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Material Safety Data Sheet (MSDS) - Sodium Salicylate

Identification

Product Name: Sodium Salicylate
Chemical Formula: C7H5NaO3
CAS Number: 54-21-7
EC Number: 200-198-0
Synonyms: O-Hydroxybenzoic acid sodium salt, Sodium o-hydroxybenzoate
Recommended Use: Analytical reagent, pharmaceutical intermediate, laboratory chemical
Supplier: [Specify Name, Address, Contact]
Emergency Contact: [Specify Emergency Number]

Hazard Identification

Classification: Eye irritation, Specific target organ toxicity (single exposure), Skin irritation
GHS Label Elements: Signal word: Warning, Hazard pictograms: Exclamation mark
Hazard Statements: Causes serious eye irritation, may cause respiratory irritation, harmful if swallowed
Precautionary Statements: Avoid breathing dust, wash hands thoroughly after handling, wear eye and face protection, use in well-ventilated area
Potential Health Effects: Irritation to eyes, skin, respiratory system, ingestion may bring nausea or vomiting, chronic exposure can impact kidneys and liver
Environment Hazards: Limited environmental impact, possible aquatic toxicity on release in large quantities

Composition / Information on Ingredients

Chemical Name: Sodium Salicylate
Common Name: Sodium o-hydroxybenzoate
Concentration: >99% by weight
Impurities/ Additives: Trace amounts of moisture or related compounds (identity varies based on synthesis)

First Aid Measures

Inhalation: Move to fresh air immediately, keep comfortable for breathing, seek medical attention if irritation persists
Skin Contact: Wash skin with plenty of soap and water, remove contaminated clothing, get medical help for persistent irritation
Eye Contact: Rinse cautiously with water for at least fifteen minutes, remove contact lenses if present, seek immediate medical attention
Ingestion: Do not induce vomiting, rinse mouth with water, call medical professionals right away, show label or safety data as reference
Most Important Symptoms: Burning, irritation, coughing, stomach pain, headache, allergic reactions in sensitive individuals

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical powder, carbon dioxide, foam
Unsuitable Extinguishing Media: High pressure water streams, avoid direct water jet on burning product
Special Hazards: Thermal decomposition releases irritating fumes, carbon monoxide, sodium oxides, toxic gases
Special Protective Equipment for Firefighters: Positive-pressure self-contained breathing apparatus, fire-resistant clothing, protective gloves and boots
Firefighting Instructions: Cool exposed containers with water spray, avoid inhalation of fumes, keep people away from danger zone, evacuate surrounding areas if needed

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, wear protective gloves, goggles, dust mask, avoid breathing dust
Environmental Precautions: Prevent entry into sewers, groundwater, or water courses, contain spillage and collect waste for proper disposal
Methods for Cleaning Up: Sweep or vacuum without creating dust, place in closed container for disposal, ventilate area, wash site after pickup

Handling and Storage

Precautions for Safe Handling: Wear suitable protective clothes, avoid breathing dust, keep containers tightly closed, use exhaust ventilation, handle with care to prevent spillage
Conditions for Safe Storage: Store in a cool, dry place away from direct sunlight, segregate from acids and oxidizing agents, keep in original container, clearly labeled
Storage Incompatibilities: Acids, strong oxidizers, moisture-sensitive materials, food and feedstuffs

Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits established, follow local regulations or general dust limits
Engineering Controls: Local exhaust ventilation or general area ventilation required for dust control, use enclosed process equipment where possible
Personal Protective Equipment: Safety goggles, chemical resistant gloves, lab coat, dust mask or particulate respirator for airborne dust
Hygiene Measures: Wash hands and face after handling, do not eat, drink, or smoke in work area, keep contaminated clothing away from clean areas

Physical and Chemical Properties

Appearance: White to off-white crystalline powder or granules
Odor: Odorless or faint aromatic smell
Melting Point: Around 200°C (with decomposition)
Boiling Point: Not applicable (decomposes before boiling)
Solubility: Freely soluble in water, slightly soluble in alcohol
pH (aqueous solution): 7-9 (for 10% solution)
Vapor Pressure: Negligible at ambient temperature
Density: About 1.44 g/cm³
Partition Coefficient: Log Pow not measured, not expected to bioaccumulate
Other Properties: Hygroscopic, may form dust in air, no explosive properties reported

Stability and Reactivity

Chemical Stability: Stable at room temperature under recommended storage conditions
Reactivity: No known hazardous reactions under regular use conditions
Possibility of Hazardous Reactions: Contact with acids liberates salicylic acid, strong oxidizers can result in exothermic reactions, thermal decomposition at elevated temperatures
Conditions to Avoid: Extreme heat, moisture, acidic environments, open flames
Incompatible Materials: Acids, strong oxidizing agents, some metals
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, sodium oxides, toxic organic vapors under fire conditions

Toxicological Information

Acute Toxicity: Oral LD50 (rat): about 930 mg/kg, possible irritation and discomfort through ingestion
Chronic Effects: Prolonged exposure linked to kidney and liver impairment, respiratory difficulties with repeated inhalation
Skin Corrosion / Irritation: Causes mild to moderate irritation on contact
Serious Eye Damage / Irritation: Produces significant redness, watering, discomfort
Respiratory or Skin Sensitization: Sensitization rare but possible among allergic individuals
Germ Cell Mutagenicity: No evidence found in standard tests
Carcinogenicity: No known cancer risk from typical exposures
Reproductive Toxicity: Data limited, not expected to affect fertility or development
STOT Single Exposure: Transient respiratory or digestive irritation
STOT Repeated Exposure: Kidney and liver stress reported in rare cases
Aspiration Hazard: Not classified as aspiratory toxin

Ecological Information

Ecotoxicity: Moderate toxicity for aquatic organisms in high concentrations, LC50 (fish, 96 hrs): 220 mg/L
Persistence and Degradability: Biodegradable; breaks down in the environment over time
Bioaccumulative Potential: Low, does not significantly concentrate in species
Mobility in Soil: Highly mobile in water, may leach through soil into groundwater
Other Adverse Effects: Low risk to ozone layer or persistent organic pollutants, larger spills may disrupt local ecosystems

Disposal Considerations

Waste Treatment Methods: Dispose of in accordance with local, regional, national regulations, neutralize with dilute acid where allowed
Product Disposal: Place in tightly sealed, labeled containers for licensed chemical disposal companies
Contaminated Packaging: Clean containers before recycling, dispose as hazardous material if residue is present
Special Precautions: Prevent release to waterways, keep separate from food waste

Transport Information

UN Number: Not classified as hazardous for transport
Transport Hazard Class: Not regulated under ADR/RID/ICAO/IATA/IMDG
Packing Group: Not assigned
Environmental Hazards: Not designated as marine pollutant
Special Precautions for Transport: Secure against physical damage, keep away from incompatible substances, label outer packages clearly

Regulatory Information

Safety, Health, and Environmental Regulations: Subject to chemical inventory requirements (REACH, TSCA, DSL, AICS)
Labeling: Follows GHS/CLP standards
Restrictions: Not specifically restricted, observe general safety regulations for workplace chemicals
Specific Provisions: OSHA: Not hazardous under OSHA Hazard Communication Standard, SARA 313: Not listed, CERCLA: Not listed, California Proposition 65: Not listed
Workplace Classification: Chemical hazard categories: Eye irritation, acute toxicity, workplace controls as per local guidelines