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Product Name: Isopropyl Bromoacetate
Chemical Formula: C5H9BrO2
Synonyms: 2-Bromoacetic acid isopropyl ester
CAS Number: 633-70-5
Recommended Use: Laboratory reagents, organic synthesis
Manufacturer Contact: Provided on purchase documentation
Emergency Phone Number: Provided on purchase documentation
Relevant Identified Uses: Research and industrial use only; not for food, drug, or household use
GHS Classification: Acute Toxicity (Oral) Category 3, Skin Corrosion/Irritation Category 2, Eye Damage/Irritation Category 2A, Specific Target Organ Toxicity Single Exposure Category 3
Signal Word: Danger
Hazard Statements: Toxic if swallowed; causes skin irritation; causes serious eye irritation; may cause respiratory irritation
Pictograms: Skull and crossbones, exclamation mark
Precautionary Statements: Avoid breathing dust/vapor; wear protective gloves, clothing, and eye protection; wash hands thoroughly after handling; do not eat, drink, or smoke while using
Potential Health Effects: Inhalation may lead to respiratory tract irritation; ingestion can result in nausea, vomiting, abdominal pain; skin and eye contact can cause severe irritation or burns
Target Organs: Eyes, skin, respiratory system, digestive system
Chemical Name: Isopropyl bromoacetate
Concentration: 98-100%
CAS Number: 633-70-5
Impurities: Trace solvents or stabilizers determined by supplier; identify through certificate of analysis
Additives: None
General Advice: Move affected person to fresh air; consult a physician immediately; provide this MSDS to medical staff
Inhalation: Remove person from exposure site; keep at rest in comfortable position for breathing; seek immediate medical attention
Skin Contact: Remove contaminated clothing immediately and wash affected area with soap and water for at least 15 minutes; seek prompt medical advice
Eye Contact: Rinse eyes with water for at least 15 minutes, lifting eyelids occasionally; do not rub eyes; seek prompt medical attention
Ingestion: Do not induce vomiting; rinse mouth thoroughly with water; seek immediate medical attention
Most Important Symptoms: May cause burning sensation, respiratory difficulties, gastrointestinal distress, skin blistering
Indication for Immediate Medical Attention: If exposed or concerned, consult toxicology center
Extinguishing Media: Use dry chemical powder, carbon dioxide (CO2), or alcohol-resistant foam; water may spread the fire
Hazardous Combustion Products: Hydrogen bromide, carbon oxides
Specific Fire Hazards: Vapors may form explosive mixtures with air; containers may explode if heated
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Advice for Firefighters: Approach from upwind; use water spray to cool fire-exposed containers; avoid breathing combustion gases
Personal Precautions: Evacuate area; ventilate; avoid breathing vapors; use personal protective equipment including respirator, gloves, and goggles
Environmental Precautions: Prevent further leakage or spillage if safe; do not allow product to enter drains or waterways
Methods for Cleaning Up: Absorb spills with inert material (vermiculite, dry sand); place in chemical waste container; clean spill area thoroughly with water and detergent
Small Spill: Use absorbent material; avoid skin contact
Large Spill: Contain spill, call emergency response, dispose of according to local regulations
Handling Precautions: Use chemical fume hood; avoid contact with skin, eyes, and clothing; refrain from inhaling vapors or mist; keep away from incompatible materials
Hygiene Measures: Wash hands after handling; prohibit food and drink in work area
Storage Conditions: Store in a tightly closed container; keep in a cool, dry, well-ventilated place; protect from light and moisture
Incompatible Materials: Strong bases, strong oxidizers, strong reducing agents, amines
Packaging Materials: Use corrosion-resistant materials for containers
Occupational Exposure Limits: No established OSHA/ACGIH limits; treat as potentially hazardous
Engineering Controls: Use appropriate exhaust ventilation, safety showers, eyewash stations; maintain negative pressure in chemical storage
Personal Protection:
Appearance: Colorless to pale yellow liquid
Odor: Pungent, sweet
Odor Threshold: Not established
pH: Not applicable
Melting Point: -42°C (approximate)
Boiling Point: 187°C (approximate)
Flash Point: 80°C (closed cup; approximate)
Evaporation Rate: Not determined
Flammability: Combustible liquid
Vapor Pressure: Low at room temperature
Vapor Density: Heavier than air
Relative Density: 1.48 g/cm³
Solubility: Slightly soluble in water; miscible with most organic solvents
Partition Coefficient: Not determined
Auto-ignition Temperature: Not determined
Decomposition Temperature: Not determined
Viscosity: Not determined
Explosive Properties: Not explosive under normal conditions
Oxidizing Properties: Not classified as an oxidizer
Chemical Stability: Stable under recommended storage conditions
Conditions to Avoid: Exposure to moisture, heat, open flames, ignition sources, and light
Incompatible Materials: Strong bases, strong oxidizers, strong reducing agents, amines
Hazardous Decomposition Products: Hydrogen bromide, carbon monoxide, carbon dioxide
Possibility of Hazardous Reactions: May react violently with incompatible materials
Acute Toxicity: Oral LD50 (rat): 252 mg/kg; data on dermal and inhalation exposure not well characterized
Skin Corrosion/Irritation: Causes irritation and potential burns
Serious Eye Damage/Irritation: Causes severe irritation, possible irreversible damage
Respiratory or Skin Sensitization: Possible irritant; no sensitization studies available
Germ Cell Mutagenicity: No data available
Carcinogenicity: Not listed by IARC, NTP, or OSHA
Reproductive Toxicity: No data available
Target Organ Effects: Eyes, skin, respiratory tract, gastrointestinal system
Symptoms: Burning sensation, cough, shortness of breath, abdominal pain, blisters
Ecotoxicity: Harmful to aquatic life; insufficient data for specific species
Persistence and Degradability: No specific biodegradation data; likely persistent
Bioaccumulative Potential: No significant bioaccumulation expected based on structure
Mobility in Soil: Product is mobile in soil and may affect groundwater
Other Adverse Effects: Avoid discharge into environment; product or its byproducts may be toxic to aquatic systems
Disposal Methods: Dispose of as hazardous waste according to local, regional, or national regulations; do not pour down drain
Contaminated Packaging: Rinse containers, offer for recycling, or dispose of at approved waste facility
Other Disposal Considerations: Incineration or chemical incinerator with afterburner and scrubber preferred; consult licensed waste disposal contractor
UN Number: UN 3265
UN Proper Shipping Name: Corrosive Liquid, Acidic, Organic, N.O.S. (contains Isopropyl bromoacetate)
Transport Hazard Class: 8 (Corrosive substances)
Packing Group: II
Marine Pollutant: Not classified as a marine pollutant
Special Precautions: Keep container tightly closed; ensure carrier and handlers are informed of hazards
Transport Label: Corrosive (8)
TSCA Status: Listed on the U.S. TSCA Inventory
DSL/NDSL (Canada): Listed/Not listed
EU Regulation (REACH): Not registered
OSHA Hazard Communication: Classified as hazardous
SARA Title III: Not subject to emergency planning requirements
California Proposition 65: Not listed
Other International Inventories: Refer to local and national regulations
