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Material Safety Data Sheet for Nitroacenaphthene

Identification

Product Name: Nitroacenaphthene
Chemical Name: 1-Nitroacenaphthene
Synonyms: Nitroacenaphthene, 1-Nitroacenaphthylene
CAS Number: 3217-98-7
Molecular Formula: C12H7NO2
Manufacturer: [Company Name/Contact]
Emergency Contact: [Emergency Phone Number]
Recommended Use: Laboratory chemicals, chemical synthesis, research

Hazard Identification

Classification: Possible carcinogen, toxic if inhaled, harmful if swallowed or upon skin contact
GHS Label Elements: Danger
Pictograms: Skull and crossbones, health hazard
Signal Word: Danger
Hazard Statements: May cause cancer, causes damage to organs through prolonged or repeated exposure, toxic to aquatic life with long lasting effects
Precautionary Statements: Do not breathe dust/fume/gas/mist/vapors/spray, wear protective gloves/protective clothing/eye protection/face protection, avoid release to the environment, wash hands thoroughly after handling

Composition / Information on Ingredients

Chemical: 1-Nitroacenaphthene
CAS Number: 3217-98-7
Concentration: 98% or greater
Impurities: Trace organic substances, non-hazardous byproducts below 2%

First Aid Measures

General Advice: Remove from exposure, keep patient calm, seek medical assistance
Inhalation: Move to fresh air without delay, support breathing if required, seek immediate medical attention
Skin Contact: Wash thoroughly with soap and plenty of water for at least 15 minutes, remove contaminated clothing, seek medical help if irritation persists
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, consult an eye specialist
Ingestion: Rinse mouth with water, do not induce vomiting, never give anything by mouth to an unconscious person, get medical help right away

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, water mist if available
Specific Hazards: Emits toxic fumes under fire conditions, including oxides of nitrogen and carbon
Protective Equipment: Self-contained breathing apparatus and full personal protective equipment required for firefighters
Precautions: Evacuate personnel, prevent contamination of water sources, cool containers exposed to fire with water spray

Accidental Release Measures

Personal Precautions: Use personal protective gear including respiratory mask, protective goggles, gloves, chemical-resistant clothing
Environmental Precautions: Prevent spillage from entering waterways, sewers, basements, or confined areas
Cleanup Methods: Collect with inert absorbent material, sweep or scoop carefully, place in suitable container for disposal, ventilate affected area
Decontamination: Wash spill site thoroughly once cleanup finished, avoid dust formation

Handling and Storage

Handling: Handle in a fume hood to minimize inhalation risk, avoid generating dust, use only with adequate ventilation, avoid skin and eye contact, wash hands and face after handling
Storage: Store in tightly closed original container, in a cool, dry, well-ventilated area away from incompatible substances such as strong oxidizers, bases, acids, keep away from sources of ignition, protect from light and moisture

Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific limits established, minimize exposure through best practices
Engineering Controls: Laboratory fume hood, local exhaust ventilation
Respiratory Protection: Approved respirator if available, use if exposure limits might be exceeded
Skin Protection: Wear chemical-resistant gloves such as nitrile, lab coat or protective clothing
Eye Protection: Safety goggles that meet ANSI standards or face shield
Hygiene Measures: Remove contaminated clothing, avoid eating, drinking or smoking in work area, wash thoroughly before breaks and after use

Physical and Chemical Properties

Appearance: Yellow to orange crystalline solid
Odor: No distinct odor
Odor Threshold: Not determined
pH: Not applicable
Melting Point: 144–146°C
Boiling Point: Data not available
Flash Point: Above 200°C
Flammability: Not readily flammable, but combustible
Vapor Pressure: Low at room temperature
Vapor Density: Not determined
Solubility: Sparingly soluble in water, soluble in organic solvents like acetone and benzene
Partition Coefficient (log Kow): Not available
Decomposition Temperature: May decompose at higher temperatures to release toxic gases
Viscosity: Not applicable for solid

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Conditions to Avoid: Exposure to heat, sparks, open flame, direct sunlight, moisture
Incompatible Materials: Strong oxidizers, strong bases, strong acids
Hazardous Decomposition Products: Oxides of carbon, oxides of nitrogen, potentially toxic organic fumes
Polymerization: No hazardous polymerization expected under normal conditions

Toxicological Information

Routes of Exposure: Inhalation, ingestion, skin contact, eye contact
Acute Toxicity: Harmful if inhaled or ingested, may cause irritation to skin, eyes, and respiratory tract
Chronic Toxicity: Suspected carcinogen based on studies of similar compounds, may cause organ damage through repeated exposure
Symptoms of Exposure: Headache, dizziness, nausea, coughing, skin redness, eye discomfort
Sensitization: Not fully assessed, possible based on structure
Mutagenicity: Some evidence from animal studies, further research required
Carcinogenicity: Classified as possibly carcinogenic by analog structure, not listed by IARC, OSHA, NTP specifically
Reproductive Toxicity: No reliable data available
Target Organs: Lungs, liver, kidneys

Ecological Information

Aquatic Toxicity: Toxic to aquatic organisms, possible long-term adverse effects on aquatic environment
Persistence and Degradability: May persist in the environment, presumed limited biodegradation based on structure
Bioaccumulation Potential: Possible potential due to molecular size and hydrophobicity
Mobility in Soil: Limited mobility, binds to organic matter
Other Hazards: No known significant effects other than listed, lack of thorough environmental data due to limited use

Disposal Considerations

Disposal Methods: Dispose of contents and container in accordance with local, state, and federal environmental regulations
Contaminated Packaging: Empty containers should be handled as hazardous waste, triple rinse before disposal if possible
Waste Treatment: Accredited hazardous waste processor for incineration, do not pour down drain or release to environment
Precautions: Prevent environmental contamination, do not mix with other waste streams unless advised by disposal facility

Transport Information

UN Number: Not allocated
UN Proper Shipping Name: Not assigned, transport under laboratory or research compounds regulations
Transport Hazard Class: Not specifically classified but handle as hazardous
Packing Group: Not established, use strong secondary containment
Marine Pollutant: Yes, do not transport with food or animal feed products
Special Precautions: Ensure upright transport, package to avoid spillage or breakage, label as toxic solid organic substance in absence of specific shipping class

Regulatory Information

TSCA (Toxic Substances Control Act): Checked for inclusion, may not be listed due to specialty nature
EINECS/ELINCS: May require notification for use in Europe
SARA Title III: Not specifically listed under extremely hazardous or reportable substances
OSHA: No specific PEL, but general duty clause applies for workplace safety
California Proposition 65: Not explicitly listed, use as though covered by carcinogen and toxicant warnings
Other National Regulations: Subject to chemical safety and health regulations in country of use, consult local laws prior to use, handling, or disposal