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Product Name: N-Propyl Bromoacetate
Chemical Formula: C5H9BrO2
CAS Number: 35223-80-4
Recommended Use: Laboratory chemical, reagent, organic synthesis
Supplier: Reliable chemical distributors and laboratory suppliers
Contact Information: Detailed contact information for technical questions and emergencies
Synonyms: 2-Bromoacetic acid n-propyl ester, Propyl 2-bromoacetate, Propyl bromoacetate
Emergency Contact: Number for 24-hour emergency response and poison control
Hazard Classification: Acute toxicity (oral and inhalation), Skin and eye irritation
Signal Word: Danger
Hazard Statements: Harmful if swallowed, causes skin irritation, causes serious eye damage, toxic if inhaled
Pictograms: Exclamation mark, health hazard
Precautionary Statements: Wash hands thoroughly after handling, use only outdoors or in well-ventilated area, avoid breathing dust, fumes, gas, mist, vapors, or spray, wear protective gloves, eye protection, and face protection
Other Hazards: Vapors can irritate respiratory tract, contact may produce burns or blistering, persistent in environment
Chemical Identity: N-Propyl Bromoacetate
Concentration: ≥98% by weight
Impurities: Trace amounts of unreacted starting materials, solvents
Molecular Weight: 181.03 g/mol
Component List: Only one constituent considered hazardous at significant levels in normal use
General Advice: Avoid contact, seek medical attention in all cases of significant exposure
Inhalation: Remove to fresh air, assist breathing if needed, call medical services
Skin Contact: Remove contaminated clothing, rinse skin with plenty of water for at least fifteen minutes, seek medical help
Eye Contact: Flush eyes immediately with plenty of water for at least fifteen minutes, hold eyelids apart, get medical help
Ingestion: Rinse mouth, do not induce vomiting, give water to drink if conscious, get immediate medical attention
Most Important Symptoms: Coughing, burning sensation, abdominal pain, severe tissue irritation
Note to Physicians: Provide symptomatic and supportive care, monitor for respiratory distress
Suitable Extinguishing Media: Carbon dioxide, dry chemical, foam, avoid water in direct jet
Hazards Arising: Releases toxic gases such as hydrogen bromide, carbon dioxide, carbon monoxide
Protective Equipment: Self-contained breathing apparatus, full protective suit
Advice for Firefighters: Control run-off to prevent environmental contamination, stay upwind, evacuate surrounding areas when necessary
Fire Hazard: May form flammable vapors with air at elevated temperatures, avoid heat and open flame
Unusual Fire Hazards: Containers may explode under fire conditions
Personal Precautions: Wear chemical-resistant gloves, goggles, protective clothing, use breathing apparatus if risk of inhalation exists
Environmental Precautions: Prevent further leakage, do not allow product to enter drains, surface water, or soil
Methods for Cleaning Up: Absorb spill with inert material such as sand or vermiculite, scoop up and place in closed, labeled waste containers, ventilate area
Cleanup Crew Protection: Proper PPE for all involved in spill response, monitor area for vapors
Decontamination: Wash area with plenty of water following removal of bulk material, dispose cleanup materials as hazardous waste
Precautions for Safe Handling: Use with local exhaust ventilation, keep containers tightly closed, avoid splashes and generation of aerosols, transfer and handle in chemical fume hood
Safe Storage Conditions: Store away from direct sunlight, heat sources, acids, bases, oxidizers, keep container tightly closed in cool, dry, well-ventilated place
Incompatibilities: Strong bases, strong acids, oxidizing agents
Packaging Materials: Use amber glass or compatible chemical-resistant containers
Hygiene Practices: Wash hands and face after handling, avoid eating, drinking, or smoking in work areas
Engineering Controls: Chemical fume hood, safety shower, eyewash stations, good general ventilation
Occupational Exposure Limits: No established regulatory limits, minimize exposure as much as possible
