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Potassium Oxide: A Down-to-Earth Look

Historic Pathways and Evolution

Tracing potassium oxide’s journey through time feels like looking into the practical needs of farmers and chemists rather than grand scientific quests. Potash formed the core of early fertilizer endeavors long before science textbooks got printed. People discovered that wood ash improved soil yields. Digging for native sources followed, with serious chemical refinement kicking into gear in the nineteenth century. Over time, manufacturing pulled in strict controls as it became clear just how reactive and strong potassium oxide acted compared to other alkalis. By the twentieth century, fertilizer companies refined methods to pump out pure, well-labeled potassium oxide, shifting the market away from ash piles and toward large-scale industrial plants. The demand for efficient plant nutrition and varied applications kept research alive. Generations of lab workers and plant managers watched this chemical turn from rural bulk commodity to a high-spec product, reflecting both progress and a growing sense of environmental responsibility.

Essential Product Overview

Potassium oxide comes as a white, powdery substance, sometimes forming fine granules. Unlike other well-known forms of potassium such as potassium chloride, this oxide means business: it’s intensely basic and carries plenty of reactive punch. Its standard product grade for industry hovers around 99% purity, which tells buyers they’re getting something with muscle, not filler or water. Potassium oxide jumps out as a super-concentrated potassium source, packing more of the element by weight than just about any other option meant for fertilizer production or chemical synthesis. It never posed as a subtle ingredient; folks use it where powerful reactions and high-potency potassium matter most.

Physical and Chemical Properties

Anyone who handles potassium oxide quickly learns about its aggressive nature. This substance absorbs moisture so desperately it turns into potassium hydroxide almost on contact with water. That, in turn, produces heat that can burn skin or corrode surfaces. In dry air, it sits tight, but any slip in storage leads to clumping and a mess. Potassium oxide weighs out at just over two grams per cubic centimeter, and basicity ranks high—one of the strongest in the alkali family. It melts at nearly 740°C, making it extremely stable against normal household fires but threatening in terms of chemical burns. Chemists and plant workers see its capacity to grab moisture, bust apart bonds, and drive up pH levels in soils or industrial processes.

Technical Specs and Product Labeling

Specifications in this field don’t come from boardroom talk—they settle out of necessity. Purity usually comes in at 98-99%, with low thresholds for sodium, calcium, or heavy metals. Water content needs to drop well below 0.5% due to the substance’s thirst for moisture and tendency to degrade. Packaging must stay tight and moisture-proof, commonly using lined drums or sealed bags. Safety labeling jumps straight to eye, skin, and respiratory hazard warnings. In fertilizer codes, potassium oxide often gets listed as “K2O equivalent,” referencing its potassium weight percentage for easy calculations in agronomy, even when the fertilizer used doesn’t contain the pure oxide. Language around use, disposal, and spill handling stands front and center on any genuine bag or drum.

Preparation and Industrial Method

Refining potassium oxide starts with high-purity potassium carbonate or potassium hydroxide. The choice depends partly on available feedstocks and price swings. Heating potassium nitrate or carbonate in the presence of metallic potassium at high temperature drives off carbon dioxide, pushing the reaction toward oxide formation. Crucible work involves carefully managing both water access and temperature to avoid runaway reactions. Large-scale outfits rely on closed systems and strict safety rules, since runaway moisture or leaks can trigger fires. Recovery and recapture of byproducts limits waste and risks. The production process speaks to both chemistry know-how and real experience in scaling up dangerous reactions.

Chemical Reactions and Ways to Modify

Potassium oxide doesn’t play well with water—add a drop, and it hisses and spits heat, turning straight to potassium hydroxide. This hydrolysis sits at the center of many applications. Blend it with acid, and the oxide neutralizes instantly, forming potassium salts. In the glass industry, potassium oxide enters the melt to adjust properties, harden output, or control viscosity. In ceramics, its behavior under firing shapes color and durability. Chemical manufacturers use O2 reactivity to drive complex syntheses or absorb atmospheric moisture. Modifying potassium oxide means changing its hydration or blending for special releases or improved safety for handling. Some processes fix it into granules with slow hydration for field applications, which keeps dust and risk down.

