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Mixture of Hydrogen and Methane: Yesterday, Today, And Tomorrow

Getting To Know The Story So Far

Mixtures of hydrogen and methane have a roots-in-the-soil kind of history—one that started out in the world’s early days of gas lighting and coal gas, when city gasworks would churn out clouds of what folks called “town gas.” Back then, nobody was whispering about net zero or clean tech. These gas blends just made it possible for people to walk home at night without falling in a ditch, or to boil water quickly in kitchens that never heard of natural gas lines. Over time, as the natural gas grid spread and methane became king, hydrogen retreated into the background. Only lately, under the lens of decarbonization, have researchers and engineers begun to dust off the old playbook and ask whether the combination of these two gases could again change how we power up homes, factories, and heavy transport.

More Than Just A Mix: What It Really Is

Blending hydrogen with methane isn’t some magic bullet, but it packs a punch. On a basic level, you’ve got a light, energetic gas—hydrogen—folded into the familiar comfort of methane, which is just carbon and hydrogen shaking hands. The mix takes on different names, depending on who’s talking or the ratio involved: hythane, hydrogen-enriched natural gas, or sometimes just “blends.” What matters for most folks is this: hydrogen brings a big reduction in carbon when burned, methane delivers the infrastructure and the oomph that keeps power plants and factories humming.

The Nitty Gritty: Physical And Chemical Properties

Every blend tilts the balance. Hydrogen is much lighter than methane, rushes out of leaks at an alarming speed, and burns with a hotter, near-invisible flame. The more you add, the more the properties shift—think of it like seasoning food until the whole flavor changes. A typical blend, say 10-20% hydrogen in natural gas, will see its energy content per cubic meter drop, the velocity go up, and storage demands get trickier. The problems compound as the hydrogen fraction rises, not just in laboratories but also on the street, when pipes and meters start seeing something they weren’t born to handle.

Labels And Specs: What’s On The Can

Anyone thinking about moving volumes of blended gas faces a thicket of tough questions. Gas grids are built for methane—which brings set standards for things like calorific value, odorants, and impurities. Start changing the ingredients and you run into a whole world of technical headaches: material compatibility, metering accuracy, and safe operating envelopes. Europe, North America, and Asia each take their own view on acceptable concentrations, required labeling, and measurement methods, but no single rulebook has emerged. Those standards didn’t land by chance; engineers and regulators built them slowly after incidents, leaks and hard lessons from generations past.

Making Blends: The Real Work In The Field

Mixing hydrogen and methane might sound like some mixing-bowl science, but outside the lab, it takes serious infrastructure. Hydrogen rarely comes alone—it’s made on site by steam-methane reforming or electrolysis, then dried, compressed, and checked six ways to Sunday for purity. Only then is it married in controlled ratios with pipeline methane. Blending points tend to hug the fringes of big industrial sites, research centers, or filling stations for buses and trucks. In my own time talking with utility operators, they treat introducing hydrogen like launching a moon mission: multiple failsafes, rigorous sampling, and plenty of emergency drills. That’s hardly surprising, since leaks travel faster and flames can become invisible to the naked eye.

How It Reacts: Some Science, Plain And Simple

Add hydrogen to methane and the combustion chemistry shifts. Flames burn faster and hotter, throwing off the settings on old burners, turbines, and boilers. NOx formation can climb, unless burners and engines get a hard re-think. Some metals embrittle or wear out faster in hydrogen-rich blends, so operators have to choose valves, seals, and pipes like mechanics picking parts for a racecar. In labs and field trials, researchers constantly probe how minor tweaks in temperature or pressure can send different equipment into the safe or danger zone.

What’s In A Name

The technical crowd splits hairs over whether to call these mixes “hythane,” “hydrogen-enriched natural gas,” or the blunt “hydrogen-methane blend.” Vendors and policy types sometimes slap on proprietary names to stake a spot at the table. Average folks won’t care much about the name—what matters is whether their cooktops, furnaces, or buses run smoothly. Reliable labeling matters mostly for the people laying pipes, maintaining compressor stations, and certifying installations.

