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Product Name: Manganese Resinate
Chemical Family: Organo-metallic salt of resin acids
Synonyms: Manganese soaps, Manganese resin acid salt
Product Code: MR-100
Uses: Industrial pigment, drier in paints and coatings, lubricant additive
Manufacturer: Chemical supply companies specializing in metal soaps
Contact Numbers: Emergency: Local Poison Control / Fire Department; Information: Standard business hours line
CAS Number: 68333-49-9
Recommended Use Restrictions: Not designed for pharmaceutical or food applications; use in well-ventilated settings
Emergency Overview: Reddish-brown paste or powder, mild resin odor, may stain skin and surfaces
GHS Classification: Acute Toxicity (Oral) Category 4, Eye Irritation Category 2A, Skin Irritation Category 2
Pictograms: Exclamation mark, Health hazard
Signal Word: Warning
Hazard Statements: Harmful if swallowed; causes skin and eye irritation; possible manganese toxicity with chronic exposure
Precautionary Statements: Wear suitable protective clothing; avoid inhalation of dust or fumes; wash hands after use; do not eat, drink, or smoke when using
Potential Health Effects: Inhalation may cause coughing or shortness of breath; skin and eye contact may cause redness; long-term overexposure may affect the nervous system
Environmental Hazards: Toxic to aquatic life with long lasting effects; avoid uncontrolled release to environment
Manganese Resinate: 40–65% by weight
Resin Acids: 30–53% (source: pine resin or tall oil resin acids)
Inert Materials: 2–10% (may include mineral oil or clay carriers)
Impurities: Minor traces of unreacted resin acids, heavy metals often <0.5%
Note: Product does not generally contain solvents but may retain moisture below 1%
Inhalation: Move individual to fresh air immediately, keep at rest in a position comfortable for breathing, seek medical advice if symptoms persist
Skin Contact: Wash exposed skin with soap and water, remove contaminated clothing, seek attention for rash or persistent irritation
Eye Contact: Rinse eyes gently but thoroughly with clean, lukewarm water for at least 15 minutes, lift eyelids as necessary, remove contact lenses if present and easy, get medical help if irritation persists
Ingestion: Rinse mouth, give small amounts of water if conscious, do not induce vomiting, get immediate medical attention
Acute Exposure Symptoms: Irritation, redness, nausea, headache, dizziness
Advice for Medical Professionals: Symptoms of manganese exposure may resemble Parkinsonism; supportive care recommended
Suitable Extinguishing Media: Use CO₂, dry chemical powder, foam, or water spray; avoid using a direct stream of water
Specific Hazards: Burning may release irritating manganese oxides, resinous vapors, and carbon monoxide
Protective Equipment for Firefighters: Full protective gear including self-contained breathing apparatus recommended
Special Procedures: Stay upwind; avoid runoff into water sources
Combustion Products: Dense smoke may form; volatile organic compounds released under fire conditions
Flammability Classification: May burn if strongly heated; not highly flammable
Personal Precautions: Wear gloves, goggles, and dust mask/respirator as needed
Environmental Precautions: Prevent entry into drains, sewers, and local waterways
Methods for Cleanup: Scoop up product with non-sparking tools, place in sealable containers for disposal, wipe surfaces with solvents rated for resins or detergents
Spill Response: For larger spills, cordon off area, ventilate, and consider use of absorbent materials
Decontamination: Rinse area with water only after complete removal of product; collect rinse for disposal
Emergency Contacts: Contact local environmental agency as required for significant releases
Handling: Use only in well-ventilated areas, avoid creating dust, minimize skin and eye contact, keep containers closed when not in use, employ good industrial hygiene
Storage: Store in cool, dry place away from oxidizing agents and strong acids
Packaging: Use lined drums, HDPE containers, or metal cans with secure closures
Incompatibilities: Do not store near strong oxidizers or alkalis; avoid mixing with foodstuffs or feed
