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Material Safety Data Sheet – Strontium Arsenite

Identification

Product Name: Strontium Arsenite
Chemical Formula: Sr3(AsO3)2
CAS Number: 13464-86-9
Synonyms: Strontium arsenate (incorrectly used), Strontium(II) arsenite
Recommended Use: Laboratory reagent, research applications
Manufacturer Contact: Reference local supplier or laboratory chemical provider for updated contacts
Emergency Phone: Refer to national poison centers or emergency chemical hotlines

Hazard Identification

GHS Classification: Toxic if swallowed, may cause cancer, toxic to aquatic life
Label Elements: Skull and crossbones, health hazard symbol, environment hazard symbol
Signal Word: Danger
Hazard Statements: Very toxic by ingestion, suspected of causing cancer, causes serious damage to organs, toxic to aquatic organisms with long lasting effects
Precautionary Statements: Avoid all contact, keep locked up, wear protective equipment, do not eat, drink, or smoke when using, use outdoors or in well-ventilated area, wash hands thoroughly after handling

Composition / Information on Ingredients

Chemical Name: Strontium Arsenite
Concentration: 100%
Molecular Formula: Sr3(AsO3)2
Molecular Weight: 557.82 g/mol
Impurities: None significant by manufacturer specification

First Aid Measures

Inhalation: Remove from exposure. Move victim to fresh air immediately. Seek medical advice if symptoms persist. If breathing stops, give artificial respiration.
Skin Contact: Remove contaminated clothing, rinse skin with copious water for at least 15 minutes. Seek medical help for irritation or rash.
Eye Contact: Flush eyes gently for at least 15 minutes under running water, keeping eyelids open. Remove contact lenses if present. Seek prompt medical attention.
Ingestion: Rinse mouth with water. Never induce vomiting. Immediately seek medical attention.
Symptoms/Effects: Abdominal cramps, vomiting, severe headache, respiratory distress, convulsions possible with large doses

Fire-Fighting Measures

Flammability: Not combustible, but toxic fumes develop if involved in fire
Explosion Risk: No known risk of explosion from pure solid
Extinguishing Media: Use carbon dioxide, dry agents, foam or water spray appropriate for surrounding material
Precautions for Firefighters: Full protective gear and self-contained breathing apparatus needed. Avoid inhaling fumes. Cool containers exposed to flames with water spray.
Combustion Products: Strontium oxides, arsenic oxides, irritating and toxic gases

Accidental Release Measures

Personal Protection: Respiratory protection, chemical-proof gloves, full protective clothing, goggles
Spill Cleanup: Carefully sweep up without creating dust. Place in sealed, labeled containers. Avoid runoff to environment.
Environmental Precautions: Prevent entry into waterways, drains, or soil. Notify authorities if spillage causes environmental contamination.
Methods for Containment: Use damp disposable cloths for final cleanup, ventilate area, decontaminate surfaces with suitable reducing agents
Disposal of Clean Up Materials: Treat as hazardous waste in accordance with local, regional, and national laws

Handling and Storage

Handling: Use only in well-ventilated areas, avoid breathing dust or vapor, never pipette by mouth, employ fume extraction where possible, keep away from food and drink
Hygiene Measures: Wash thoroughly before eating, drinking, or smoking. Do not eat or store food in work area.
Storage Conditions: Store in tightly closed, labeled containers in dry, cool, locked corrosive-resistant cabinet, away from acids, reducing agents
Incompatible Materials: Strong acids, strong oxidizers, active metals

Exposure Controls and Personal Protection

Control Parameters: Workplace exposure limits for inorganic arsenic suggested at 0.01 mg/m³ (OSHA), Strontium compounds handled with strict engineering controls
Engineering Controls: Use chemical fume hood, local exhaust ventilation, keep work area monitored
Personal Protection - Eyes: Chemical safety goggles or face shield
Personal Protection - Hands: Impermeable gloves, nitrile or neoprene preferred
Personal Protection - Skin: Chemical-resistant clothing, lab coat or apron
Respiratory Protection: Approved respirator with appropriate cartridge if exposure limits exceeded

Physical and Chemical Properties

Appearance: Solid powder, off-white to pale yellow
Odor: Odorless
Melting Point: Decomposes
Boiling Point: Not applicable
Solubility: Slightly soluble in water
Density: Approximately 4.2 g/cm³
pH: Not applicable
Vapor Pressure: Not relevant
Evaporation Rate: Not applicable
Other Information: No notable volatility under normal conditions

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions
Reactivity: Reacts with strong acids to form toxic arsenic gases
Hazardous Decomposition Products: Arsenic oxides, strontium oxides under fire or high heat
Conditions to Avoid: Heat, moisture, incompatible substances
Polymerization: Will not occur

Toxicological Information

Acute Toxicity: Highly toxic by ingestion and possible inhalation, lethal doses reported at low milligram levels
Chronic Toxicity: Known carcinogen, long-term exposure may affect blood, nervous system, skin, and respiratory tract
Routes of Exposure: Inhalation, ingestion, skin and eye contact
Symptoms: Abdominal pain, numbness, skin lesions, cardiovascular issues, neurological symptoms after cumulative exposure
Carcinogenicity: Arsenic classified as carcinogenic to humans (IARC Group 1, OSHA regulated)
Other Health Effects: Possible reproductive effects, organ damage on repeated exposure

Ecological Information

Ecotoxicity: Very toxic to aquatic life, persistent hazard for fish and invertebrates
Mobility in Soil: Limited mobility due to low solubility, possible accumulation
Persistence/Degradation: Arsenic component does not biodegrade, potential for bioaccumulation
Long-Term Effects: Risk of groundwater and sediment contamination, danger of trophic accumulation
Water Hazard Rating: Classified as severe water pollutant in many regulatory frameworks

Disposal Considerations

Waste Treatment: Collect in sealed, labeled, corrosion-resistant containers
Methods of Disposal: Hand over to licensed hazardous material disposal contractor
Disposal of Packaging: Triple rinse and treat rinsate as chemical waste, destroy or render unusable before landfill
Precautions: Do not discharge to sewers, rivers, or open environment, follow all jurisdictional rules on arsenic disposal

Transport Information

UN Number: 1557
Proper Shipping Name: Arsenic Compounds, solid, n.o.s. (includes strontium arsenite)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: II
Labels Required: Toxic substance label
Additional Requirements: Secure material in upright containers, document as hazardous chemical, assure vehicle driver trained for hazardous cargo
Special Precautions: Emergency procedures required for accidents or spillage in transit

Regulatory Information

OSHA: Regulated toxin, subject to exposure monitoring and medical surveillance
EPA: Listed under RCRA hazardous waste codes, TRI-reportable substance, Clean Water Act toxic pollutant
EU Regulations: Subject to REACH restrictions, included in Annex XVII substances
SARA Title III: Subject to sections for toxic chemicals, immediate and delayed hazards
Other Local Laws: Restrictions on handling, disposal, reporting, workplace exposure limits; check all applicable jurisdictions