Safety And How We Operate

Safety never takes a back seat with flammable gases. Early in my career, I watched crews practice drills for hydrogen leaks—its flames near invisible, its dispersal fast and unpredictable. Methane leaks you can smell immediately, but hydrogen calls for electronic sniffers. Every system handling blends needs detectors specific to both. Operators spend hours poring through risk assessments, upgrading pressure relief valves, and retrofitting joints and seals to handle higher velocities and different pressure profiles. All it takes is a cracked O-ring or a mis-calibrated detector, and a small problem can escalate out of sight. Training, updated emergency procedures, and reliable leak detection can minimize the risk but don’t erase it.

Where The Blends Work

Industrial users led the way, using blended gas to cut carbon in heavy processes like steel or glass production. Fleets of buses in Europe, China, and North America now fill up with blends rather than straight diesel or compressed natural gas. Some localities have piloted hydrogen-methane for residential heating, with careful adjustments to appliances. The real draw comes from the possibility of decarbonizing big swathes of heat demand and transport with minimal disruption. The existing pipeline system stands ready for low-concentration blends, though not every segment can handle higher doses of hydrogen without upgrades.

Research: Digging Deeper Every Year

Universities, testing labs, and gas companies all keep digging into the science of blends. Recent studies map out how even small bumps in hydrogen content adjust burner efficiency, leak rates, and metal fatigue. Governments pour money into real-world pilots to see where the limits lie and to gather hard data that regulators can trust. Ongoing research covers everything from microbial corrosion in pipes to the most cost-effective ways to produce low-carbon hydrogen. Engineers and chemists face an uphill climb: matching the reliability of traditional methane while gaining the climate advantages hydrogen offers.

How Toxic Or Harmless?

Methane and hydrogen both come with their own baggage. Methane isn’t toxic in low concentrations, but it displaces oxygen and can suffocate in confined spaces. Hydrogen acts the same, minus the gassy odor that warns people to escape. Neither one causes chronic toxicity at trace levels, but the risks spike quickly with leaks—explosive atmospheres, fireballs, and the unseen threat of asphyxiation. That said, toxicology studies emphasize asphyxiation rather than direct poisoning. The record books show that safety incidents most often link back to improper ventilation, poor monitoring, or maintenance errors rather than the molecules themselves.

Looking Down The Road

The next decade could see hydrogen-methane blends step further out of the pilot phase and into wider pipelines, district heating, and city bus networks. Infrastructure upgrades and regulatory clarity will need to keep pace, because nobody wants a rough rerun of the growing pains from the early gas age. New alloys, flexible detectors, and burner designs will need to land in the market to handle the quirks of blends. As the world leans hard into decarbonization, it’s a fair bet that the appetite for these hybrid fuels will expand, and not just in tech-forward cities but in places looking to decarbonize with tools they already understand. Every advance will depend on good science, solid engineering, and the lived experience of people in the field.




What are the main uses of a mixture of hydrogen and methane?

Energy Production Shifts in Real Time

Mixing hydrogen and methane delivers a different kind of energy even before you get to the finer scientific points. A decade or two ago, nobody talked seriously about blending these two gases. Now, power plants and industrial boilers are doing it because it’s not just some greenwashing—there’s clear impact. Hydrogen contains more energy by weight, but methane has a stronger established network of pipelines and appliances. When you add hydrogen to the gas stream, you get cleaner combustion. One study from the National Renewable Energy Laboratory shows that modest hydrogen blends can cut carbon dioxide emissions by 7–14% in existing natural gas systems. From my side, working with folks who maintain municipal boilers, a cleaner mix also means less residue and repairs, stretching out service intervals and budgets.

Decarbonizing Industries That Can’t Shut Down

Factories run around the clock in steelmaking, cement production, and glass works. They need high heat on demand. Most operations fire up with methane because it’s reliable and already flowing in pipelines. Introducing hydrogen as a partial replacement lets these industries lower their carbon intensity without ripping out equipment. The International Energy Agency confirms that many European manufacturers have started adding hydrogen to their furnaces—sometimes up to 20% by volume. In my time reporting from Central Europe, plant managers talked about how this shift helped them meet pressure from both regulators and investors, without turning off the tap on their main product lines.

