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Product Name: Pine Oil
Chemical Family: Terpene alcohols
Synonyms: Pine needle oil, Dipentene
Manufacturer: Name, Address, Emergency phone number
Recommended Use: Cleaning agent, fragrance, disinfectant
CAS Number: 8002-09-3
UN Number: 1272
EMERGENCY OVERVIEW: Colorless to pale yellow oily liquid with a characteristic pine odor. Flammable liquid and vapor. May cause skin and eye irritation.
GHS Classification: Flammable liquids—Category 3, Skin Irritation—Category 2, Eye Irritation—Category 2A, Acute Toxicity (oral)—Category 4
Signal Word: Warning
Hazard Statements: Combustible liquid. Causes skin and serious eye irritation. Harmful if swallowed. May be harmful in contact with skin. May cause allergic skin reactions.
Precautionary Statements: Keep away from heat, sparks, open flames. Wash hands thoroughly after handling. Wear protective gloves, eye and face protection. In case of inadequate ventilation, wear respiratory protection.
Potential Health Effects: Contact with skin and eyes may produce irritation or allergic reaction in some individuals. Swallowing can cause gastrointestinal discomfort, nausea, vomiting. Prolonged exposure can affect the central nervous system.
Main Ingredient: Pine Oil (Terpene alcohols) 85–100%
Minor Components: alpha-Terpineol, beta-Terpineol, borneol, other terpene derivatives
Impurities: Water, resinous substances, possibly trace solvents
CAS Numbers: 8002-09-3 (pine oil), 8000-41-7 (alpha-terpineol)
Inhalation: Remove person to fresh air. Seek medical attention if symptoms persist.
Skin Contact: Remove contaminated clothing. Wash skin with soap and water for at least 15 minutes. Seek medical attention for persistent irritation.
Eye Contact: Rinse immediately with plenty of water for at least 15 minutes. Remove contact lenses if safe to do so. Seek medical attention.
Ingestion: If swallowed, do not induce vomiting. Rinse mouth. Seek immediate medical assistance; give small quantity of water if person is conscious and alert. Symptoms may include nausea, vomiting, abdominal pain.
Suitable Extinguishing Media: Use foam, dry chemical, carbon dioxide, or water spray (fog). Do not use water jet.
Special Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear.
Specific Hazards: Generates hazardous vapors and combustion products such as carbon monoxide, carbon dioxide.
Explosion Hazard: Vapors can form explosive mixtures with air especially in unventilated areas.
Firefighting Instructions: Move containers away from fire if it can be done safely. Cool with water spray. Prevent runoff to sewers or waterways.
Personal Precautions: Wear suitable personal protective equipment—gloves, goggles, respirator. Remove sources of ignition. Ensure proper ventilation.
Environmental Precautions: Prevent product from entering drains, surface water, or soil. Notify authorities if significant spill enters watercourse.
Methods for Cleaning Up: Contain spill. Absorb with sand, earth, inert material. Collect in suitable containers for disposal. Use non-sparking tools. Clean area thoroughly with soap and water after removal.
Handling: Handle in well-ventilated areas away from heat and open flames. Avoid breathing vapors and contact with eyes or skin. Use explosion-proof equipment.
Storage Conditions: Store in tightly closed containers in a cool, dry, well-ventilated place away from direct sunlight and incompatible substances such as oxidizing agents and acids.
Incompatible Materials: Strong oxidizers, acids, bases.
Special Storage Requirements: Store away from ignition sources, keep containers upright and secure to prevent leaks.
Occupational Exposure Limits: No OSHA PEL or ACGIH TLV for pine oil; good industrial hygiene practices recommended.
Engineering Controls: Local exhaust ventilation to keep vapor concentrations below exposure limits. Use mechanical ventilation in confined spaces.
Personal Protective Equipment (PPE): Wear chemical-resistant gloves (nitrile, neoprene), safety goggles, protective clothing. If exposure limits may be exceeded, use an appropriate NIOSH-approved respirator.
Hygiene Practices: Wash hands after handling. Remove contaminated clothing and wash before reuse. No eating, drinking, or smoking in work area.
Appearance: Colorless to pale yellow oily liquid
Odor: Distinct pine scent
pH: Slightly acidic to neutral
Melting Point: -24°C
Boiling Point: 200–220°C
Flash Point: 65°C (closed cup)
Evaporation Rate: Slower than water
Solubility: Slightly soluble in water; soluble in alcohol and ether
Density: 0.93–0.96 g/cm³ at 20°C
Vapor Pressure: 0.22 mmHg at 25°C
Partition Coefficient (n-octanol/water): 2.74–3.28
Auto-ignition Temperature: 220°C
Viscosity: Slightly viscous liquid at room temperature.
Chemical Stability: Stable under normal storage and handling conditions.
Hazardous Polymerization: Will not occur under recommended conditions.
Conditions to Avoid: Heat, sparks, open flames, direct sunlight, static discharge.
Incompatible Materials: Avoid contact with strong oxidizers, acids, alkaline substances.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, irritating vapors if involved in a fire.
Acute Toxicity: Oral LD50 (rat) 3200 mg/kg
Routes of Exposure: Inhalation, ingestion, skin and eye contact.
Potential Health Effects: Skin—may cause irritation or allergic dermatitis in sensitive individuals. Eyes—causes irritation, possible conjunctival inflammation. Inhalation—respiratory tract irritation, headache, nausea with excessive exposure. Ingestion—gastrointestinal distress, potential for aspiration into lungs and pneumonia.
Chronic Effects: Repeated or prolonged exposure can cause sensitization, eczema. No evidence of carcinogenic, mutagenic, or reproductive toxicity from standard use.
Target Organs: Skin, eyes, central nervous system, gastrointestinal tract.
Ecotoxicity: Toxic to aquatic life. May cause long-term adverse effects in the aquatic environment.
Persistence and Degradability: Biodegradable but may be slow in some environments.
Bioaccumulation Potential: Potential for bioaccumulation in aquatic organisms due to moderate log Kow.
Mobility in Soil: Low water solubility limits mobility, but volatile components may disperse.
Other Adverse Effects: Large releases can be hazardous to aquatic plants and animals. Limit release to the environment.
Waste Disposal Methods: Dispose of according to local, regional, national, and international regulations. Do not discharge into drains, surface water, or soil. Waste may require incineration under controlled conditions by licensed waste treatment companies.
Container Disposal: Rinse empty containers with water before disposal. Do not reuse containers for other purposes without proper cleaning.
UN Number: 1272
Proper Shipping Name: PINE OIL
Hazard Class: 3 (Flammable liquids)
Packing Group: III
Labels Required: Flammable liquid
Special Precautions: Keep away from oxidizing agents and ignition sources during transport. Ensure containers are tightly sealed and upright.
TSCA: Listed
DSL/NDSL (Canada): Listed
EU Classification: Xi Irritant, N Dangerous for the environment
Risk Phrases: R10 (flammable), R36/38 (irritating to eyes and skin), R43 (may cause sensitization by skin contact), R51/53 (toxic to aquatic organisms, may cause long-term adverse effects)
Safety Phrases: S2 (keep out of reach of children), S24/25 (avoid contact with skin and eyes), S29 (do not empty into drains), S37/39 (wear suitable gloves and eye/face protection)
