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Material Safety Data Sheet: Suberonitrile

Identification

Product Name: Suberonitrile
Chemical Name: Octanedinitrile
Synonyms: 1,6-Dicyanohexane, Octanedinitrile
CAS Number: 3938-65-2
Recommended Use: Chemical intermediate, specialty chemical production
Supplier: Industry supplier details required for site-specific data
Emergency Telephone: Local or regional chemical emergency response number

Hazard Identification

GHS Classification: Acute toxicity (oral, dermal, inhalation), Eye irritation, Skin irritation
Signal Word: Danger
Hazard Statements: Toxic if swallowed, inhaled, or absorbed through skin. Causes skin and eye irritation. Suspected of causing genetic defects.
Pictograms: Skull and crossbones, exclamation mark, health hazard
Precautionary Statements: Prevent all contact with skin and eyes, avoid breathing dust or vapors, use only outdoors or in well-ventilated areas
Routes of Exposure: Inhalation, skin absorption, ingestion
Target Organs: Central nervous system, respiratory system, skin, eyes
Potential Health Effects: Cyanide-like symptoms, including headache, dizziness, shortness of breath, confusion, potential loss of consciousness

Composition / Information on Ingredients

Chemical Identity: Suberonitrile
Concentration: ≥98% (industrial grade material)
Impurities: Minimal, typically other alkane dinitriles ≤2%
Molecular Formula: C8H12N2
EC Number: 223-454-8
Relevant Constituents: No significant stabilizers or other hazardous components
Other Ingredients: None contributing to hazard

First Aid Measures

Inhalation: Immediately remove to fresh air. Maintain open airway. Call for medical assistance. Provide oxygen if possible. Monitor for cyanide poisoning effects.
Skin Contact: Remove contaminated clothing. Rinse skin thoroughly with soap and water for at least 15 minutes. Get medical attention for symptoms.
Eye Contact: Rinse cautiously with water for 15 minutes while holding eyelids open. Do not rub eyes. Contact a healthcare provider.
Ingestion: Rinse mouth thoroughly. Never give anything by mouth to an unconscious person. Seek emergency medical help immediately. Do not induce vomiting.
Notes for Physicians: Monitor for delayed symptoms; treat symptomatically; consider administration of antidotes for cyanide toxicity such as hydroxocobalamin.
Self-Protection: Use suitable PPE to avoid exposure during rescue.

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, carbon dioxide, alcohol-resistant foam
Unsuitable Media: Water jets may spread fire
Specific Hazards: Generates toxic and irritating gases such as hydrogen cyanide and nitrogen oxides under fire conditions
Protective Equipment: Full protective gear including self-contained breathing apparatus (SCBA)
Advice for Firefighters: Approach from upwind; prevent runoff from entering water supplies; cool containers with water spray
Decomposition Products: Hydrogen cyanide, carbon monoxide, nitrogen oxides

Accidental Release Measures

Personal Precautions: Evacuate area, ventilate space. Wear full protective clothing with NIOSH-approved respirator.
Environmental Precautions: Prevent from entering drains, surface water, and soil.
Clean-up Methods: Absorb spills with inert material such as sand or vermiculite. Place waste in sealed chemical waste containers for disposal. Decontaminate surfaces with dilute bleach solution.
Notification Procedures: Report large releases to local regulatory authorities.
Secondary Hazards: Vapors may be flammable; keep away from ignition sources.

Handling and Storage

Handling: Work in a well-ventilated area or fume hood. Use chemical-resistant gloves and protective goggles. Prevent skin and eye contact. Avoid breathing dust or vapor. Do not eat, drink, or smoke in work area.
Storage: Store in tightly closed containers in a cool, dry, well-ventilated facility away from direct sunlight and incompatible substances such as oxidizers, acids, and bases.
Storage Temperature: Recommended between 2°C and 8°C to maintain stability.
Incompatibilities: Strong oxidizing agents, strong acids or bases
Special Requirements: Secure storage location with restricted access. Label containers clearly.

Exposure Controls and Personal Protection

Exposure Limits: No established OSHA/NIOSH legal limits, but practice stringent industrial hygiene controls for toxic nitriles
Engineering Controls: Use local exhaust ventilation, process enclosures, or other engineering controls to keep airborne concentrations below recommended limits
Personal Protective Equipment (PPE): Chemical-resistant gloves (nitrile, neoprene), chemical splash goggles, lab coats or coveralls. Use full-face respirator with appropriate cartridges if significant dust or vapor is present.
Hygiene Measures: Wash hands and face before eating, drinking, or smoking. Remove contaminated clothing and launder before reuse.
Monitoring Methods: Use gas detection instruments in high-risk areas.

