing and fewer chemical reactions with pool accessories—often save money down the line. Bulk suppliers and catalogue vendors keep DBDMH on their lists, providing access for both small-scale and large-scale buyers.

    Small facilities, such as independent health spas and community recreation centers, like the predictability DBDMH brings. There’s a learning curve up front, but staff turnover becomes less of a worry when the sanitizer process takes fewer steps and generates fewer complaints.

    An Operator’s Viewpoint

    From a boots-on-the-ground perspective, DBDMH’s use in recreational and industrial water speaks to a certain pragmatism. Many facility operators just want a product that plays well with standard dosing equipment and doesn’t force them into buying specialty gear. Direct addition into skimmers or automated feeders lets staff focus on other maintenance tasks.

    I've seen facilities transition to DBDMH after frustrations with inconsistent chlorine results, especially in pools subject to variable attendance. Keeping free bromine levels steady meant fewer headaches during audits and customer feedback sessions. DBDMH also stands up to tough organic loads without much help from stabilizers or constant monitoring of cyanuric acid levels that chlorine-based products demand.

    I’ve noticed a knock-on effect: fewer customer complaints about red eyes or chemical smells, and less fading of poolside materials. This ripple effect extends to the back office, where reduced claims, less chemical wastage, and less overtime for after-hours remediation build a stronger business case for making the switch.

    Technical Challenges and How People Work Around Them

    No product comes without its quirks. DBDMH can interact with ammonia and certain metals, impacting both water quality and infrastructure. Monitoring still matters, even with a reliable compound in play. Some operators install additional water-quality sensors or run regular spot tests, building DBDMH dosing into a larger cycle of checks and balances. Long-term, that diligence pays off, with less scale buildup and fewer unexpected maintenance breakdowns.

    One issue I’ve noticed is with automated chemical feeders not always calibrated for DBDMH’s particular dissolution rate. Tweaks are part of the process. Some systems need plate upgrades or adjusted circulation speeds to get the most consistent output.

    Facility managers report that, once those kinks work out, DBDMH performs without daily troubleshooting. It reduces “problem weekends” where pool clarity vanishes or microbial counts spike right before a scheduled opening.

    Alternatives, and Why DBDMH Holds Its Own

    It’s easy to get caught up in the debate between bromine and chlorine. Both have roots going back a century or more in public health, with fine-tuned chemistries for targeted use. What DBDMH offers is a middle ground for those who feel chlorine dominates but leaves too many headaches.

    People ask about ozone, UV, and other non-chemical sanitation solutions. Those work—up to a point. Ozone and UV target pathogens on contact, but have no residual to keep microbes at bay between treatments. DBDMH provides that ongoing protection, suitable for systems where exacting cleanliness is a daily concern. Plus, it operates in a wider range of water qualities, so river water, hard municipal mixes, and even well water fall within its reach.

    Saltwater pools come up in comparison. These setups use electrolysis to generate chlorine on-site. While convenient, they introduce new hardware requirements and operational quirks, including salt corrosion on metal fixtures and pH spiking after every cycle. DBDMH persists without altering water composition as drastically or demanding expensive retrofits.

    Potential Improvements and Solutions for Existing Hurdles

    DBDMH enjoys a strong track record. Yet, there’s always room for progress. Improving dissolution rates and compatibility with next-generation dosing equipment has become a focus. Suppliers now look for coatings or granule sizes that minimize clumping and extend storage life even during humid summer months. For users, education is key. Proper handling, clear labeling, and sensible storage routines can head off most potential accidents.

    Updating operators with short training modules on bromine-specific strategies, including test kit calibration and dose-response times, supports safer, smoother transitions. Packaging advances, such as child-resistant caps and tamper seals, address ongoing worries about accidental exposure. Upstream solutions—such as automation technologies that sense and adjust chemical levels—could partner with DBDMH to create safer, leaner operations, minimizing overkills and conserving resources.

    Waste disposal still matters. I’ve spoken with water managers who collaborate with local environmental agencies to monitor outflows, treating spent water before discharge. This sort of partnership showcases a responsible approach, balancing the tools of chemistry with shared environmental stewardship.

    Why DBDMH Continues to Matter

    As public and private spaces demand safer, cleaner water, practical solutions remain vital. DBDMH offers a balance between robust chemical performance and user comfort. Its advantages—stable storage, broad-spectrum efficacy, and ease of integration—explain its growing footprint. In a sector often slow to change, this compound’s steady, unassuming presence helps facilities run efficiently, keep users safe, and meet the scrutiny of both regulatory agencies and an increasingly informed public.

    Those of us who have walked the decks of busy pool facilities, or who have worked alongside maintenance teams during the pressure of seasonal high use, recognize that a dependable disinfectant saves time, money, and frustration. DBDMH earns its keep not through flash or hype but by quietly delivering on each of those promises. For this reason, it’s become more than just another bottle on the chemical shelf—it’s a practical ally in the ongoing quest for clean, healthy, and responsive water care.