Synonyms and Common Product Names

Potassium oxide shows up in records and labeling under several names. On material safety data sheets (MSDS), it’s listed as “potassium monoxide,” although that’s rare in everyday talk. Fertilizer bags in North America often mark content as “potash (as K2O).” In the chemical trade, folks usually call it by its oxide label, but glassmakers and ceramics workers may drop references to “potash oxide” or simply “oxide.” No one mistake exists in the lingo—just the context from factory floor to agronomist’s field guide.

Staying Safe and Running Operations Smoothly

Anyone working with potassium oxide quickly learns respect. Direct skin contact burns, and eye exposure brings real danger. Breathing dust inflames airways, making dust masks and goggles standard gear even in lab settings. Storage demands solid containers, cool rooms, and dryness. Open air creates clumping and caking, upping both loss and risk. Spillage in the workplace needs rapid cleanup, often involving dry agents, since water turns the substance corrosive. Training on handling, emergency eyewash access, and thoughtful disposal prevent most problems. Fire safety especially calls for non-water suppression due to violent reactions. Committees set strict exposure limits and enforce best practices both for industry and agriculture, and safety data sheets flag potassium oxide as a hazardous substance, not something for casual use or storage.

Real-World Applications

Fertilizer represents the major slice for potassium oxide by a long shot. Farmers count on its ability to drive root growth and fill nutritional needs, especially where soils lack potassium. Most commercial NPK blends calculate total potassium content as the oxide, streamlining calculations even for mixed or compound fertilizers. In glassmaking, potassium oxide improves durability and heat resistance, important for special glassware, television tubes, and lenses. Ceramics and refractories grab potassium oxide to adjust melting behavior and color, favoring properties that other potassium salts can’t give. Certain detergents draw on it for shifting alkalinity. Researchers probe potassium oxide for its role in catalysts and even as an energy storage component, betting on its high reactivity. For battery technology and specialty chemicals, folks look for quick and potent potassium sources at scale.

Research, Development, and New Directions

Academics run experiments using potassium oxide as a catalyst, exploring its effects on both speed and selectivity in organic reactions. Clean energy research examines how potassium oxide alters electron flows and improves charge storage, especially for new battery designs that seek to move away from lithium and cobalt. In agriculture, ongoing studies assess soil amendment with oxide-derived blends, pushing yields while minimizing run-off and addressing sustainability. Industrial process chemists look for ways to stabilize the oxide, reduce dust, and bind it into safer forms for handling. Environmental scientists ask how best to recover potassium from wastes, redesigning circular production loops. Down in the lab, small changes in formulation and handling have driven several advances in safety and performance across the years. Every year, a new research group seems to find a fresh angle.

Toxicity and Long-Term Exposure

Potassium oxide’s health effects stack up mostly from its caustic nature, not direct toxicity of the potassium ion. Exposure in people leads to burns and scarring, especially on damp or sweaty skin. Because potassium is an essential mineral, the element itself poses no harm in trace amounts—but exposure to oxide quickly gets out of control due to chemical burns at the site of contact. Animal studies show similar effects, with tissue corrosion and long-term irritation leading workplace safety regulators to keep exposure times and concentrations low. Chronic occupational contact produces risk for persistent skin and airway problems. So, real-world toxicity of potassium oxide connects less to systemic organ damage and more to physical and chemical destruction where it lands. Workers need solid protection and constant safety oversight.

Looking Forward: Future Prospects

Researchers and manufacturers put serious effort into making potassium oxide safer for field use. Encapsulation and controlled-release particles have started to shift the fertilizer market as governments turn attention to runoff and waterway protection. Technological growth in glass, solar cells, and specialty ceramics grabs at potassium oxide for its rare combination of reactivity and base strength. Battery innovation challenges lithium’s dominance, and as new chemistries take hold, potassium oxide stands ready for alternative anode development. Environmental advocates urge closed-loop recycling, while industry players hunt cheaper production routes and safer packaging. As global agriculture pushes toward efficiency, potassium oxide’s contribution looks likely to hold steady as both a base nutrient and a specialty industrial ingredient, shaped by safety, innovation, and environmental needs.




What is potassium oxide used for?