Physical and Chemical Properties

Appearance: Clear to pale yellow liquid or crystalline solid
Odor: Mild, ether-like
Odor Threshold: Data not available
pH: Not applicable (neutral organic compound)
Melting Point: 47-49°C
Boiling Point: 267-269°C
Flash Point: 125°C (closed cup)
Evaporation Rate: Data not available
Flammability: May be combustible
Upper/Lower Flammability Limits: Not established
Vapor Pressure: 0.02 mmHg at 25°C
Vapor Density: Heavier than air
Relative Density: 0.97 g/cm³ at 20°C
Solubility: Low water solubility; mixes with organic solvents
Partition Coefficient (log Kow): Estimated 1.7
Autoignition Temperature: >400°C
Decomposition Temperature: >250°C
Viscosity: Data not available
Other Data: Stable under recommended storage conditions

Stability and Reactivity

Chemical Stability: Stable under normal conditions of storage and use
Possibility of Hazardous Reactions: Can react with strong oxidizers and acids yielding toxic gases
Conditions to Avoid: High temperature, open flames, sources of ignition, direct sunlight, incompatible materials
Incompatible Materials: Acids, alkalis, oxidizing agents
Hazardous Decomposition Products: Hydrogen cyanide, carbon oxides, nitrogen oxides

Toxicological Information

Routes of Exposure: Inhalation, dermal, oral
Acute Toxicity: Estimated oral LD50 (rat): 80 mg/kg (toxic if swallowed). Inhalation LC50 (rat): data limited but potentially low with rapid onset of central nervous system effects.
Skin Corrosion/Irritation: Causes moderate skin irritation; lengthy or repeated contact may result in dermatitis
Serious Eye Damage/Irritation: Causes moderate irritation, redness, tearing
Respiratory Sensitization: Not classified; toxic effects predominate
Skin Sensitization: Not classified; irritation noted
Germ Cell Mutagenicity: Limited animal data suggest possible genetic effects; precautions warranted
Carcinogenicity: Not listed by IARC, NTP, or OSHA
Reproductive Toxicity: No conclusive studies; take precautions
Specific Target Organ Toxicity: Central nervous system depression, cyanide-like toxicity
Aspiration Hazard: Not classified; take care to prevent ingestion
Additional Information: Symptoms include headache, dizziness, confusion, nausea, possible respiratory failure

Ecological Information

Ecotoxicity: Toxic to aquatic life and potentially to soil organisms if released in significant quantities
Persistence and Degradability: Expected to be slowly biodegradable; hydrophobic properties slow breakdown in aquatic settings
Bioaccumulative Potential: Moderate potential based on log Kow
Mobility in Soil: Low water solubility means slow migration to groundwater; binds to organic content in soil
Other Adverse Effects: No evidence of ozone depletion, not a persistent organic pollutant by global criteria
Precautions: Avoid contamination of public waterways, effluent treatment recommended

Disposal Considerations

Waste Disposal Methods: Collect material and contaminated absorbent in sealed, labeled chemical waste containers. Arrange for removal through authorized waste disposal contractors. Incineration with afterburner and scrubber preferred.
Container Disposal: Rinse empty containers, neutralize residues, send for appropriate destruction by licensed facilities.
Do Not: Dispose of untreated material in municipal sewers, open environment, or landfill.
Regulatory Recommendations: Follow local, regional, and national hazardous waste regulations.
Special Precautions: Prevent fire/explosion risk in disposal environment.

Transport Information

UN Number: 2811
UN Proper Shipping Name: Toxic solid, organic, n.o.s. (contains Suberonitrile)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: II
Labels: Toxic
Environmental Hazards: Marine pollutant; significant risks if spilled in transit
Transport Precautions: Secure and label packaging; keep away from foodstuffs and incompatible chemicals. Ensure vehicles are equipped for spills and emergencies.
Special Transport Requirements: Carrier must observe national and international dangerous goods protocols

Regulatory Information

TSCA: Listed on the United States Toxic Substances Control Act inventory
REACH: Registered or pre-registered as required in the EU
OSHA: Regulated as a toxic substance; employers must inform and train employees under the Hazard Communication Standard
SARA Title III: Immediate (acute) health hazard
Clean Water Act: Not specifically listed, but reportable quantity requirements apply on calculation-based basis if aquatic release
California Proposition 65: Not currently listed
Other National/International Regulations: May be subject to additional state or country-specific controls
Workplace Practices: Mandate risk training, safety data sheet access, and incident reporting for all workers handling Suberonitrile