Wusu, Tacheng Prefecture, Xinjiang, China admin@sinochem-nanjing.com 3389378665@qq.com
Follow us:



Material Safety Data Sheet: Triethyltin Acetate

Identification

Product Name: Triethyltin Acetate
Chemical Formula: C8H18OSn
CAS Number: 595-06-8
Recommended Use: Laboratory research and chemical synthesis
Manufacturer: Chemical supplier information as specified on product label
Emergency Contact: Emergency response hotline listed on the shipment label
Synonyms: Acetic acid, triethyltin ester
Contact for Information: Product regulatory affairs department as listed

Hazard Identification

GHS Classification: Acute Toxicity (Inhalation and Oral Category 2), Skin Corrosion/Irritation Category 2, Eye Damage Category 1, Reproductive Toxicity Category 1B, Environmental Hazard (Acute Aquatic Toxicity, Chronic Aquatic Toxicity Category 1)
Pictograms: Skull and crossbones, Corrosive, Environment
Signal Word: Danger
Hazard Statements: Highly toxic if inhaled or swallowed, causes severe skin burns and eye damage, very toxic to aquatic life with long lasting effects, may damage fertility or the unborn child
Precautionary Statements: Wear suitable protective equipment, do not eat or drink when using, avoid release to the environment, wash exposed skin thoroughly after handling, obtain special instructions before use
Routes of Entry: Inhalation, ingestion, skin absorption, eye contact
Target Organs: Central nervous system, kidneys, liver, reproductive organs

Composition / Information on Ingredients

Substance: Triethyltin Acetate
Concentration: 98–100% (as supplied)
Chemical Identity: Triethyltin Acetate (C8H18OSn)
EC Number: 209-870-2
Impurities: Contains trace amounts of related organotin compounds which may contribute to similar hazard profiles
Molecular Weight: 263.95 g/mol

First Aid Measures

Inhalation: Move victim to fresh air immediately. Provide artificial respiration if breathing has stopped. Call emergency medical services. Oxygen may be given if difficulty in breathing.
Skin Contact: Remove contaminated clothing. Rinse skin with copious running water for 15 minutes. Seek medical advice. Remove chemical from skin thoroughly.
Eye Contact: Flush eyes with gently flowing water for at least 15 minutes, lifting eyelids. Remove contact lenses if present and easy to do. Get urgent medical attention.
Ingestion: Rinse mouth with water, do not induce vomiting. Keep victim calm and call poison control center or physician at once. Give nothing by mouth to an unconscious person.
Symptoms/Effects, Acute and Delayed: Severe irritation or burns to eyes, nose, throat, and skin; headaches, dizziness, nausea, convulsions, potential loss of consciousness.

Fire-Fighting Measures

Suitable Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Water spray only to cool fire-exposed containers.
Specific Hazards: Tin fumes, carbon monoxide, carbon dioxide, and organic vapors develop under combustion. Fire may produce irritating, corrosive vapors.
Protective Equipment: Firefighters should use self-contained breathing apparatus and full protective gear. Remove sources of ignition and prevent contamination runoff entering drains.
Advice for Firefighters: Fight fire from safe distance or a protected location. Use water spray for cooling, avoid direct contact with released material.

Accidental Release Measures

Personal Precautions: Isolate spill area and restrict access. Wear appropriate gloves, face protection, and chemical resistant clothing.
Environmental Precautions: Prevent releases to surface water or drainage systems, avoid soil contamination, alert local environmental authority if spill is significant.
Containment/Cleanup: Cover spill with inert absorbent (sand or vermiculite). Scoop up material, place in non-metal container for disposal. Ventilate area. Wash spill area after collection.
Disposal of Clean-Up Materials: Handle all materials according to local hazardous waste protocols.

Handling and Storage

Handling: Operate in well-ventilated fume hood. Minimize skin and eye contact. Avoid inhaling dust, vapors, or mist. Keep away from sources of ignition, heat, and incompatible materials.
Storage: Store in tightly sealed containers in a cool, dry, well-ventilated area. Keep away from light. Protect from physical damage and segregate from oxidizing or acidic materials.
Incompatible Materials: Strong oxidizers, acids, alkalis, moisture, chlorinating agents.
Hygiene Measures: Wash hands after handling and before eating or drinking. Change contaminated clothing. No food or beverages in work area.

