Wusu, Tacheng Prefecture, Xinjiang, China admin@sinochem-nanjing.com 3389378665@qq.com
Follow us:



MSDS for Vinyl Bromide (Stabilized)

Identification

Product Name: Vinyl Bromide (Stabilized)
Synonyms: Bromoethylene, Bromoethene
Recommended Use: Used in chemical manufacturing and research applications
Manufacturer Information: Contact manufacturer for full address and emergency phone line
Emergency Phone Number: Refer to country-specific chemical emergency network
CAS Number: 593-60-2
UN Number: 1301
Chemical Formula: C2H3Br
Molecular Weight: 106.95 g/mol

Hazard Identification

GHS Classification: Flammable gases, Category 1; Carcinogenicity, Category 2; Acute toxicity (Inhalation), Category 3
Signal Word: Danger
Hazard Statements: Extremely flammable gas; Suspected of causing cancer; Toxic if inhaled
Pictograms: Flame, Health hazard, Skull and crossbones
Routes of Exposure: Inhalation, skin contact, eye contact
Potential Health Effects: Respiratory tract irritation, dizziness, headache, central nervous system depression, risk of cancer with prolonged exposure
Other Hazards: May form explosive mixtures with air; can displace oxygen in confined spaces

Composition / Information on Ingredients

Chemical Name: Vinyl Bromide
Concentration: ≥99%
Stabilizer: Trace levels of chemical stabilizer (contact manufacturer for details)
Impurities: No hazardous impurities above threshold levels disclosed
CAS Number: 593-60-2
EC Number: 209-799-6

First Aid Measures

Inhalation: Move affected person to fresh air, keep warm and at rest, provide medical attention if symptoms persist or breathing is difficult
Skin Contact: Remove contaminated clothing, wash skin with plenty of soap and water, seek medical help if irritation develops
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if easy to do, continue rinsing, obtain medical attention
Ingestion: Unlikely route of exposure, do not induce vomiting, seek medical help
Most Important Symptoms/Effects: Shortness of breath, coughing, dizziness, drowsiness, unconsciousness, cancer risk after repeated exposure
Immediate Medical Attention: Provide oxygen if breathing is difficult, perform artificial respiration as needed, get medical aid for all significant exposures

Fire-Fighting Measures

Suitable Extinguishing Media: Use dry chemical, CO2, or alcohol-resistant foam; water spray for cooling exposed containers only
Unsuitable Extinguishing Media: Do not use water jet directly on fire
Specific Hazards Arising: Highly flammable gas, forms explosive mixtures with air, may produce toxic and corrosive gases (HBr, CO)
Protective Equipment: Wear self-contained breathing apparatus and full protective clothing
Special Procedures: Evacuate area, fight fire from safe distance, stop leak if safe
Explosion Data: Vapors heavier than air, may travel long distances to ignition sources, flashback possible

Accidental Release Measures

Personal Precautions: Evacuate personnel, eliminate ignition sources, ventilate area, wear appropriate PPE including respiratory protection
Environmental Precautions: Prevent release into soil, drains, waterways, or sewers; notify authorities
Methods for Cleaning Up: Stop gas flow if it can be done safely, ventilate area, use explosion-proof equipment, do not touch or walk through spilled material
Other Information: Isolate hazard area and keep unauthorized personnel away, monitor oxygen levels in confined spaces

Handling and Storage

Handling: Use only in explosion-proof fume hoods or approved systems, ground/bond containers and equipment, avoid inhalation, contact with skin and eyes, refrain from smoking near storage or handling areas
Storage: Store in cool, well-ventilated, secure facility, keep away from heat, sparks, open flames and incompatible materials; use pressure-resistant containers with proper labeling
Incompatibilities: Strong oxidizers, peroxides, acids, alkali metals
Other Precautions: Check container integrity regularly, keep containers tightly closed when not in use, install gas detection and alarm systems where stored

Exposure Controls and Personal Protection

Occupational Exposure Limits: ACGIH TLV: 0.1 ppm (TWA); OSHA PEL: 0.1 ppm, confirmed animal carcinogen
Engineering Controls: Provide local exhaust ventilation, ensure explosion-proof electrical equipment, monitor airborne levels regularly
Respiratory Protection: Use supplied air or self-contained breathing apparatus in case of inadequate ventilation or high exposure
Hand Protection: Wear chemical-resistant gloves (butyl rubber or nitrile recommended)
Eye Protection: Use chemical safety goggles or face shield
Skin Protection: Use flame-resistant, chemical-protective clothing
Hygiene Measures: Wash hands thoroughly after handling, remove contaminated clothing and wash before reuse, avoid eating or drinking in work areas