Personal Protective Equipment: Chemical-resistant gloves, safety goggles, face shield, lab coat, respirator (if proper ventilation is not available)
Respiratory Protection: NIOSH or EN-approved respirator for organic vapors when vapors are present above recommended levels
Hand and Eye Protection: Impervious gloves (nitrile or neoprene), approved eye protection with side shields
Environmental Controls: Avoid discharge into environment, use containment if possible
Appearance: Colorless to pale yellow liquid
Odor: Pungent, characteristic
Odor Threshold: Not readily available
pH: Not applicable (pure substance)
Boiling Point Range: Approximately 185–190°C
Melting Point: Below -10°C
Flash Point: Above 61°C (closed cup)
Flammability: Not highly flammable, can emit toxic vapors when heated
Vapor Pressure: Moderate at room temperature
Solubility: Slightly soluble in water, soluble in organic solvents
Density: ~1.5 g/cm³ at 20°C
Partition Coefficient (Log Kow): Estimated moderate
Decomposition Temperature: Decomposes above 220°C releasing hazardous gases
Chemical Stability: Stable under recommended storage conditions
Reactivity: Reacts with strong bases and nucleophiles
Conditions to Avoid: Excessive heat, open flame, static discharge, moisture
Incompatible Materials: Strong oxidizing agents, strong bases, acids, amines, metal powders
Hazardous Decomposition Products: Hydrogen bromide, carbon monoxide, carbon dioxide, irritating fumes
Polymerization: Not anticipated under normal conditions
Routes of Exposure: Inhalation, skin absorption, ingestion, eye contact
Acute Toxicity: Harmful if swallowed or inhaled, may cause burns to skin and eyes
Chronic Effects: Prolonged exposure can result in respiratory tract, kidney, or liver damage
Symptoms: Burning sensations, cough, lung irritation, nausea, vomiting, dizziness, eye and skin burns
Carcinogenicity: No specific data, not listed by IARC, NTP, OSHA
Mutagenicity: Data not available
Reproductive Toxicity: Not assessed
Other Data: Potential for cumulative effects with repeated exposure, risk of chemical burns on skin
Toxicity to Aquatic Life: Moderately toxic to aquatic organisms, risk of bioaccumulation
Persistence/Degradability: Not readily biodegradable, may persist in environment
Bioaccumulative Potential: Moderate to high potential due to chemical structure
Mobility in Soil: Moderate mobility, limited by low solubility in water
Other Harmful Effects: Vapor and waterborne releases can harm aquatic ecosystems and disrupt biological processes
Advice: Release to the environment should be avoided, proper containment for spills is essential
Waste Methods: Dispose as hazardous chemical waste in accordance with local, state, and federal regulations
Containers: Rinse emptied containers with compatible solvent, triple rinse, and puncture before disposal or recycling
Recommended Disposal: Incineration at licensed facility, do not discharge to sewer or surface water
Contaminated Packaging: Treat as hazardous waste, label and handle in line with chemical waste guidelines
Regulatory Compliance: Ensure documentation for waste transfer, keep safety records for audits
UN Number: UN 2810
Proper Shipping Name: Toxic liquid, organic, n.o.s. (contains N-Propyl Bromoacetate)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: III
Labels Required: Toxic, environmental hazard as appropriate
Transportation Modes: Land, air, sea—confirm all packaging meets DOT, IATA, IMO guidelines
Special Precautions: Use sealed containers, avoid loading with incompatible goods
Inventories: Listed in TSCA (United States), REACH (EU), DSL (Canada) with reporting required
Hazard Categories: Immediate health hazard, delayed health hazard, environmental hazard
Labeling Requirements: GHS hazard label, precautionary codes, pictograms
SARA Title III: Immediate (acute) health hazard
Right-to-Know Listings: Subject to state-specific chemical safety disclosures
Workplace Labelling: Clear hazard communication per OSHA, WHMIS, CLP regulations
Further Regulation: Restrictions may exist for transport, storage, and use in some jurisdictions—check with local agencies regularly for updates
