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Material Safety Data Sheet: Lead Monoxide

Identification

Product Name: Lead Monoxide
Synonyms: Litharge, Lead(II) Oxide
Chemical Formula: PbO
CAS Number: 1317-36-8
EC Number: 215-267-0
Recommended Use: Battery manufacturing, ceramics, paint pigments, glass production
Supplier Details: Consult product label for manufacturer contact information
Emergency Contact: Refer to the emergency phone number provided by your supplier

Hazard Identification

Classification: Acute toxicity (oral, inhalation), Carcinogenicity, Reproductive toxicity, Specific target organ toxicity (repeated exposure)
Signal Word: Danger
Hazard Statements: Toxic if swallowed, Toxic if inhaled, May damage the unborn child, Suspected of causing cancer, Causes damage to organs through prolonged or repeated exposure
Precautionary Statements: Avoid all direct contact, Do not eat, drink, or smoke near product, Use only in well-ventilated spaces, Wear protecting clothing and equipment
Symptoms of Exposure: Headache, abdominal cramping, irritation of respiratory tract, anemia, neurological effects, kidney damage

Composition / Information on Ingredients

Chemical Name: Lead Monoxide
Concentration: Typically 98–100%
Impurities: Trace amounts of lead dioxide (PbO2), metallic lead (Pb), other lead compounds depending on product source
Additional Components: No other intentionally added substances reported

First Aid Measures

Inhalation: Remove to fresh air immediately, keep at rest, seek medical help if breathing discomfort continues, administer oxygen if authorized and necessary
Skin Contact: Remove contaminated clothing and wash affected area thoroughly with soap and water, consult medical staff for severe irritation or if symptoms develop
Eye Contact: Rinse immediately with gentle, clean water for several minutes lifting eyelids, remove contact lenses if present and easy to do, get medical attention for persistent irritation
Ingestion: Do not induce vomiting, rinse mouth with water, give water to drink if the person is fully conscious, seek immediate medical advice
Special Recommendations: Monitor victim for lead poisoning symptoms, provide information on possible exposure route to healthcare professionals

Fire-Fighting Measures

Suitable Extinguishing Media: Use extinguishing agents suitable for the surrounding fire such as dry powder, CO2, foam, or water spray
Unsuitable Media: Avoid full water jet
Specific Hazards: Product is not flammable, but toxic fumes including lead oxide and lead fumes can form in a fire
Protective Equipment: Firefighters require self-contained breathing apparatus and full protective clothing to prevent exposure to fumes
Special Procedures: Evacuate area if large amounts involved, keep unnecessary people away, cool affected containers with water spray

Accidental Release Measures

Personal Precautions: Wear protective equipment including gloves, goggles, and an appropriate respirator, wash hands thoroughly after handling, restrict access to spill area
Environmental Precautions: Prevent entry into drains, water courses, or soil; notify authorities if large spills could threaten groundwater or the environment
Containment: Secure spill area, suppress dust by moistening with water if safe, use barriers to prevent spreading
Cleanup Methods: Sweep up or vacuum spilled lead monoxide while minimizing dust, gather in properly labeled containers for safe disposal, do not use compressed air
Decontamination: Wash area thoroughly with water after cleanup, dispose of wash water as contaminated waste

Handling and Storage

Handling: Use local or general exhaust ventilation, avoid dust generation and buildup, wear recommended protective gear, keep away from food, drinks and smoking materials
Storage: Store in closed, labeled containers placed in dry, cool, and well-ventilated areas away from acids and incompatible materials
Incompatibilities: Strong acids, reducing agents, ammonium salts, organics, easily oxidizable materials
Special Storage Conditions: Protect from physical damage, frequent inspections for leaks or breakdowns, store dust-contaminated protective clothes separately

Exposure Controls and Personal Protection

Occupational Exposure Limits: OSHA PEL: 0.05 mg/m³ (as Pb), ACGIH TLV: 0.05 mg/m³ (as Pb) TWA
Engineering Controls: Local exhaust ventilation or general dilution ventilation recommended, handle only in designated well-ventilated areas
Personal Respiratory Protection: Use NIOSH-approved respirators for lead dust if ventilation cannot control exposure
Skin Protection: Wear impervious gloves such as nitrile or neoprene, use full-body protective clothing to avoid contamination
Eye and Face Protection: Use safety goggles with side shields or face shield for splash or dust risk
Work Hygiene Practices: Wash hands and face after working with lead monoxide, remove and clean contaminated clothing before reuse, provide eye wash station and emergency shower in work area