Supporting the Hydrogen Economy—One Step at a Time

You hear plenty of hype about moving everything to pure hydrogen, but making that jump will take decades. Infrastructure rewiring comes with enormous cost and political risk. Mixing hydrogen into methane networks offers a proving ground for hydrogen distribution. The U.K. and Australia both use such blends in public pilot projects. These efforts measure safety, efficiency, and resident acceptance before heavy investments roll out. Utility workers I’ve interviewed in Wales tell me that public trust matters: if appliances keep working and there’s no compromise on safety, regular folks start seeing hydrogen as more than just a buzzword on climate plans.

Indirect Value in Mobility and Synthetic Fuels

Some researchers push hydrogen-methane blends as a feedstock for new types of synthetic fuels—not just for heating or electricity. With careful tweaks to catalysts and pressure, you end up with different end products, including low-carbon diesel substitutes. Transit agencies in California and Germany already run buses and trucks on these synthetic fuels. There’s a crazy patchwork of rules and incentives, but the mix gives flexibility. In my interviews with fleet operators, reliability trumps everything, and running on a combo fuel means fewer headaches adapting new engines or storage tanks.

Potential Hazards and Solutions

No new practice comes without hiccups. Hydrogen diffuses faster than methane and ignites more easily, raising safety concerns for aging lines and seals. The Gas Technology Institute recommends better leak detection and replacement of vintage pipes—tasks nobody likes, but necessary to avoid surprises. Solutions sit in public-private partnerships that fund upgrades and train first responders. In cities where this work happens, like Rotterdam, claim data shows a drop in incidents and higher insurance confidence.

Looking Ahead with Blends

Blending hydrogen and methane isn’t a panacea, but it moves the world away from pure fossil use. It helps old industries and city grids pick up pace toward net zero, instead of stalling from sticker shock or technical hurdles. Each step creates new jobs and skills in engineering, maintenance, and emergency response. That kind of progress feels tangible off the factory floor and at every kitchen stove—real change one small mixture at a time.

Is the mixture of hydrogen and methane safe to handle?

Everyday Risks, Uncommon Mixtures

Handling gases brings a certain edge to the job. Propane tanks, natural gas lines, even the familiar blue flame on your stove — there’s a respect for safety baked into these routines. Add hydrogen to the list, and the recipe changes. Hydrogen flames burn clear; leaks can disappear without a trace. Add it to methane, and people start talking about “blending” as a shortcut to cleaner fuels. The idea sounds simple enough, but the details matter in a big way.

Flammability Changes Everything

Mixing hydrogen and methane isn’t just a matter of numbers on a gauge. Hydrogen wants to escape. Its molecules move fast and slip through seals that hold methane just fine. Once you mix the two, pipelines and valves you trusted start acting differently. I once visited a plant hardened by decades of natural gas service. Hydrogen-methane blends found every weak point — gasket, weld, hand-tightened fitting — and seeped out. Hydrogen’s low ignition energy makes leaks incredibly risky. A source from the U.S. Department of Energy says even a 20% hydrogen blend noticeably raises explosion hazards compared to pure methane.

Old Infrastructure, New Headaches

America’s natural gas system wasn’t designed with hydrogen in mind. Many pipes, especially the older steel ones under Main Street, face embrittlement from hydrogen. This corrosion problem means pipe bursts become more likely if hydrogen gets loose in the mix. I spoke with a repair crew out of Chicago that swapped out cast iron after a hydrogen test run showed leaks at connections that held methane without issue. While plastic pipes offer better hydrogen resistance, the grid still runs on plenty of old iron and steel. Swapping out a nation’s pipes isn’t just a tough engineering problem — it’s a political one, tangled with costs and timelines.

How Are We Testing These Limits?

Europe’s doing real-world trials on hydrogen-methane blends, and some U.S. utilities have started pilot projects. The National Renewable Energy Laboratory ran a study with 20% hydrogen in natural gas and watched for equipment damage or leaks. Ordinary appliances struggled; pilot lights flickered out, and some sensors grew unreliable. These aren’t lab problems — they’re kitchen-table issues for anyone using gas to cook or heat their home. Insurance companies aren’t about to ignore this, either.

Rethinking Gas Safety

Hydrogen-methane mixtures bring real engineering hurdles. Every worker on a pipeline or in a plant knows safety isn’t just a handbook — it’s a way of life. Traditional leak detectors don’t catch clear hydrogen flames, so workers on the ground need new tools and training. Hydrogen embrittlement means extra inspections and expensive replacements. Smart operators check every gasket, every meter, every spot where gas can get loose. Public safety rules need to catch up with new energy approaches, not lag behind.

