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Material Safety Data Sheet for Iprodione

Identification

Product Name: Iprodione
Chemical Family: Dicarboximide Fungicide
Synonyms: 3-(3,5-dichlorophenyl)-N-isopropyl-2,4-dioxoimidazolidine-1-carboxamide
CAS Number: 36734-19-7
Recommended Use: Agricultural fungicide for crop protection
Supplier Information: Manufacturer or supplier information available on commercial packaging
Emergency Telephone: Contact local poison control or emergency services

Hazard Identification

Classification: Harmful if swallowed, Eye irritation, Skin sensitization
Hazard Statements: May cause damage to organs through prolonged or repeated exposure, Toxic to aquatic life with long lasting effects
Pictogram: Health hazard symbol, Exclamation mark, Environment
Signal Word: Warning
Precautionary Statements: Wear suitable protective clothing, Avoid release to natural water sources, Wash hands thoroughly after handling, Do not eat, drink or smoke during use
Routes of Exposure: Inhalation, skin and eye contact, ingestion

Composition / Information on Ingredients

Active Ingredient: Iprodione — 97%
Other Ingredients: Inert components to 100% (proprietary blends vary by formulation)
Purity: Technical grade above 95% purity
Impurities: Trace levels of production byproducts
Molecular Formula: C13H13Cl2N3O3
Molecular Weight: 330.2 g/mol

First Aid Measures

Inhalation: Remove the exposed individual to fresh air, If breathing is difficult, provide oxygen, Seek immediate medical attention
Skin Contact: Remove contaminated clothing, Wash affected area with soap and water, Get medical help if irritation persists
Eye Contact: Rinse carefully with clean, running water for several minutes, Avoid rubbing eyes, Seek medical evaluation for prolonged effects
Ingestion: Do not induce vomiting, Rinse mouth, Call a poison center or physician, Do not consume food or drink
Note to Physician: Treat symptomatically; Supportive care for irritation or systemic effects

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, foam, dry chemical, or carbon dioxide
Unsuitable Extinguishing Media: High volume jets can spread chemicals
Hazards from Combustion: May form toxic and irritating gases including carbon monoxide, carbon dioxide, hydrogen chloride, and oxides of nitrogen
Protective Equipment: Use self-contained breathing apparatus, Full fire-fighting turnout gear
Specific Firefighting Procedures: Move containers from fire area if safe, Cool storage with water spray, Do not release runoff into drains or water bodies

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, Use PPE such as gloves, goggles, and respirator
Environmental Precautions: Prevent entry into water courses, sewers, or soil
Cleanup Methods: Use non-sparking tools, Absorb with inert material like sand or vermiculite, Collect in sealed containers for proper disposal, Wash contaminated area with water, Isolate area until cleanup is complete

Handling and Storage

Handling: Avoid breathing dust, Wear protective equipment, Prevent accidental contact with skin and eyes, Do not eat, drink, or smoke while handling
Storage Conditions: Keep containers tightly closed, Store away from heat, sparks, open flame, or incompatible materials, Keep in a cool, well-ventilated area, Store away from strong oxidizers
Incompatibilities: Avoid contact with strong acids, alkalis, oxidizing agents

Exposure Controls and Personal Protection

Occupational Exposure Limits: Not established for iprodione, Follow general dust standards (e.g., ACGIH TLV for nuisance particulates)
Engineering Controls: Use adequate ventilation, Preferably local exhaust, Maintain safety showers and eyewash stations nearby
Respiratory Protection: Use NIOSH-approved dust/mist respirator
Skin Protection: Chemical-resistant gloves, Long-sleeved clothing
Eye Protection: Safety goggles or face shield
Hygiene Measures: Wash hands and face after handling, Remove contaminated clothing promptly, Launder before reuse

Physical and Chemical Properties

Appearance: White to grayish powder or crystalline solid (depending on grade)
Odor: Slight aromatic
Melting Point: 133–136°C
Boiling Point: Not applicable (decomposes before boiling)
Vapor Pressure: Very low, less than 2 x 10−6 mmHg at 25°C
Solubility in Water: Nearly insoluble (13 mg/L at 20°C)
pH: 4.0–8.0 (1% solution)
Partition Coefficient, log Kow: 2.73–3.28
Specific Gravity: About 1.3 g/cm3 (solid)
Stability in Solvents: Soluble in acetone, ethanol, moderately soluble in methanol; nearly insoluble in hexane
Flash Point: Not flammable

Stability and Reactivity

Chemical Stability: Stable under normal storage and ambient temperatures
Decomposition: Breaks down above 200°C, releasing toxic fumes
Conditions to Avoid: Excessive heat, open flame, strong acids or bases, prolonged light exposure
Incompatible Substances: Strong oxidizers, strong acids, strong bases
Hazardous Decomposition Products: May release carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides
Polymerization: Not known to occur

Toxicological Information

Acute Toxicity Oral (LD50, rat): About 2000 mg/kg
Acute Dermal (LD50, rabbit): > 2000 mg/kg
Inhalation Toxicity: Not classified as hazardous in normal conditions
Skin Irritation: Moderate irritant
Eye Irritation: Causes irritation
Skin Sensitization: May cause allergic skin response on prolonged or repeated exposure
Chronic Effects: Evidence from studies suggests possible liver and reproductive impacts in high and long-term exposure
Carcinogenicity: Classified as probable human carcinogen by some agencies based on animal evidence
Mutagenicity: Evidence suggests no genetic mutation hazard in standard tests
Reproductive Toxicity: Some adverse effects observed in animal development studies at high doses
Target Organs: Liver, reproductive system at high exposures

Ecological Information

Ecotoxicity: Highly toxic to aquatic organisms including fish and invertebrates
Persistence and Degradability: Degrades slowly in soil and water, Half-life up to 3–12 months under some conditions
Bioaccumulation: Moderate potential, Not likely to travel far in environment due to low solubility
Mobility in Soil: Low, Binds to soil particles
Adverse Environmental Effects: Potentially impacts amphibians, aquatic insects, algae
Precautions: Prevent drift and runoff to waterways during application or disposal

Disposal Considerations

Product Disposal: Destroy by incineration in approved facility, Ensure complete combustion
Container Disposal: Triple-rinse empty containers, Dispose in accordance with local regulation
Waste Code: Consult local, regional authorities for waste classification codes
Precautions for Disposal: Do not dispose in household garbage or into surface water, Discharge prohibited
Disposal Recommendation: Use all product material for intended use to minimize waste

Transport Information

UN Number: Not regulated for transport by most international standards
Proper Shipping Name: Not classified as dangerous for transport under UN, IMDG, IATA
Transport Hazard Class: Not applicable
Packing Group: Not assigned
Special Precautions: Avoid cargo movement with foodstuffs, Keep product dry and protected from heat
Labels: Environmental hazard label recommended for bulk shipments

Regulatory Information

TSCA: Listed on U.S. Toxic Substances Control Act inventory
FIFRA Status: Registered pesticide product, Label use only
EU Regulation: Approved under EU Plant Protection Products Regulation as active substance
OSHA: Not specifically regulated as hazardous chemical
SARA (Title III): Not listed as extremely hazardous, May require Tier II reporting
WHMIS (Canada): Classified as D2B — toxic / Irritant material
Other National Inventories: Listed or exempt in most industrial registries
Labeling Requirements: User must follow label directions, PPE requirements, environmental restrictions set by national authorities