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Product Name: Nickel Nitrate
Chemical Formula: Ni(NO3)2·6H2O
Synonyms: Nickel(II) Nitrate Hexahydrate
CAS Number: 13478-00-7
Recommended Use: Used in electroplating, as a chemical reagent, and in catalysts for laboratory and industrial processes
Manufacturer Information: Full name and contact details, including addresses and emergency phone numbers
Emergency Phone Number: Local poison control center, company emergency contact
GHS Classification: Acute Toxicity - Oral (Category 4); Skin Sensitizer (Category 1); Carcinogen (Category 1A); Eye Irritation (Category 2A); STOT - Repeated exposure (Category 2); Aquatic Acute (Category 1); Aquatic Chronic (Category 1)
Signal Word: Danger
Hazard Statements: May cause allergic skin reaction, suspected of causing cancer, causes serious eye irritation, toxic if swallowed, toxic to aquatic life with long lasting effects
Pictograms: Skull and crossbones, exclamation mark, health hazard, environment
Precautionary Statements: Avoid breathing dust or fumes, wear protective gloves and eye protection, wash skin thoroughly after handling, do not eat or drink while using, avoid release to waterways
Target Organs: Lungs, kidneys, respiratory tract, skin
Component: Nickel Nitrate Hexahydrate
Chemical Formula: Ni(NO3)2·6H2O
CAS Number: 13478-00-7
Concentration: Greater than 98% by weight
Impurities: Typically contains trace elements from manufacturing, but majority present as stated above
If Inhaled: Remove to fresh air, seek medical attention if symptoms continue, keep at rest in position comfortable for breathing
If on Skin: Take off contaminated clothing, immediately wash with soap and plenty of water, get medical advice if irritation continues
If in Eyes: Rinse cautiously with water for several minutes, remove contact lenses if possible, continue rinsing, seek medical attention
If Swallowed: Rinse mouth, do not induce vomiting, drink plenty of water if conscious, get medical attention immediately
Important Symptoms: Allergic reactions, coughing, skin rash, eye discomfort, gastrointestinal distress
Immediate Medical Attention Needed: In cases of respiratory distress, persistent burning or severe allergic reactions
Suitable Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam
Unsuitable Media: Do not use water jets directly on burning product
Specific Hazards: Product supports combustion; releases toxic nitrogen oxides and nickel compounds on heating; may intensify fire due to oxidizer content
Special Protective Equipment for Firefighters: Full face mask and self-contained breathing apparatus
Firefighting Instructions: Remove product from fire area if it can be done safely, cool containers with water spray
Personal Precautions: Use personal protective equipment, avoid dust formation, ventilate area
Environmental Precautions: Prevent further leakage or spillage if safe; keep product out of drains and surface water
Cleanup Methods: Collect spillage, scoop up carefully avoiding dust, place in a suitable container for disposal, clean contaminated area thoroughly
Decontamination: Wash area with plenty of water, ensure all residues are removed, dispose as hazardous waste according to regulations
Advice for Emergency Responders: Use chemical resistant gloves, eyewear, respiratory protection if ventilation is poor
Precautions for Safe Handling: Use only in well-ventilated areas, avoid contact with eyes, skin, and clothing, prevent formation of dust
Incompatible Materials: Reducing agents, easily oxidizable materials, combustibles
Handling Practices: Wear gloves, goggles, and a lab coat, keep container tightly closed when not in use, use tools and equipment resistant to corrosion by nitrates
Storage Conditions: Store in a cool, well-ventilated place, away from heat and direct sunlight, keep away from incompatible materials, store containers upright and tightly closed
Storage Containers: Use containers made from glass, polyethylene, or other materials resistant to corrosion
Control Parameters: Nickel compounds OSHA PEL - 1 mg/m³ (8-hour TWA, as nickel), NIOSH REL – 0.015 mg/m³ (as Ni), ACGIH TLV – 0.1 mg/m³ (inhalable fraction)
Engineering Controls: Local exhaust ventilation, safety showers, eyewash stations
Personal Protective Equipment: Chemical splash goggles, nitrile or rubber gloves, protective clothing resistant to chemicals, suitable respiratory protection for dust
