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Product Name: N-Propyl Acetate
Chemical Formula: C5H10O2
Synonyms: 1-Acetoxypropane, Propyl Acetate, Acetic Acid N-Propyl Ester
CAS Number: 109-60-4
Recommended Use: Solvent for coatings, inks, fragrances
Supplier Information: Company details can be found on the label and shipping paperwork
Emergency Phone Number: Refer to local poison control center or on-site safety emergency contact
Classification: Flammable liquid and vapor (Category 2); Eye irritation (Category 2A); Specific target organ toxicity, single exposure (Category 3)
GHS Label Elements: Pictogram: Flame, Exclamation mark; Signal Word: Danger
Hazard Statements: Highly flammable liquid and vapor; Causes serious eye irritation; May cause drowsiness or dizziness
Precautionary Statements: Keep away from heat and sparks; Store in a well-ventilated place; Wear protective gloves and eye protection; If inhaled, move to fresh air and keep at rest; IF ON SKIN: Wash thoroughly with soap and water
Chemical Name: N-Propyl Acetate
Concentration: 99% or above
CAS Number: 109-60-4
Impurities: Trace amounts of other esters and alcohols may be present depending on production process
Stabilizers/Additives: None commonly added for standard industrial use
Inhalation: Remove to fresh air at once; If symptoms continue, seek medical advice; Provide oxygen if breathing is difficult
Skin Contact: Wash skin thoroughly with soap and water; Remove contaminated clothing
Eye Contact: Rinse eyes carefully with plenty of water for at least 15 minutes, lifting eyelids occasionally; If irritation persists, consult a physician
Ingestion: Do not induce vomiting; Rinse mouth with water; Seek medical attention immediately
Most Important Symptoms: Eye irritation, coughing, dizziness, headaches
Immediate Medical Attention: Needed for severe exposures by inhalation or ingestion
Suitable Extinguishing Media: Use dry chemical, CO2, alcohol-resistant foam, or water spray
Unsuitable Extinguishing Media: Do not use strong water jets as the liquid floats on water and may spread fire
Fire Hazards: Vapor forms explosive mixtures with air, can travel to ignition sources and flash back
Special Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Specific Methods: Use water spray to cool containers exposed to flames; Remove containers from fire area if safe
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, and possibly acetic acid may form in a fire
Personal Precautions: Evacuate non-essential personnel; Ensure adequate ventilation; Avoid breathing vapors
Protective Equipment: Gloves, eye protection, respirator if needed
Environmental Precautions: Prevent spillage from entering drains, waterways, or soil
Methods for Clean-up: Contain and collect spilled liquid with non-combustible absorbent materials like sand or earth, transfer to proper containers for disposal
Decontamination: Wash spill area thoroughly after material pickup
Precautions for Safe Handling: Avoid inhaling vapor and contact with skin and eyes; No smoking, flames, or sparking tools; Use with proper ventilation and grounded equipment to prevent static discharge
Storage Conditions: Store in tightly closed, clearly labeled containers; Keep in cool, dry, well-ventilated area, away from sources of ignition and incompatible materials
Incompatible Materials: Strong oxidizers, acids, bases
Special Requirements: Static-free tools, bonding and grounding procedures for containers and equipment
Hygiene Measures: Wash hands thoroughly after handling; Do not eat or drink in work area
Control Parameters: TLV (ACGIH): 200 ppm; STEL: 250 ppm
Engineering Controls: Local exhaust ventilation, explosion-proof equipment
Personal Protective Equipment: Goggles or face shield, chemical-resistant gloves, flame-resistant clothing
Respiratory Protection: Use an approved respirator if exposure limits are exceeded or if ventilation is inadequate