Moving Forward With Caution

Blending hydrogen with methane offers cleaner-burning energy, but safety questions keep coming up. Utilities have to weigh lower emissions against the need to retrofit huge systems built decades ago. If hydrogen is the future, the present asks for real honesty about the risks and the real investment to handle them. It’s not just a chemistry puzzle — it’s a street-level safety issue that demands attention from everyone involved.

What is the typical ratio of hydrogen to methane in such mixtures?

Why the Hydrogen-Methane Ratio Matters

Stepping into the world of gas mixtures reveals a landscape that demands attention to detail. The proportion of hydrogen to methane doesn’t just influence combustion or processing—safety, economics, and efficiency are all at stake. Some folks treat these mixtures like interchangeable parts, but real-world results rest on getting those numbers right. Hydrogen brings high energy per kilogram and lightness, methane promises stable burning and bulk energy delivery. Balancing these properties comes down to the practical ratios chosen during blending or generation.

Common Ratios Found in Industry

Most industrial sources and scientific literature put hydrogen-to-methane ratios between 20:80 and 50:50. In synthetic natural gas that comes from coal gasification or reforming, hydrogen often stays around 40% with methane making up most of the rest. Biogas, after thorough upgrading, might end up closer to 10–20% hydrogen and 55–65% methane. These numbers shift based on feedstock, equipment, and intended use. I’ve seen situations in chemical plants where a 30:70 mix lets operators fine-tune flame speed without risking flashback, especially with older pipelines not originally designed for high hydrogen content.

The Impact of Ratio on Processes

Too much hydrogen, say above 50% for most existing pipelines, turns safety into a major concern. Hydrogen diffuses quickly and its flammability in air covers a broad range. That means leaks or improper venting can become hazardous, particularly in aging infrastructures like those in North America and Europe. Methane, by contrast, slows combustion and is more forgiving in mixed-use infrastructures.

The hydrogen-to-methane ratio also influences environmental outcomes. Hydrogen burns without carbon dioxide as a byproduct, while methane does emit some—but far less than coal or oil. People hoping to push carbon reduction often look at increasing hydrogen content in natural gas. A typical 20:80 blend cuts emissions without upending established gas appliances or stoves. I once worked on a campus energy project where a 15% hydrogen blend ran in standard boilers with almost no tuning needed. Exceeding that required better materials in burner heads and careful monitoring.

Facts from The Field

The International Energy Agency recommends ratios of up to 20% hydrogen in existing natural gas networks to ensure compatibility with seals and regulators common in homes and businesses. Producer gas or town gas, used in the past before modern natural gas infrastructure, ran even higher ratios—sometimes 50% hydrogen or more—though equipment and safety standards were less reliable.

Hydrogen-rich blends tend to increase NOx emissions because of higher flame temperature. That keeps regulators cautious about pushing hydrogen levels up without investment in low-NOx technologies. Utility companies have started pilot projects with 10–15% hydrogen blends, testing durability and emissions in real-world conditions. The results shape public policy and investment decisions, especially for aging urban networks.

Finding a Practical Solution

Adjusting the hydrogen-to-methane ratio isn’t about theory. It’s about reliability, safety, and the ability to adapt today’s infrastructure for tomorrow’s needs. Instead of pushing for one-size-fits-all blends, collaboration between utilities, appliance makers, and regulators points the way forward. Routine leak testing, tougher pipelines, and new burner designs all play a part. A measured approach—starting with lower ratios—helps build confidence and captures the benefits of hydrogen without taking on too much risk too quickly. The right blend depends on the network, goals, and readiness to invest both money and time.

How is a mixture of hydrogen and methane stored and transported?

Mixing Two Gases, Facing Real-World Challenges

Combining hydrogen and methane sparks interest for anyone thinking about energy’s future. Both are gaseous fuels, but they couldn't be more different. Methane, or natural gas, already moves through pipelines from wells to homes and factories. Hydrogen, the lightest molecule around, behaves differently—it leaks through the tiniest gaps and can even embrittle metal pipes. Mixing the two brings up unique headaches, especially if you want to move them as safely as pure natural gas.