Exposure Controls and Personal Protection

Engineering Controls: Use chemical fume hood or exhaust ventilation. Local exhaust at points of emission.
Exposure Limits: Triethyltin compounds: ACGIH TLV-TWA 0.1 mg(Sn)/m³, OSHA PEL 0.1 mg/m³ (as tin).
Personal Protective Equipment: NIOSH-approved respirator if exposure likely, chemical splash goggles or face shield, butyl rubber or nitrile gloves, lab coat with closed sleeves, chemical-resistant apron.
Work Practices: Implement eyewash stations and safety showers in areas of use. Prohibit eating, drinking, smoking during use.

Physical and Chemical Properties

Appearance: Colorless or slightly yellow liquid, faint characteristic odor
Boiling Point: 177–180°C at 760 mmHg
Melting Point: Below room temperature
Flash Point: 65–70°C (closed cup)
Vapor Pressure: 0.1 mmHg at 20°C
Solubility: Insoluble in water, miscible with organic solvents (e.g. ether, acetone, benzene)
Density: ~1.36 g/cm³ at 20°C
pH: Not applicable (non-aqueous)
Partition Coefficient (log Kow): Estimated 2.1–3
Auto-Ignition Temperature: Not measured

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions, but reacts with strong oxidizing agents and acids.
Reactivity: May decompose under prolonged exposure to moisture and UV light, generating flammable, corrosive vapors.
Hazardous Reactions: Contact with acids liberates toxic gases. Builds pressure if container is sealed and heated.
Decomposition Products: Ethyl tin compounds, acetic acid, carbon oxides, tin oxides.
Conditions to Avoid: Heat, flames, sparks, static discharge, moisture, direct sunlight.

Toxicological Information

Acute Toxicity: Oral LD50 (rat): 16 mg/kg. Generates severe systemic toxicity in low doses. Inhaled vapor or dust triggers high toxicity with possible fatal outcomes.
Skin Corrosion/Irritation: Causes burns and tissue destruction with direct contact.
Eye Damage/Irritation: Severe, persistent eye injury with possible permanent damage.
Respiratory Sensitization: Inhalation produces respiratory tract burns, coughing, and difficulty breathing.
Chronic Toxicity: Neurological symptoms (tremors, confusion, ataxia), potential reproductive or developmental effects, kidney and liver impairment seen in animal studies.
Carcinogenicity: No strong human evidence, but related organotin compounds show tumorigenic effects in rodent studies.
Mutagenicity and Teratogenicity: Evidence for genetic damage and developmental toxicity from laboratory tests.
Target Organs: Nervous system, liver, kidneys, reproductive system.

Ecological Information

Aquatic Toxicity: Highly toxic to aquatic life (EC50 for Daphnia magna: 0.01–0.1 mg/L). Persistent in the environment with risk of bioaccumulation.
Persistence and Degradability: Not readily biodegradable, toxic breakdown products linger in soil and sediment for extended periods.
Bioaccumulative Potential: Strong tendency to accumulate in food chains, raising environmental risk.
Mobility in Soil: Low to moderate mobility depending on soil composition, but poses long-term risks to groundwater and surrounding systems.
Other Adverse Effects: Disrupts aquatic invertebrates and algae, impacts fish health and development, potentially toxic to birds and mammals consuming contaminated food.

Disposal Considerations

Waste Disposal Methods: Collect and store excess material or contaminated absorbents in labeled hazardous waste drums. Dispose through licensed hazardous waste contractor following local, state, and federal regulations.
Contaminated Packaging: Triple rinse or puncture, then dispose as hazardous waste. Do not reuse empty containers.
Precautions: Do not allow material to enter natural waterways. Avoid discharge to sewer or municipal waste streams.
Regulations for Disposal: Reference EPA Resource Conservation and Recovery Act (RCRA), European Waste Catalogue (EWC) codes for organotin waste.

Transport Information

UN Number: UN2788
Shipping Name: Organotin Compound, Liquid, N.O.S. (Triethyltin Acetate)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: I (high danger)
Marine Pollutant: Yes
Transport Labels: Poison, Environmentally hazardous
Special Precautions for Transport: Protect from heat, sources of ignition. Ship in tightly closed containers, secondary containment recommended.
Regulatory Provisions: Comply with international agreements (ADR/RID, IMDG, IATA/ICAO).

Regulatory Information

US Regulations: TSCA (Toxic Substances Control Act) listed; SARA Title III Section 313 reportable; CWA hazardous substance.
Europe: REACH (EC 1907/2006) registered substance; subject to restrictions on use in biocidal products or water treatment.
Other International: Listed under PIC (Prior Informed Consent) for export restrictions, included in priority pollutant schedules.
Other Obligations: Requires hazard communication as per OSHA, WHMIS, and GHS. Emergency planning and risk management measures required for quantities above threshold limits.