Potassium Oxide and Agriculture: Feeding the World

Farmers look for ways to get more out of each acre. Many soils don’t give crops what they crave. Potassium oxide comes in handy here. When manufacturers turn it into potash fertilizers, fields get the extra potassium they need. Plants push out better roots, hold onto water longer, and fight off disease in tough seasons. Corn, wheat, and fruit trees like apples and cherries all depend on potassium to survive swings in weather. In my own experience helping out at my uncle's orchard, a shortage of potassium spelled small fruit and tired-looking leaves. After a simple fertilizer with potassium oxide, the trees bounced back with healthy growth.

Glass and Ceramics: Beyond the Farm

Potassium oxide doesn’t end its journey in crop fields. Glassmakers rely on it to get glass that melts at lower temperatures and cuts down on energy bills. Mixing in potassium instead of the more common sodium changes how the final glass looks and feels. The glass from camera lenses and laboratory equipment benefits from this. With potassium content boosted through potassium oxide, glass gets better resistance to chemicals, holds its shape, and feels smoother to the touch.

Ceramics factories also use potassium oxide. It toughens up porcelain and other fine ceramics, helping cups, plates, and tiles last longer in kitchens and bathrooms. It makes glazes shine brighter and stand up to scratches or stains. My time in a community pottery workshop showed me how a tweak in kiln ingredients—swapping in different fluxes—gave ceramics that smooth, clear finish most folks look for on vases or dinner plates.

Industrial Chemistry: More Than a Fertilizer

Potassium oxide helps drive many industrial reactions. It reacts quickly with water, forming potassium hydroxide—a strong base found in everything from soap and cleaning agents to biodiesel fuel. Chemical manufacturers turn to potassium hydroxide derived from potassium oxide since it helps split fats into soap and glycerin. Lye made this way also finds a use in food processing: German pretzels with their brown, crisp skin owe their texture to a lye dip.

Other industries feed potassium oxide into specialty chemicals used in batteries, water treatment, and even rocket propellants. High-purity potassium is a critical piece in some battery electrolytes. By starting with potassium oxide, chemists get a pathway to these niche but important compounds.

Safety and the Environment

Handling potassium oxide calls for respect. It reacts strongly with water, giving off heat and forming caustic material. A small spill on wet hands stings and burns, so good training and protective gear become part of using it right—both in industry and smaller labs. During school chemistry labs, I remember our teachers drilling in the lesson: always add potassium oxide to water slowly, never the other way around, or risk a boiling mess.

On a bigger scale, using too much potassium oxide on fields contributes to runoff and algae blooms in lakes and rivers. The conversation about smart fertilizer use keeps growing as farmers try to protect both yield and planet. Soil testing, better application methods, and slow-release formulas can all limit excess potassium washing away. In my own gardening, following the directions instead of dumping extra made for healthier plants and fewer weeds in the local creek.

Looking Forward

Potassium oxide plays a silent but important role from farm rows to science labs. Knowing how it shapes food, materials, and chemistry helps make smarter choices—whether growing crops, shaping glass, or powering up research. By paying attention to safety and the environment, communities can continue to benefit from what potassium oxide brings without running into bigger problems down the road.

Is potassium oxide dangerous or hazardous?

Handling Potassium Oxide: Common-Sense Precautions

Potassium oxide rarely comes up outside certain industries or labs. It’s a white or gray powder that can react strongly with water, sparking heat and forming potassium hydroxide. If you’ve ever seen what happens when water touches metallic potassium, you get the idea. In everyday life, the risk from potassium oxide is almost nil, but without respect for its properties, there’s room for trouble.

This compound stands out for its caustic bite. Touching it with bare skin or letting it get near your eyes isn’t just uncomfortable—it burns. Add water, and it gets worse. From personal experience in industrial settings, protective gloves, goggles, and even face shields become necessities. One careless move, and you end up in the emergency wash station wondering what you missed in the safety briefing. The lesson sticks.

Why Potassium Oxide Isn’t Found in Your Kitchen

Potassium oxide shows up in fertilizer production, glassmaking, and sometimes in labs doing chemical synthesis or research. It’s not built for home settings, grocery shelves, or consumer use. That’s down to reactivity and the potential for serious injury if mishandled. The upside: run-of-the-mill exposure just doesn’t happen. The downside: those who work with it need to treat it as hazardous, because that’s the reality.

Accidents have happened in agriculture or manufacturing. Potassium oxide mishandled during mixing has led to serious burns and even fires. A friend once shared a story where a small spill caused the shop’s water bucket to boil over with caustic steam—luckily, no one was hurt. Standards for its storage and handling exist for a reason, and that reason is real-world experience. Every splash and cloud of dust is a reminder that gloves and masks aren’t just for show.