Physical and Chemical Properties

Appearance: Fine, yellow to reddish-yellow powder
Odor: Odorless
Molecular Weight: 223.19 g/mol
Melting Point: 888°C (1630°F)
Boiling Point: 1470°C (2678°F)
Density: 9.53 g/cm³
Solubility: Insoluble in water, dissolves in acids
pH: Not applicable (insoluble in water)
Vapor Pressure: Negligible at room temperature
Other Properties: Forms hazardous fumes at high temperature, stable at room conditions

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Conditions to Avoid: Moist conditions, high humidity, incompatible chemical contact, high temperatures
Incompatible Materials: Acids, strong reducers, organic materials, ammonium, magnesium
Hazardous Decomposition Products: Toxic lead fumes, lead oxides, possible generation of corrosive vapors on contact with acids
Reactivity: Reacts slowly with water or carbon dioxide to form lead carbonate, reacts vigorously with strong acids
Polymerization: No risk of hazardous polymerization

Toxicological Information

Routes of Exposure: Inhalation of powder or dust, ingestion, skin contact
Acute Effects: Toxic by ingestion, inhalation causes cough, respiratory tract irritation, ingestion leads to gastrointestinal effects
Chronic Effects: Cumulative poison, repeated exposure leads to anemia, kidney damage, peripheral and central nervous system impact, reproductive and developmental harm
Carcinogenicity: Classified as possibly carcinogenic to humans (IARC Group 2A)
Symptoms: Abdominal pain, nausea, joint pains, weakness, memory issues, behavioral changes, loss of appetite
Target Organs: Blood, nervous system, kidneys, reproductive organs
Special Sensitivity: Young children and pregnant women are particularly vulnerable

Ecological Information

Toxicity to Aquatic Life: Highly toxic to aquatic organisms, accumulates in the environment, persistent in sediment and soils, may bioaccumulate in animal tissues
Persistence and Degradability: Not biodegradable, persists in soil and water, does not degrade under natural conditions
Mobility in Soil: Binds strongly to soil particles, low mobility but long-term environmental persistence
Bioaccumulation Potential: Can bioaccumulate in organisms and enter food chain
Other Environmental Concerns: Contamination of water bodies poses risk to drinking water sources and aquatic food webs

Disposal Considerations

Waste Disposal Methods: Dispose as hazardous waste according to local regulations, consult permitted hazardous waste contractor
Container Disposal: Triple rinse containers before disposal, puncture or crush only after cleaning, label as contaminated if not thoroughly cleaned
Special Handling and Precautions: Minimize dust generation during disposal, do not allow waste to enter surface water or sewer systems, record disposal details
Regulations: Dispose of in compliance with federal, state, and local environmental regulations relating to lead and hazardous substances

Transport Information

UN Number: UN 2291
Proper Shipping Name: Lead monoxide
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: III
Label(s) Required: Toxic substance label required on external packaging
Special Transport Measures: Secure packages to prevent spillage, follow vehicle labeling rules, provide documentation on lead hazard to carriers
International Transport: Compliant with requirements of IMDG, IATA, ADR as hazardous toxic material

Regulatory Information

OSHA: Lead compounds regulated as hazardous under OSHA Subpart Z
TSCA: Listed on the Toxic Substances Control Act inventory
SARA Title III: Subject to reporting under Section 313 (Toxic Chemical Release Reporting)

RCRA: Waste classified as hazardous (D008) due to lead content
CERCLA: Subject to reporting requirements, Reportable Quantity (RQ): 10 lbs (4.54 kg)
IARC/NIOSH/ACGIH: Listed as probable carcinogen by IARC, exposure limits established by NIOSH and ACGIH
International Regulations: Covered under REACH, RoHS, and regulations in many countries controlling workplace and environmental exposure