Physical and Chemical Properties

Physical State: Gas (liquefied under pressure)
Appearance: Colorless
Odor: Sweet, chloroform-like
Odor Threshold: 180 ppm
Boiling Point: 15.8°C (60.4°F)
Melting Point: -138°C (-216.4°F)
Evaporation Rate: Rapid
Flammability: Extremely flammable gas
Upper/Lower Flammability Limit: 9.6% (upper), 6.0% (lower, v/v in air)
Vapor Pressure: ~2100 hPa @ 20°C (liquid)
Vapor Density: ~3.7 (air = 1)
Relative Density: 1.53 (water = 1) as liquid
Solubility: Slightly soluble in water, soluble in organic solvents
Partition Coefficient (log Kow): 1.5
Auto-Ignition Temperature: 510°C (950°F)
Decomposition Temperature: Not specified
Viscosity: Not applicable

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions with stabilizer
Possibility of Hazardous Reactions: Polymerizes violently without inhibitor, may form peroxides, reacts with strong oxidizing agents
Conditions to Avoid: Heat, flames, sparks, static discharge, direct sunlight
Incompatible Materials: Strong oxidizers, acids, alkali metals, peroxides
Hazardous Decomposition Products: Hydrogen bromide, carbon monoxide, carbon dioxide
Other Reactivity Notes: May attack plastics, rubber, and coatings

Toxicological Information

Acute Toxicity: Median lethal concentration (LC50) rat (inhalation): 4600 ppm/4h
Chronic Toxicity: Suspected carcinogen, evidence of tumors in animal studies
Skin/Sensitization: Not known to cause sensitization
Eye Damage/Irritation: Causes eye irritation
Respiratory/Skin Sensitization: Not classified as sensitizer
STOT (Specific Target Organ Toxicity): May cause damage to organs with repeated exposure (lungs, liver, central nervous system)
Genotoxicity: Positive in some in vitro tests
Symptoms of Overexposure: Nausea, dizziness, headache, weakness, respiratory distress, unconsciousness at high levels, carcinogenic risk through chronic exposure

Ecological Information

Ecotoxicity: Toxic to aquatic organisms and can cause long-term effects in the environment
Persistence and Degradability: Low-to-moderate persistence; degrades under photolysis in air
Bioaccumulative Potential: Has moderate potential to bioaccumulate
Mobility in Soil: Likely to volatilize from soil surfaces, low soil adsorption
Other Adverse Effects: Ozone-forming potential under photochemical conditions
Precautions: Prevent large releases to soil and water

Disposal Considerations

Waste Treatment Methods: Burn in a chemical incinerator equipped with afterburner and scrubber, in compliance with local, state, and federal regulations
Unused Product: Return to supplier or authorized hazardous waste handler
Contaminated Packaging: Empty containers under controlled conditions; do not reuse packaging for other substances
Precautions: Avoid contact with reactive agents; ensure complete destruction before disposal, never discard in regular trash or sewers
Regulations: Dispose of product and packaging in accordance with applicable environmental and safety regulations

Transport Information

UN Number: 1301
UN Proper Shipping Name: Vinyl Bromide, stabilized
Class: 2.1 (Flammable Gas)
Packing Group: Not assigned for gases
Environmental Hazards: Marine pollutant
Special Precautions: Secure all cylinders, label containers clearly, ship under chemical gas regulations with emergency response guide
Regulatory Agency: DOT, IMDG, IATA all classify as regulated hazardous material
Transport Label: Flammable Gas

Regulatory Information

OSHA Classification: Regulated carcinogen, hazardous chemical
TSCA Status: Listed on Toxic Substances Control Act Inventory
SARA Title III: Immediate (acute) and delayed (chronic) health hazard, fire hazard
CERCLA Reportable Quantity: Listed substance, subject to release reporting at specified thresholds
Proposition 65 (California): Listed chemical known to cause cancer
REACH Status: Registered and regulated in the European Union
Other National/Regional Regulations: Specific restrictions and recordkeeping in many jurisdictions, subject to additional local handling, reporting, and exposure control requirements