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Product Name: Nickel Nitrite
Chemical Formula: Ni(NO2)2
CAS Number: 13478-00-7
Synonyms: Nickel dinitrite, Nickelous nitrite
Recommended Use: Research, chemical synthesis
Supplier Details: Contact details from supplier label
Emergency Contact: Emergency phone number as supplied on original label
Classification: Oxidizing solid, Acute toxicity (oral/inhalation), Skin and eye irritant, Suspected carcinogen, Environmental hazard
GHS Label Elements: Flame over circle, Skull and crossbones, Exclamation mark, Health hazard, Environment
Signal Word: Danger
Hazard Statements: May intensify fire (oxidizer); Toxic if swallowed or inhaled; Causes skin irritation; Causes serious eye damage; Suspected of causing cancer; Very toxic to aquatic life
Precautionary Statements: Avoid breathing dust or vapors; Wear protective gloves, eye protection and face protection; Store away from heat/sparks/open flames; Do not release to the environment
Chemical Name: Nickel Nitrite
Common Name: Nickel nitrite
Concentration: 100%
CAS Number: 13478-00-7
Other Components: No significant impurities contributing to hazard
Inhalation: Move person to fresh air, keep at rest, seek medical attention for persistent symptoms
Skin Contact: Wash thoroughly with soap and water, remove contaminated clothing
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present, continue rinsing, seek medical care
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical attention
Key Symptoms: Irritation, cough, redness, nausea, difficulty breathing
Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Do not use dry combustible materials for extinguishing
Hazards from Combustion: Emits toxic fumes of nitric oxides and nickel compounds
Protective Equipment: Firefighters should wear self-contained breathing apparatus and protective suit
Additional Considerations: Cool containers exposed to fire with water spray
Special Hazards: Compound supports combustion and intensifies fire if in contact with flammable material
Personal Precautions: Evacuate area, use personal protective equipment including respiratory protection
Environmental Precautions: Prevent release into drains, surface waters and soil
Containment: Sweep up avoiding dust formation, collect in closed container for disposal
Clean-Up Methods: Wash area with plenty of water after material removal
Handling: Use in well-ventilated areas, avoid contamination with combustible materials, keep away from heat and open flames, avoid contact with eyes, skin and clothing
Hygiene Measures: Wash hands after handling and before eating or drinking
Storage: Store in tightly closed containers away from combustible substances, acids and bases, in a cool, dry place with access restricted to trained personnel
Incompatible Materials: Strong acids, reducing agents, organic materials, flammable materials
Occupational Exposure Limits: Nickel compounds (as Ni): OSHA PEL 1 mg/m³ TWA (inhalable), ACGIH TLV 0.1 mg/m³ TWA (inhalable)
Engineering Controls: Use local exhaust ventilation and safety shower and eyewash stations near work area
Personal Protection: Respiratory protection, chemical-resistant gloves, lab coat, protective goggles, face shield as applicable
Environmental Controls: Avoid emissions to the environment, use appropriate waste collection measures
Appearance: Yellow to greenish crystalline powder
Odor: Odorless
pH: Not available
Melting Point: Decomposes before melting
Boiling Point: Not applicable
Flash Point: Nonflammable (oxidizer)
Solubility: Soluble in water
Vapor Pressure: Not available
Relative Density: Approx. 2.9 g/cm³
Partition Coefficient: Not available
Auto-ignition Temperature: Not applicable
Chemical Stability: Stable under regular storage conditions
Thermal Decomposition: Produces toxic gases including nitrogen oxides and nickel oxides
Conditions to Avoid: Excessive heat, moisture, contact with combustible and reducing materials
Incompatible Materials: Acids, organic substances, strong reducing agents, flammable materials
Hazardous Decomposition Products: Nitrogen oxides, nickel compounds
Acute Toxicity: Harmful if swallowed or inhaled; may cause nausea, vomiting, abdominal pain, sore throat, cough, shortness of breath
Skin Corrosion/Irritation: Causes skin irritation; redness and discomfort possible with prolonged contact
Serious Eye Damage/Irritation: Causes serious eye irritation or damage
Respiratory Sensitization: May cause allergic respiratory reaction
Carcinogenicity: Nickel compounds classified as Group 1 (carcinogenic to humans) by IARC
Mutagenicity: Evidence of mutagenic effects in laboratory settings
Target Organ Effects: Lungs, nasal cavity, skin
Chronic Effects: Prolonged exposure may result in nickel sensitization, dermatitis, asthma, increased cancer risk
Aquatic Toxicity: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Mobility in Soil: Relatively mobile in aqueous environment; risk of leaching into groundwater
Persistence and Degradability: Not readily biodegradable; nickel ions persist in environment
Bioaccumulation: Potential for bioaccumulation in aquatic organisms
Other Adverse Effects: Nickel compounds threaten aquatic and soil life, disrupt food chains
Waste Treatment Methods: Dispose as hazardous waste through licensed disposal company
Contaminated Packaging: Treat empty containers as hazardous waste, do not reuse
Special Precautions: Avoid release to sewer or water course; follow local, regional and national regulations
Safe Handling of Waste: Use approved containers, ensure proper labeling and documentation
UN Number: UN2727
UN Proper Shipping Name: NITRITES, INORGANIC, N.O.S. (Nickel nitrite)
Transport Hazard Class: 5.1 (Oxidizer)
Packing Group: II
Environmental Hazards: Marine pollutant
Special Precautions: Segregate from foodstuffs, combustibles, acids; keep container upright and secure during transport
Regulations: Compliant with IMDG, IATA, ADR transport guidelines
OSHA: Classified as hazardous, listed under specific exposure limits for nickel compounds
TSCA: Listed in U.S. Toxic Substance Control Act inventory
SARA Title III: Subject to reporting requirements under sections 302/313 due to acute and chronic health hazards
EPA: Listed as hazardous under RCRA; constituent of concern for air and water emissions
WHMIS (Canada): Classified as chemical hazard, subject to mandatory labeling requirements
REACH/CLP (EU): Registered; hazard pictograms and statements required under EU GHS/CLP
Other Regulations: Included on relevant state and international chemical control lists, subject to occupational exposure reporting and pollution control measures
