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Product Name: P-Bromoaniline Fluoroacetate
Chemical Formula: C8H7BrFNO2
Synonyms: 4-Bromoaniline, Fluoroacetic Acid Ester
Recommended Use: Research, chemical synthesis, intermediate
Company Identification: Hazard control and reporting handled according to national and local regulations
Emergency Phone Number: Poison control and firefighting service at the country level
GHS Classification: Acute Toxicity, Category 2 (oral), Skin Corrosion/Irritation, Category 2, Eye Damage, Category 2A
Hazard Statements: Fatal if swallowed; causes skin and eye irritation; possible mutagenic effects; hazardous to aquatic environments
Signal Word: Danger
Precautionary Statements: Avoid breathing dust/fume/gas/mist/vapors/spray; wash hands thoroughly after handling; do not eat, drink, or smoke when using; proper PPE required
Pictograms: Skull and crossbones, exclamation mark, health hazard, environment
Chemical Name: P-Bromoaniline Fluoroacetate
CAS Number: 70953-13-7
Concentration: >98% by weight
Impurities: Trace organic compounds, brominated side products may be present under 2%
General Advice: Immediate medical attention is essential with any exposure
Inhalation: Remove from exposure site into fresh air; seek urgent medical supervision if symptoms appear
Skin Contact: Remove contaminated clothing, flush skin continuously with water for at least 20 minutes; wash with mild soap; seek prompt medical care
Eye Contact: Rinse eyes with water for 15 minutes, lifting eyelids occasionally; immediate medical evaluation is required
Ingestion: Rinse mouth thoroughly—do not induce vomiting; immediate medical help is essential
Most Known Symptoms: Headache, dizziness, abdominal pain, drowsiness, skin and eye redness, blurred vision
Suitable Extinguishing Media: Dry chemical powder, foam, carbon dioxide, water spray
Unsuitable Media: Direct water jets may spread material
Protective Equipment: Self-contained breathing apparatus, full protective suit
Hazardous Products: Hydrogen bromide, carbon oxides, nitrogen oxides, hydrogen fluoride on decomposition
Special Procedures: Remove containers from zone if safe; prevent run-off into waterways
Personal Protection: Ventilated respirator, multi-layer gloves, protective goggles, disposable gown
Environmental Protection: Block seepage into soil and water sources; cover drains
Cleanup Methods: Absorb spill with inert material; collect in non-leaking, tightly sealed containers for hazardous waste disposal; decontaminate area and equipment with soap and water after removal
Emergency Procedures: Evacuate non-essential personnel, avoid dust generation
Safe Handling: Use in well-ventilated laboratory setting, with fume hood; avoid unnecessary contact or inhalation; no eating or drinking nearby; always keep containers tightly sealed
Storage Conditions: Store locked away from incompatible substances (acids, bases, strong oxidizers); keep at 2–8°C, protected from humidity and light; use secondary containment whenever possible
Incompatible Materials: Acid chlorides, anhydrides, strong oxidizers, strong acids and bases
Exposure Limits: No specific OSHA, NIOSH or ACGIH TLV established; treat as highly toxic
Engineering Controls: Fume hood, eyewash station, safety shower required nearby
Personal Protective Equipment (PPE): Lab gloves with nitrile or butyl resistance, splash-resistant goggles, full-body lab coat, respiratory protection for airborne concentrations
Hygiene Measures: Remove and wash contaminated clothing before reuse; thorough hand washing before breaks and at end of work shift
Physical State: Solid or crystalline powder
Color: Light yellow to off-white
Odor: Pungent, sweetish
Melting Point: 81–85°C
Boiling Point: Data not available
Solubility: Slightly soluble in water, freely soluble in many polar organic solvents
Vapor Pressure: Negligible at ambient temperature
Density: Approx. 1.7 g/cm³
pH: Not applicable (non-aqueous solid)
Partition Coefficient (log Kow): Not measured—estimated moderate bioaccumulation risk
Chemical Stability: Stable at low temperatures if protected from light and moisture
Conditions to Avoid: High temperatures, direct sunlight, strong oxidizing or reducing agents
Hazardous Reactions: May react violently with strong oxidizers; potential to release toxic fumes under fire or decomposition
Decomposition Products: Hydrogen bromide, hydrogen fluoride, carbon dioxide, carbon monoxide, nitrogen oxides
Acute Toxicity: Extremely toxic by oral route; probable human oral LD50 less than 5 mg/kg
Chronic Effects: Prolonged exposure impacts central nervous system; may damage kidneys, liver; mutagenicity suggested by similar compounds, not fully studied
Skin/Eye Irritation: Causes burning, redness, and swelling
Sensitization: May cause allergic skin reactions
Carcinogenicity: Not listed by IARC, NTP, or OSHA; insufficient long-term data
Symptoms of Exposure: Nausea, vomiting, muscle cramps, respiratory distress, faintness, seizures may occur at high doses
Ecotoxicity: Very toxic to aquatic organisms; acute aquatic LC50 less than 1 mg/L (estimated); long-term exposure disrupts population balance
Mobility: Chemical shows moderate persistence in soil; possible leaching risk
Bioaccumulation: Likelihood of bioaccumulation in aquatic food chains; insufficient measurement data
Degradability: Slow microbial breakdown under aerobic conditions; persistent under anaerobic conditions
Other Adverse Effects: Avoid release to environment; marine and freshwater toxicity concern
Waste Treatment Methods: Chemical waste container with clear hazard labeling; professional hazardous waste incineration preferred
Packaging Disposal: Decontaminate and rinse with minimal water, then treat as hazardous waste
Precautions: Do not flush to drain, sewer, or natural water sources
Disposal Guidance: Follow country and local environmental control guidelines for hazardous laboratory chemicals; consult professional hazardous materials handler
UN Number: 2811 (Toxic solid, organic, n.o.s.)
UN Proper Shipping Name: Toxic solid, organic, n.o.s. (P-Bromoaniline Fluoroacetate)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: I (high danger)
Marine Pollutant: Yes
Transport Labels: Toxic, Marine Pollutant
Special Precautions: Only trained personnel should manage transport; use secure, sealed containers clearly marked with hazard class; emergency contact details with shipment
International Inventories: Not listed on US TSCA, EU EINECS, or Japanese ENCS inventories as of publication
Regulatory Status: Subject to workplace safety oversight for handling of acute toxins under OSHA and national equivalents
Labeling Requirements: GHS/CLP hazard symbols, precautionary and response phrases
Restrictions: Professional use only; not for food, drug, or household applications
Key Legislation: Listed under European Regulation (EC) No. 1907/2006 (REACH) as “very high concern,” with possible additional local regulatory measures for synthesis and import/export
