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Material Safety Data Sheet: Mercury Salicylate

Identification

Product Name: Mercury Salicylate
Chemical Formula: C7H5HgO3
Synonyms: Mercuric salicylate, Mercurisalicylate
Recommended Uses: Laboratory research, some historical medical applications
Supplier Details: Manufacturer and distributor information with 24-hour emergency contact
CAS Number: 253-350-9

Hazard Identification

Classification: Acute toxicity (oral, dermal, inhalation), skin and eye irritant, reproductive toxicity, specific organ toxicity (kidneys, nervous system)
Signal Word: Danger
Hazard Statements: Fatal if swallowed, toxic if inhaled or in contact with skin, may damage fertility or unborn child, causes damage to organs with prolonged exposure
Pictograms: Skull and crossbones, Health hazard
Precautionary Statements: Avoid contact with skin and eyes, avoid breathing dust or fumes, wear protective clothing, operate only in well-ventilated areas

Composition / Information on Ingredients

Chemical Identity: Mercury(II) salicylate
Concentration: >98% mercury(II) salicylate by weight
Impurities: Trace amounts of related mercury compounds may be present, not expected to represent additional hazards
Other Ingredients: No significant non-hazardous components reported

First Aid Measures

Inhalation: Move to fresh air immediately, administer oxygen if breathing becomes difficult, seek medical attention without delay
Skin Contact: Remove contaminated clothing, wash with copious amounts of water and soap, seek medical help
Eye Contact: Rinse with water for several minutes, lift eyelids, remove contact lenses if present, obtain medical advice
Ingestion: Do not induce vomiting, rinse mouth with water, call Poison Center or doctor, provide information on compound
Important Symptoms: Abdominal pain, kidney damage, neurological symptoms: tremors, irritability, memory loss, potential delayed health effects
Advice to Doctor: Supportive care, chelation therapy may be indicated, monitor neurological and renal function closely

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, CO2, foam, do not use water streams on burning powder
Specific Hazards: Toxic mercury vapors and oxides may release during combustion, salicylic acid decomposition may add irritating fumes
Protective Equipment for Firefighters: Full protective suit, self-contained breathing apparatus
Precautions: Evacuate surrounding area, avoid inhaling fumes, restrict runoff from entering water supplies or sewers

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, use chemical-resistant gloves, goggles, and respirators
Environmental Precautions: Prevent from entering soil, waterways, drains, or sewers
Cleanup Methods: Scoop spilled material into specialized hazardous waste containers, use moistened absorbent material to minimize dust, ventilate area thoroughly, decontaminate surfaces with appropriate mercury neutralizers
Disposal: Follow specialized mercury-contaminated waste regulations, ensure no dispersal of dust or vapors during collection

Handling and Storage

Safe Handling: Avoid generating dust, operate under fume hood where possible, handle only with trained personnel wearing specified PPE, wash hands thoroughly after use
Storage Instructions: Store in tightly closed, clearly labeled containers, keep in a dry, cool, well-ventilated area dedicated to toxic chemicals
Incompatibilities: Avoid contact with oxidizing agents, strong acids, or bases; store away from food and drink

Exposure Controls and Personal Protection

Occupational Exposure Limits: Mercury exposure limit (OSHA PEL): 0.1 mg/m³ (ceiling), ACGIH TLV: 0.025 mg/m³ (TWA)
Engineering Controls: Local exhaust ventilation, physical containment devices such as glove boxes
PPE: Chemical-resistant gloves, lab coat, eye protection (goggles or face shield), approved respiratory protection when dust or vapor is generated
Hygiene Measures: Change contaminated clothing, do not eat, drink, or smoke during handling, shower after handling significant quantities

Physical and Chemical Properties

Appearance: White to off-white powder
Odor: Slight, phenolic
Melting Point: Decomposes above 135°C
Solubility: Slightly soluble in water, more soluble in alcohols
Density: Approximately 4.7 g/cm3
Vapor Pressure: Not significant at room temperature
pH: No data available
Flammability: Not combustible, but may support combustion when mixed with organic materials

Stability and Reactivity

Chemical Stability: Stable under properly controlled storage, decomposes at high temperatures
Hazardous Reactions: Contact with strong acids can release toxic mercury and salicylic acid vapors
Materials to Avoid: Oxidizing agents, reducing agents, strong bases
Hazardous Decomposition Products: Mercury vapors, other toxic metal compounds, carbon oxides
Conditions to Avoid: High heat, humidity, moisture

Toxicological Information

Acute Toxicity: Extremely toxic by ingestion, inhalation, or skin absorption
Chronic Effects: Possible kidney damage, central nervous system impairment, tremor, personality changes, memory loss with repeated exposure
Carcinogenicity: Mercury compounds are classified as possible human carcinogens by some agencies
Reproductive Toxicity: Documented risk to fertility and fetal development in people and animal studies
Target Organs: Kidneys, nervous system, possibly liver
Routes of Exposure: Skin, eyes, inhalation, ingestion
Symptoms: Nausea, vomiting, abdominal pain, dizziness, tremors, hypersalivation, behavioral changes

Ecological Information

Aquatic Toxicity: Acute and chronic toxicity to fish, aquatic invertebrates, and algae at very low concentrations
Persistence and Degradability: Mercury accumulates in sediments and biota
Bioaccumulative Potential: High, especially in aquatic food chains; biomagnification leads to amplified effects in predators
Mobility in Soil: Limited; mercury forms stable complexes, but runoff contamination can occur
Hazard to Wildlife: Highly toxic to birds, mammals, aquatic organisms, risk of secondary poisoning up the food chain

Disposal Considerations

Waste Treatment Methods: Collect all waste, contaminated absorbents, PPE in sealed and labeled containers for hazardous waste disposal
Disposal Practices: Do not dispose in regular trash, drains, or local landfill; follow EPA, state, and local regulations for mercury waste
Special Precautions: Prevent release into environment at all stages, final treatment must comply with mercury waste incineration or secure chemical landfill procedures

Transport Information

UN Number: 2025
Proper Shipping Name: Mercury compound, n.o.s. (Mercury Salicylate)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: III
Marine Pollutant: Yes; label shipments accordingly
Transport Label: Toxic, Marine Pollutant
Special Precautions: Protect containers against physical damage, keep upright, meet all labeling and documentation requirements for international and local transport

Regulatory Information

TSCA Status: Mercury salicylate, regulated substance under the Toxic Substances Control Act
SARA Title III: Listed as an extremely hazardous substance
RCRA Status: Discarded material classified as hazardous waste (U151: Mercury compounds)
OSHA Regulations: Occupational exposure limits and workplace safety requirements apply
International Regulations: Covered by international treaties on mercury use and transport; subject to registration, reporting, and notification
WHMIS Classification (Canada): D1A (very toxic), D2A (carcinogenicity, mutagenicity, reproductive toxicity)