General Hygiene: Wash hands thoroughly after handling, do not eat or smoke in the work area, launder clothing before reuse
Occupational Exposure Limits: Manganese (total dust): 0.1 mg/m³ (ACGIH TLV), 5 mg/m³ ceiling (OSHA PEL)
Engineering Controls: Local exhaust ventilation recommended; enclose processes where possible; monitor air regularly
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), splash-resistant goggles, long-sleeved workwear, NIOSH-approved dust respirator
Hygienic Practices: Regular hand washing, no open food in processing areas, eye wash stations available
Other Controls: Implement spill containment plans, train workers in safe handling
Appearance: Reddish-brown paste, waxy solid, or powder
Odor: Mild resin-like
pH: Not applicable (insoluble in water)
Boiling Point: Decomposes before boiling
Melting Point: Variable, typically 100–130°C
Flash Point: >180°C (closed cup)
Evaporation Rate: Negligible
Solubility in Water: Insoluble
Solubility in Organic Solvents: Moderate (mineral spirits, turpentine, some alcohols)
Relative Density: 0.9–1.2 (water = 1)
Vapor Pressure: Not measurable
Partition Coefficient: Not determined
Other Properties: May stain surfaces, slow volatilization
Chemical Stability: Stable under normal storage and handling conditions
Reactivity: Reacts with strong acids and oxidizers, decomposition possible at high temperatures
Hazardous Polymerization: Will not occur
Decomposition Products: Manganese oxides, carbon monoxide, hydrocarbons
Conditions to Avoid: Prolonged exposure to heat, open flames, incompatible chemicals
Routes of Exposure: Skin contact, inhalation of dust/fume, ingestion
Acute Effects: Skin and eye irritation, gastrointestinal upset if ingested, coughing if inhaled
Chronic Effects: Manganese toxicity may cause neurological symptoms (tremors, headaches), rare with standard safety practices
LD50 (Oral - rat): Estimated 2000–3500 mg/kg for similar manganese compounds
Carcinogenicity: Not classified by IARC, NTP, or ACGIH as carcinogenic
Mutagenicity: No convincing evidence in available studies
Reproductive Toxicity: Not expected under normal use
Sensitization: May cause allergic reactions in sensitive individuals
Ecotoxicity: Harmful to aquatic organisms; manganese is persistent and accumulates in sediment
Mobility: Low in soil, tends to bind to organic material
Persistence and Degradability: Resin acids degrade slowly; manganese remains indefinitely in environment
Bioaccumulation Potential: Manganese may concentrate in aquatic and terrestrial organisms
Aquatic Toxicity Reference: LC50 (fish) unavailable for resinate specifically; inorganic manganese demonstrates moderate toxicity
Other Effects: Avoid release to waterways or soil to lower environmental risk
Disposal Methods: Treat as hazardous waste according to local, state, national regulations
Unused Product: Send to licensed chemical disposal or hazardous waste incinerator
Contaminated Packaging: Rinse, puncture, and recycle or dispose through authorized waste handler
Waste Code: Dependent on local regulations; typical for metal soap waste
Special Precautions: Do not mix with general waste; notify disposal contractor of manganese content
UN Number: Not regulated for ground or sea transport, unless in bulk
UN Proper Shipping Name: Not assigned; refer to local regulations
Transport Hazard Class: N/A under normal supply
Packing Group: N/A
Environmental Hazards During Transport: Avoid leaks or spills
Special Transport Notes: Secure containers, avoid exposure to moisture or strong oxidizers
Regulatory Requirements: Label as "Industrial Chemical" with hazard pictograms as needed
OSHA: Manganese listed as regulated substance; workplace exposure standards apply
TSCA: Manganese resinate appears on US TSCA inventory
REACH: Notified as a substance of concern in the EU for aquatic toxicity
Canada WHMIS: Classified as hazardous due to chronic toxicity
Other Restrictions: Subject to notification under several local, state, and provincial chemical regulations
Labeling: Signal words, pictograms, and hazard statements required on shipping packages
Community Right-to-Know: Report manganese content if thresholds exceeded in the US or other relevant jurisdictions