Environmental Concerns and Responsible Management

Potassium oxide can harm the ecosystem if a major release occurs, especially around water. The compound reacts with moisture and could alter soil and water pH, affecting whether plants and animals can thrive. Farmers and manufacturers who handle it use containment systems and emergency plans, not only to protect the people on site, but to keep nearby land and waterways safe.

Transportation adds another piece to the puzzle. Trucks moving potassium oxide must follow hazardous materials protocols—secured containers, spill kits, paperwork kept up to date. I’ve seen inspections at shipping terminals that catch issues early, and those checks make a difference. One overlooked barrel might mean cleanup crews facing a mess that spreads farther than anyone wants to see.

Solving the Puzzle: Respecting Risks, Protecting People

Knowledge and preparation cut risk down to size. Worker training, clear signage, up-to-date data sheets, and ready access to personal protective equipment create an environment where accidents stay rare. There’s always a risk of complacency, especially for those who’ve handled the same materials for years. But strong leadership—people who don’t let safety standards slide—sets the tone for everyone else.

For anyone facing potassium oxide, the answer to "is it dangerous?" means thinking past labels and remembering the personal impact. From the first time I put on protective gear to handle it, I understood that respect for chemicals isn’t about fear—it’s about making sure the shift ends without a trip to the emergency room. That holds true for anyone, whether on a fertilizer production line or a research bench.

How should potassium oxide be stored?

The Risks Potassium Oxide Brings

Potassium oxide reacts fiercely with water, releasing heat and forming potassium hydroxide. This creates a hot, caustic solution that can burn skin and eyes in seconds. Moisture in the air alone can start that reaction, so a bag left open quickly becomes a hazard. Over the years, I’ve seen even seasoned lab staff get caught off guard by how strongly potassium oxide goes after even tiny bits of water. Fires, chemical burns, and damaged equipment tend to follow careless storage.

Safe Storage Starts With the Right Container

Standard glass jars won’t cut it—potassium oxide eats through rubber stoppers and corrodes even some types of metal. Best practice means using airtight containers made from high-density polyethylene or strong glass with Teflon linings. Always check seals for cracks or dust, since even minor leaks can let in humidity. I’ve learned that the smallest oversight—like a missed chip in the edge of a container—lets in just enough air to start trouble.

Keep It Dry, Dark, and Cool

Humidity is the enemy, so a dry storage environment stands at the front line. Desiccators filled with silica gel or other moisture-trapping agents do the heavy lifting. I always make room for one in any storage plan. Never store potassium oxide near sinks or plumbing, since just a splash of water can cause a dangerous reaction.

Temperature swings also raise the risk of condensation inside containers, so a steady, cool environment helps avoid that. I’ve seen storage lockers in hot buildings where condensation runs down the inside of poorly sealed jars, ruining the product and ramping up the hazard to anyone who opens it.

Avoid Mixing With Incompatibles

Potassium oxide should not share shelves with acids or flammable substances. Mixing those by accident can trigger explosions. Any chemist who has shared lab space can recall the occasional scare from jars left in the wrong spot. Proper labeling marks each substance clearly, and placing it in a separate, locked cabinet keeps mix-ups at bay.

Protect the People First

Access controls help by keeping untrained people from stumbling onto dangerous materials. In my own work, I’ve seen too many labs overlook security, only to scramble after an intern or janitor gets too close. Training means more than a quick demo on handling—it includes emergency procedures and real-time drills so staff respond fast if anything spills or reacts.

Handling the Inevitable Accident

Even with the best plans, spills happen. Neutralizing potassium oxide on contact with water is not an option—the resulting heat just spreads the caustic mess. Dry sand or soda ash can contain most minor spills, but every workspace should keep an eyewash station and emergency shower close. Years of experience show that proper spill kits and clearly posted emergency numbers make all the difference when seconds count.

The Value of Diligence

Potassium oxide will always demand respect. Secure containers, moisture-free rooms, clear labels, and strong training programs all contribute to a safer workspace. It’s not enough to write procedures—everyone using, storing, or disposing of the material owes it to themselves and their coworkers to follow them every time. One forgotten detail opens the door to danger, so attention to each step never goes out of style.