Hygiene Measures: Wash hands before breaks, after handling, and at end of work; avoid inhalation and ingestion; remove contaminated clothing before eating or leaving area
Appearance: Green crystalline solid
Odor: Odorless
Melting Point: 56.7°C (decomposes)
Solubility: Very soluble in water
pH (aq solution): Slightly acidic
Boiling Point: Decomposes before boiling
Vapor Pressure: Not applicable (solid at room temperature)
Density: About 2.05 g/cm³
Molecular Weight: 290.81 g/mol (hexahydrate form)
Flash Point: Not flammable as a solid, but can enhance burning of combustible materials
Other Properties: Hygroscopic, oxidizing, decomposes on heating emitting toxic gases
Chemical Stability: Stable under recommended storage and handling conditions; decomposes with heat
Reactivity: Acts as a strong oxidizer; increases risk of fire in contact with combustibles
Conditions to Avoid: High temperatures, exposure to moisture, contact with reducing agents or flammable materials
Hazardous Decomposition Products: Nitrogen oxides, nickel oxides
Incompatible Substances: Strong acids, strong reducing agents, flammable materials, powdered metals, organic solvents
Routes of Exposure: Inhalation, ingestion, skin contact, eye contact
Acute Toxicity: Ingestion or inhalation may cause severe irritation, nausea, diarrhea, headache, malaise, and in larger exposures possible damage to kidneys and lungs
Chronic Toxicity: Prolonged contact may sensitise skin or respiratory tract, known human carcinogen (IARC Group 1), can cause allergic skin reactions, potential to harm respiratory and renal function after repeated exposure
Symptoms on Exposure: Rash, itching, asthma-like symptoms, eye redness, swelling of mouth and throat, difficulty breathing in severe cases
Carcinogenicity: Classified as carcinogenic to humans based on sufficient evidence linking nickel compounds with lung and nasal cancer
Reproductive Toxicity: Some animal studies suggest possible reproductive risks; no conclusive human data, so caution advised
Additional Effects: Some individuals may experience severe allergic reactions or heightened sensitivity from repeated contact
Toxicity to Aquatic Life: Very toxic to aquatic life, causes long-lasting harmful effects in water systems and soil due to nickel ion persistence
Bioaccumulation Potential: Nickel can build up in aquatic organisms, leading to higher concentrations up the food chain
Mobility in Soil: Nickel nitrate is soluble and readily travels with water through soil, reaching groundwater
Degradability: Substance does not degrade easily in environment; increases risk of spreading contamination
Other Ecological Concerns: Chronic nickel contamination can impact growth, reproduction, and survival rates in fish, algae, and aquatic invertebrates
Waste Treatment Methods: Handle as hazardous waste, never dispose in environment or general trash
Disposal Containers: Use tightly closed, labeled containers suitable for chemical waste
Precautions: Wear full personal protective equipment during spill cleanup and waste handling
Recommended Disposal: Consult licensed hazardous waste disposal company; follow local, state, and federal regulations; treatment processes often involve solidification or chemical reduction
Contaminated Packaging: Dispose of contaminated packaging as hazardous waste; do not reuse without proper decontamination
UN Number: 2725
UN Proper Shipping Name: Nickel Nitrate
Transport Hazard Class: 5.1 (Oxidizing Substances)
Packing Group: III
Environmental Hazards: Yes, dangerous to environment
Transport Labels: Oxidizer, Environmentally Hazardous
Transport Precautions: Prevent package leaks, keep separate from flammables and reducing agents, ensure all personnel handling material trained in hazard management
Special Precautions: Emergency response and spill kits required in transport vehicles; driver must be aware of product hazards
Carcinogen Status: Regulated as a carcinogen by OSHA, NTP, IARC
TSCA Status: Listed on the Toxic Substances Control Act inventory
SARA Title III: Subject to reporting under emergency planning and community right-to-know sections
European Regulations: Classified under CLP; subject to REACH registration and restrictions
WHMIS: Classified as Class D2A (Very toxic, carcinogenic), Class D2B (Toxic), Class C (Oxidizer)
Other Relevant Regulations: Subject to national, regional, and local environmental and workplace exposure limits; users must ensure compliance with all applicable legislation and guidance