Environmental Exposure Controls: Prevent leaks and spills; Use closed systems
Monitoring: Regular workplace air monitoring recommended
Appearance: Clear, colorless liquid
Odor: Pleasant, fruity odor resembling pears
Odor Threshold: Approximately 0.18 ppm
pH: Not applicable
Melting Point/Freezing Point: -92°C
Boiling Point: 101°C
Flash Point: 15°C (open cup), 20°C (closed cup)
Evaporation Rate: 1.0 (butyl acetate = 1)
Flammability: Highly flammable liquid
Explosive Limits: Lower: 1.7%, Upper: 8.0% (by volume in air)
Vapor Pressure: 24 mmHg at 20°C
Vapor Density: 3.9 (air = 1)
Relative Density: 0.888 (water = 1)
Solubility in Water: 2.3 g/100 ml at 25°C
Partition Coefficient (n-octanol/water): Log Pow 1.2
Auto-ignition Temperature: 460°C
Decomposition Temperature: Not available
Viscosity: 0.7 mPa.s at 25°C
Molecular Weight: 102.13 g/mol
Stability: Stable under standard temperature and pressure, sealed storage with proper precautions
Reactivity: Ignites in the presence of strong oxidizers; Can form peroxides after extended storage
Hazardous Reactions: May react violently with nitric acid, sulfuric acid, and strong bases
Conditions to Avoid: Heat, flames, sparks, static electricity, incompatible materials
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrid smoke in fire
Polymerization: Not known to occur
Incompatibility: Metals, oxidizers, some plastics may weaken with prolonged exposure
Acute Toxicity: Oral LD50 (rat): 8,750 mg/kg; Inhalation LC50 (rat, 4 hr): 16,000 ppm
Skin Corrosion/Irritation: Mildly irritating
Serious Eye Damage/Irritation: Causes eye irritation
Respiratory Sensitization: Vapors can cause drowsiness, headaches
Skin Sensitization: Not typically sensitizing
Germ Cell Mutagenicity: Not classified as mutagenic
Carcinogenicity: Not listed as carcinogenic (IARC, NTP, OSHA)
Reproductive Toxicity: No evidence found in animal studies
Specific Target Organ Toxicity (Single Exposure): Transient effects on central nervous system
Specific Target Organ Toxicity (Repeated Exposure): Not established
Aspiration Hazard: May be harmful if swallowed and enters airways
Ecotoxicity: Harmful to aquatic organisms at high concentrations; LC50 (Fish, 96 hr): 74 mg/L; EC50 (Daphnia, 48 hr): 350 mg/L
Persistence and Degradability: Readily biodegradable in soil and aquatic environments
Bioaccumulation Potential: Expected to have low potential (Log Kow 1.2)
Mobility in Soil: High mobility due to water solubility
Other Adverse Effects: Volatile, may contribute slightly to formation of atmospheric ozone under certain conditions
Waste Treatment Methods: Incinerate under controlled conditions in accordance with federal, state, and local regulations
Container Disposal: Rinse thoroughly, then recycle or dispose in compliance with legal requirements for hazardous waste
Special Precautions: Do not allow undiluted product or large quantities to reach wastewater or open water systems; Waste handlers should use personal protective equipment
Disposal of Packaging: Empty containers may retain vapors; handle and dispose with caution
UN Number: UN1276
Proper Shipping Name: n-Propyl Acetate
Transport Hazard Class: 3 (Flammable Liquid)
Packing Group: II
Labels Required: Flammable Liquid
Marine Pollutant: No
Special Precautions for Transport: Keep away from heat, open flames, properly label all containers, ensure container integrity
Additional Notes: Consult regulations for air, sea, and ground transport for further instructions
Safety, Health and Environmental Regulations: Listed on TSCA, AICS, DSL, EINECS/ELINCS, ENCS inventories
SARA Title III, Sections 311/312: Fire hazard, Acute health hazard
SARA Title III, Section 313: Not subject to reporting
California Proposition 65: Not listed
OSHA: Classified as hazardous chemical
WHMIS Classification (Canada): B2 – Flammable Liquid, D2B – Toxic Material
Chemical Safety Assessment: Safety assessment available on request from manufacturer