Pressure, Pipes, and Puzzles

A hydrogen-methane mixture isn't handled like plain old natural gas. Hydrogen's small size causes faster leaks, and it sometimes weakens common steel pipelines. Not every pipeline built for methane tolerates a blend containing more than a few percent hydrogen. Utilities testing these blends often stick to about 5-20% hydrogen by volume to dodge rapid corrosion or dramatic changes in gas behavior.

Pipeline operators can't just drop in a hydrogen-rich mix and cross their fingers. Testing each section of pipeline matters. Modern steel pipes with plastic linings handle blends fairly well, but older steel pipes sometimes develop tiny cracks under the stress. Some operators spend more money inspecting and sometimes swapping out old sections, trying to keep the gas flowing without endangering property or workers. In the Netherlands, Germany, and the UK, small pilot projects give a taste of what’s possible, but those operate under constant monitoring.

Compression and Storage: Not the Same for Both Gases

Storing a hydrogen-methane mix takes more attention to detail than it sounds. Hydrogen packs less energy per cubic meter, so pressurizing the mix becomes more important to deliver enough energy in the same volume. Conventional underground storage—like salt caverns or depleted gas fields—has seen more research. Some reservoirs handle small amounts of hydrogen, but scientists keep close watch for leaks. Hydrogen loves to escape and reacts with certain minerals, so site selection makes all the difference.

Above ground, high-pressure steel tanks see use, but these require careful engineering to avoid accidents. Hydrogen needs thicker, specially designed vessels, and adding it to methane forces storage standards to rise. At every step, sensors and gas detectors play a big role, alerting operators to leaks before things turn dangerous. I once visited a facility that mixed hydrogen at low concentrations with natural gas for testing. What struck me most—the tight procedures for every valve turn and pressure check. Checking for leaks became a full-time job.

Transport Beyond Pipelines

Not every location sits close to a pipeline. Road and rail transport come next, but tankers built for methane can't always handle hydrogen safely. Specialized tube trailers, built to handle high-pressure hydrogen, sometimes shuttle between blending points. Trucks need to follow strict safety codes. Leaked hydrogen won't just sit near the ground; it rises fast and burns nearly invisible, so safety protocols grow even stricter. While this raises the cost, a shortcut here can spell disaster for communities and workers.

A Pressing Need for Better Standards and New Materials

Mixing hydrogen and methane stands out as an attractive stopgap on the way to cleaner energy, but the technical hurdles aren't just paperwork. Teams around the world work on better alloys and coatings to prevent embrittlement, while gas companies hunt for cheap ways to update pipelines and storage. These efforts matter—building trust with customers and first responders gets you further than any shiny press release. Eventually, clear standards plus investment in new tech should cut risks and bring this blended future closer.

What industries commonly use a hydrogen and methane gas mixture?

Steel and Metals Processing

Take a look inside a steel mill, and you see flames that reach thousands of degrees. Those huge furnaces chew through materials and spit out the backbone of bridges, trains, and city buildings. In many of these foundries, a blend of hydrogen and methane steps up. Blending these two allows steelmakers to control the atmosphere inside furnaces. Hydrogen strips oxygen from metal oxides, helping to produce iron without too much carbon stuck inside. That means stronger and cleaner steel, with fewer climate-changing emissions. In my visits to mills, workers care about that blend as it lets them balance heat and protect the metal surface. Hydrogen alone burns hot but costs plenty and can cause metal brittleness. methane alone creates more CO2. Mixing both lets plants cut costs and pollution while getting a better steel product. The world needs more of that, with green steel becoming a hot topic for climate-conscious builders.

Glass Manufacturing

Head over to the glassworks, and you find another spot where this gas duo matters. Melting sand into panes or bottles with perfect clarity means careful temperature control and keeping oxygen away from the melt. Many glass makers blend hydrogen and methane to create the right flame for delicate operations in making flat glass, vials, or specialty bulbs. The hydrogen keeps impurities down, stopping that annoying haze or tint. Methane delivers steady heat for batch after batch. By tuning the ratio, plant engineers reduce energy costs and lower emissions, making glass cleaner and safer—especially where medical and food packaging demands higher quality.

