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MSDS for Tetrapotassium Pentacyanoaurate

Identification

Product Name: Tetrapotassium Pentacyanoaurate
Chemical Formula: K4[Au(CN)5]
Synonyms: Gold pentacyanide potassium salt
Supplier: Laboratory chemical supplier details
Recommended Use: Laboratory reagent, industrial synthesis
Contact Information: Emergency phone number, address of supplier

Hazard Identification

GHS Classification: Acute Toxicity – Oral (Category 2), Skin Irritation (Category 2), Eye Irritation (Category 2A)
Signal Word: Danger
Hazard Statements: Highly toxic if swallowed, skin irritant, causes serious eye irritation, toxic to aquatic organisms
Precautionary Statements: Do not breathe dust, avoid contact with skin and eyes, wash thoroughly after handling, use only outdoors or in well-ventilated areas, wear suitable protective equipment

Composition / Information on Ingredients

Chemical Name: Tetrapotassium Pentacyanoaurate
CAS Number: 13967-50-5
EC Number: 237-748-0
Percent Composition: 100%
Impurities: No hazardous impurities above disclosure limits

First Aid Measures

Inhalation: Move to fresh air, seek immediate medical advice if respiratory symptoms develop
Skin Contact: Remove contaminated clothing, flush skin with running water for 15 minutes, seek medical attention for irritation
Eye Contact: Rinse eyes cautiously with water for several minutes, remove contact lenses if present, ensure medical evaluation
Ingestion: Do not induce vomiting, rinse mouth, seek urgent medical attention immediately

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, foam, carbon dioxide, do not use water jets
Specific Hazards: Cyanide fumes may form, gold compounds can decompose under fire conditions
Protective Equipment: Self-contained breathing apparatus, chemical resistant suit
Special Procedures: Remove containers from fire area if safe, avoid inhaling combustion gases

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, avoid inhalation, avoid direct contact
Spill Cleanup: Ventilate area, scoop spilled material into appropriate hazardous waste container, wash contaminated area with dilute sodium hypochlorite then neutralize
Environmental Precautions: Prevent spill from entering drains or watercourses, report as required by local regulations
Protective Equipment: Respiratory protection, chemical resistant gloves, safety goggles, full body covering

Handling and Storage

Safe Handling: Use local exhaust ventilation, avoid all unnecessary exposure, keep containers tightly closed, avoid generation of dust
Storage Conditions: Store in original container, cool, dry, well-ventilated area away from acids, oxidizers, and foodstuffs
Incompatible Materials: Strong acids, oxidizing agents, sources of ignition
Special Requirements: Lockable storage preferred, label area clearly

Exposure Controls and Personal Protection

Control Parameters: Occupational exposure limit values not established for this compound, monitor cyanide exposure as precautionary step
Engineering Controls: Chemical fume hood, local exhaust ventilation
Personal Protection: Nitrile or neoprene gloves, laboratory coat, safety goggles or full face shield, certified respirator in case of dust formation, wash hands before breaks and at end of work

Physical and Chemical Properties

Appearance: Yellow crystalline powder
Odor: No characteristic odor
pH: Aqueous solution is alkaline
Melting Point/Freezing Point: Not determined
Boiling Point: Decomposes before boiling
Solubility: Soluble in water
Density: Around 2.5 g/cm3
Vapor Pressure: Negligible
Partition Coefficient: Not available
Viscosity: Not applicable

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: Reacts with acids to release toxic hydrogen cyanide gas, strong oxidizers may cause violent reaction
Conditions to Avoid: Moisture, acid contact, high temperatures, exposure to incompatible substances
Decomposition Products: Cyanide compounds, potassium oxides, gold dust

Toxicological Information

Acute Effects: Rapid poisoning from ingestion or inhalation, severe irritation to skin and eyes
Chronic Effects: Potential cyanide toxicity, repeated exposure may lead to thyroid or nervous system effects
Symptoms of Exposure: Nausea, headache, dizziness, confusion, convulsions, respiratory distress
Validated Data: No long-term animal studies available; cyanide toxicity is well documented in literature
Carcinogenicity, Mutagenicity, Teratogenicity: Not classified, no reliable data for this compound

Ecological Information

Aquatic Toxicity: Highly toxic to aquatic organisms, cyanide component causes acute and long-term aquatic toxicity
Mobility: Soluble, readily migrates in groundwater
Bioaccumulation Potential: Gold complexes tend not to bioaccumulate significantly, but cyanide persistence affects toxicity
Persistence/Degradability: Cyanide ions degrade under aerobic conditions, can persist under anaerobic circumstances
Other Environmental Hazards: Do not allow material to contaminate soil, water bodies, or wastewater

Disposal Considerations

Waste Disposal Methods: Dispose of as hazardous waste in accordance with local, regional, and national regulations
Contaminated Packaging: Triple rinse and treat as hazardous, follow proper disposal channels
Special Instructions: Neutralize cyanide with sodium hypochlorite before disposal, never discharge into natural waters or sewers

Transport Information

UN Number: 1680
Proper Shipping Name: Potassium cyanide mixture
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: I
Transportation Requirements: Label as toxic, keep securely sealed, transport documents must indicate this product as hazardous

Regulatory Information

Inventory Listings: Listed in TSCA, EINECS, and other chemical inventories as potassium gold cyanide complexes
Regulations: Subject to cyanide control regulations, hazardous substance under OSHA, reportable quantity (RQ) applies for cyanide content
Workplace Requirements: Safety data sheet availability, worker training, exposure monitoring, emergency washing stations
Other Regulatory Status: Complies with REACH registration requirements in the European Union, use and transport restrictions apply