What is the chemical formula of potassium oxide?

Unlocking the Role of K2O in Chemistry and Beyond

Potassium oxide stands out in chemistry because it delivers a straight shot of potassium and oxygen fused in a simple crystal lattice. Its formula, K2O, might float by as just another bit of trivia, but every chemistry classroom and a good chunk of the global fertilizer industry know how big a deal that is.

I remember handling potassium oxide back in university labs. It reacts so quickly with water I hardly had a moment to blink. Watching this powder fizz and heat up told me this wasn’t just some boring mineral dust. Handling it drove home two lessons. First, safety gear never sits out of style. Second, even basic compounds shape everything from food on plates to the batteries charging our electronics.

Why Does K2O Matter?

Potassium plays a headliner role in plant growth. Fields don’t yield much if their soil misses enough of this nutrient. Fertilizer companies rely on potassium oxide because it contains over 83% potassium by weight. Potash, a catchall for potassium salts, often gets measured in “equivalent K2O” to streamline comparisons. This helps growers talk apples to apples when buying nutrients for crops.

The scavenger hunt for efficient potassium sources never really ends. In some farming circles, it’s easy for growers to think one fertilizer's the same as another. That couldn’t be further from the truth. Potassium oxide fuels high yields because it dissolves and gets to plant roots quickly, keeping soils rich and crops healthy. That’s not just about business profits. Countries lean on bumper harvests to feed growing populations, and missing potassium starts a domino effect: weak plants, poor food quality, and hungry communities.

Potassium oxide also turns up in glassmaking, acting as a flux that drops melting temperatures. Some of the clearest windowpanes and brightest glazes in history owe their sparkle to a bit of potassium slipped into the batch. Outside the kiln, batteries also tap into potassium compounds. Storage technology must squeeze every watt-hour for our phones, laptops, and grids, so chemists bank on a range of potassium-based materials.

Risks, Realities, and Smarter Solutions

I’ve seen what skipping safety can do with chemicals like K2O. Powders may seem harmless, but contact with skin or inhaling dust stings and burns. Reacting with water releases heat and caustic compounds, which means storage and application must always get careful handling. Some factories still struggle to meet best safety standards. Modernizing these facilities not only protects workers but ensures the end-use materials reach consumers uncontaminated.

Looking at solutions, investing in training for anyone dealing with concentrated chemicals makes a big difference. Schools still rely too much on memorization, skipping the hands-on side of chemical safety. Early and clear demonstration stories stay with people longer than any list of safety slogans ever could. Fortifying supply chains to track purity, packaging, and safe shipment could stamp out most accidental exposures.

Summing Up the Basics and the Bigger Picture

The K2O of potassium oxide may seem like just a label, but this stuff fuels life from soil to silicon. Its punchy chemical behavior creates opportunities to boost crops, build better glass, and push battery tech. Getting those benefits safely and responsibly keeps chemistry not just clever, but crucial for everyday living.

What precautions should be taken when handling potassium oxide?

Why Potassium Oxide Demands Respect

Potassium oxide isn’t your everyday chemical. In the lab or out in industry, it shows a feisty side. Anyone who’s ever cracked open a jug for the first time knows it grabs water from the air and forms caustic potassium hydroxide. That reaction heats up—burns, actually—fast enough to blister skin or scar eyes before you can even react. This isn’t distant theory. I’ve seen a young tech stare at a white powder turning into syrup on their gloves, confusion flashing across their face before the burning started. Burns set in quick, and cleanup took hours.

Its reaction with water isn’t rare knowledge, either. The CDC and European Chemicals Agency both list it as a corrosive to skin, eyes, and even the respiratory tract. One quick puff of dust at the wrong angle and you can kiss comfort goodbye until the grittiness fades. Health isn’t the only thing on the line; chemical spills lead to expensive cleanup and lost workdays, so taking precautions isn’t about paranoia—it’s about practicality.

Addressing the Real Hazards

Goggles and tight-fitting gloves should never sit unused on the bench. I’ve felt the difference between latex and proper nitrile when scraping powder out of a jar. Regular latex breaks down too quickly. Anyone handling potassium oxide needs gloves built for caustics, ideally doubled up—one pair inside another—so if the first tears, you spot it before more damage creeps in. For eyes, wraparound safety goggles make sense, because even one wayward speck can cut a day short.