Semi-Conductor and Electronics Production

Silicon chips form a hidden web that powers nearly every device today. The factories that make these chips run massive process chambers loaded with sensitive materials. A precise gas blend makes thin film chemical vapor deposition (CVD) safer for workers and more reliable for product yield. Adding hydrogen to methane lets engineers lay down the perfect crystalline silicon layer over a wafer without introducing too much carbon or risk of defects. During my tour at a fab plant, I noticed rows of control panels monitoring gas flow every second, with strict safe handling rules since these gases can be toxic or explosive. Mistakes cost millions in ruined products, but getting it right delivers faster phones and smarter cars around the globe.

Energy and Power Generation

Cleaner fuels sit at the center of the push for a sustainable future. Natural gas sometimes doesn’t burn clean enough. Hydrogen by itself delivers high energy with water as the main byproduct, but its distribution network isn’t wide yet. Plants across the world blend hydrogen and methane to run turbines or engines, trimming greenhouse gas emissions from each megawatt made. Some gas stations experiment with these blends to find the right formula for tomorrow’s vehicles. In countries where natural gas dominates, adding hydrogen offers a step towards future-ready infrastructure without tearing up miles of pipeline, making this blend a practical bridge from fossil fuels to renewables.

Chemical Synthesis and Laboratory

On the lab bench, researchers combine hydrogen and methane in reactors to create specialty chemicals, fertilizers, and advanced plastics. The world’s food supply relies on these kinds of reactions, from ammonia production to hydrogenation processes. In chemical plants I’ve visited, engineers talk about using gas blends as both a feedstock and a fuel, chasing purity and consistency for safe, high-yield reactions. Controlling that gas mix not only improves safety but saves energy, which matters as utilities raise rates and climate goals sharpen.

Moving Forward

Industries get more creative each year with hydrogen and methane mixes. They keep samples safer, products stronger, and keep costs in check. Producers and researchers also look for carbon capture and better blending tech to ensure progress doesn’t slow as demand shifts. With rising energy needs and climate rules tightening, these gases are likely to stay at the center of tomorrow’s industrial toolbox.

Mixture Of Hydrogen And Methane
Names
Preferred IUPAC name dihydrane-methane
Other names Mixed gas
Hydrogen-methane blend
Hythane
Hydromethane mixture
Hydrogen enriched natural gas
Pronunciation /ˈmɪks.tʃər əv ˈhaɪ.drə.dʒən ənd ˈmiːθeɪn/
Identifiers
CAS Number ['68410-61-9']
Beilstein Reference 1718736
ChEBI CHEBI:131765
ChEMBL CHEMBL1233499
ChemSpider 109777120
DrugBank DB11106
ECHA InfoCard 05be79e9-56a9-418b-924a-8e07f7b4df2d
EC Number 270-141-7
Gmelin Reference Gmelin Reference: 137
KEGG C14825
MeSH D004928
PubChem CID 129607178
RTECS number MI7700000
UNII 7U0WT64A3T
UN number UN1965
Properties
Chemical formula H2+CH4
Molar mass Molar mass: 8.04 g/mol
Appearance Colorless gas
Odor Odorless
Density 0.08375 kg/m³
Solubility in water slightly soluble
log P 0.55
Vapor pressure 38517.03 mmHg at 25 °C
Acidity (pKa) 38 (string)
Magnetic susceptibility (χ) +0.000018
Refractive index (nD) 1.00048
Viscosity 0.011 mN·s/m²
Dipole moment 0 Debye
Thermochemistry
Std molar entropy (S⦵298) 133.1 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) 0 kJ mol⁻¹
Std enthalpy of combustion (ΔcH⦵298) -568 kJ/mol
Pharmacology
ATC code V03AN05
Hazards
GHS labelling GHS02, GHS04
Pictograms GHS02, GHS04
Signal word Danger
Precautionary statements P210, P271, P377, P381, P403
NFPA 704 (fire diamond) 4-4-2
Flash point -200 °C
Autoignition temperature 632°C
Explosive limits Explosive limits: 5-75%
Lethal dose or concentration Lethal dose or concentration: **LC50 (rat) 576000 ppm (4 hours)**
NIOSH UN1064
PEL (Permissible) PEL: 1,000 ppm
REL (Recommended) recommended
IDLH (Immediate danger) 1000 ppm
Related compounds
Related compounds Hydrogen
Methane
Hydrogen chloride
Methanol
Carbon monoxide
Carbon dioxide
Ammonia