Respirators sometimes seem overkill, especially in a big warehouse. Dust masks, the paper kind, do little against fine caustic particles. A certified half-face respirator with P2 or P3 filters blocks the worst of the airborne dust, keeping it out of the lungs. Facility managers should install clear warnings and run staff through demos. Training can’t slide; people need to remember these steps long after their orientation packet gathers dust.

The work zone itself tells a story about safety. Good ventilation keeps the air clear. Closed transfer systems and scoopless dispensing—shovels, not scoops, for bulk movement—make powder clouds less likely. Spill kits, not just a dusty box in the corner, need to sit near each point of use, equipped for a fast response with absorbent materials that neutralize caustics on contact. If you’ve ever had to hunt for a spill kit with caustic water stinging your boots, you know planning beats improvisation every time.

Respecting Waste and Reaction Risks

Once potassium oxide enters a process, it produces runoff, and disposal without neutralization can damage plumbing, harm local water sources, and invite heavy fines. Acidic neutralization—done slowly, in well-controlled steps—limits steam, splatter, and heat. Everyone involved in waste handling must have clear access to pH indicators and neutralizing agents, not just instructions buried in procedure manuals. Supervisors gain credibility when they perform these tasks at least once—fellow workers learn best from lived experience, not just printed rules.

Potassium oxide loves to react with water, acids, organic materials—pretty much anything that comes close, if conditions allow. Stockpiles should stay well away from flammable materials, acids, and even paper records as insurance against accidental spills. Labeling every drum in big, bold type with hazard symbols prevents guesswork during those stressful moments when things go wrong. Anyone who’s worked a shift in a multi-chemical storage room knows the value of clear labeling when alarms sound.

The Bottom Line: No Shortcuts

Treating potassium oxide with respect comes down to choosing reliable safety equipment, designing smart storage and movement routines, and refreshing everyone’s memory with hands-on training often enough that no one gets complacent. Protective gear, full transparency around hazards, and practical drills turn workplace safety from a checklist into second nature—all rooted in hard-earned lessons from the way real teams actually work.

Potassium Oxide
Potassium Oxide
Names
Preferred IUPAC name Dipotassium oxide
Other names Dipotassium oxide
Potassium monoxide
Pronunciation /pəˈtæsiəm ˈɒksaɪd/
Identifiers
CAS Number 12136-45-7
3D model (JSmol) `__K2O__`
Beilstein Reference 3200482
ChEBI CHEBI:88321
ChEMBL CHEMBL1201636
ChemSpider 14747
DrugBank DB14572
ECHA InfoCard 100.029.712
EC Number 215-208-9
Gmelin Reference 1739
KEGG C14315
MeSH D011089
PubChem CID 16211286
RTECS number TL6475000
UNII 7F6A1G4E6E
UN number UN2063
Properties
Chemical formula K2O
Molar mass 94.2 g/mol
Appearance White to yellow powder
Odor Odorless
Density 2.32 g/cm³
Solubility in water Reacts violently
log P -4.4
Vapor pressure Negligible
Acidity (pKa) 15
Basicity (pKb) pKb = 0.2
Magnetic susceptibility (χ) +20.0·10⁻⁶ cm³/mol
Refractive index (nD) 1.45
Dipole moment 2.96 D
Thermochemistry
Std molar entropy (S⦵298) 94.5 J/(mol·K)
Std enthalpy of formation (ΔfH⦵298) -363.2 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -363.7 kJ mol⁻¹
Pharmacology
ATC code A12BA02
Hazards
Main hazards Causes severe skin burns and eye damage. Reacts violently with water.
GHS labelling GHS02, GHS05, GHS08
Pictograms GHS02,GHS05
Signal word Danger
Precautionary statements H260-H315-H319-H335
NFPA 704 (fire diamond) 3-0-2
Lethal dose or concentration LD50 (oral, rat): 250 mg/kg
LD50 (median dose) LD50 (median dose): Oral rat: 273 mg/kg
NIOSH 0281
PEL (Permissible) 15 mg/m3
REL (Recommended) 20 mg/m3
IDLH (Immediate danger) Not established
Related compounds
Related compounds Lithium oxide
Sodium oxide
Rubidium oxide
Caesium oxide
Potassium peroxide
Potassium superoxide