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Product Name: Imidacloprid Pesticide Grade 97%
Chemical Name: 1-(6-Chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine
Synonyms: Confidor, Gaucho, Admire
Recommended Use: Agricultural insecticide
Manufacturer: Insecticide production facility or distributor, full name and address based on supplier
Emergency Contact: National emergency response hotline or local poison control center
CAS Number: 138261-41-3
UN Number: 3077
Use Restrictions: Only use for authorized crop protection by suitably trained workers
Classification: Acute Toxicity Oral Category 4, Acute Toxicity Inhalation Category 4, Eye Irritation Category 2B, Hazardous to Aquatic Environment Acute Category 1
Hazard Statements: Harmful if swallowed or inhaled, causes eye irritation, very toxic to aquatic life
Pictograms: Exclamation mark, Environment
Signal Word: Warning
Precautionary Statements: Avoid breathing dust or vapor, use personal protective gear, wash thoroughly after handling, keep out of reach of children and animals
Active Ingredient: Imidacloprid 97%
Chemical Formula: C9H10ClN5O2
Impurities: Proprietary trace impurities may be present, usually below 3%
Other Ingredients: Stabilizers and inerts as specified by the manufacturer, no hazardous contributing agents reported
Concentration Range: 97% active ingredient minimum by weight
Inhalation: Remove person to fresh air, seek medical attention for difficulty breathing, monitor for respiratory symptoms
Skin Contact: Remove contaminated clothing, rinse skin immediately with water for at least 15 minutes, use gentle soap if available, get medical help for persistent irritation
Eye Contact: Flush eyes with running water for a minimum of 15 minutes, remove contact lenses after initial flushing, contact healthcare provider right away
Ingestion: Rinse mouth thoroughly, offer water to rinse and dilute (unless drowsy or unconscious), do not induce vomiting, seek medical attention, provide product label or MSDS to medical personnel
Important Notes: Symptomatic treatment only, no specific antidote for imidacloprid poisoning, monitor vital signs
Suitable Extinguishing Media: Dry chemical, CO2, foam, water spray
Specific Hazards: May release irritating and toxic fumes of chlorine, nitrogen oxides, and hydrogen chloride gas when heated
Protective Equipment for Firefighters: Self-contained breathing apparatus, full protective gear, avoid inhalation of smoke
Additional Advice: Prevent contaminated run-off from entering waterways, cool containers exposed to fire with water spray from a safe distance
Personal Precautions: Wear chemical-resistant gloves, goggles, protective clothing, and NIOSH-approved respiratory protection
Environmental Precautions: Prevent release into drains, surface and groundwater, or soil; notify authorities if large quantities enter the environment
Methods for Cleanup: Use inert absorbent for spills, sweep carefully to prevent dust generation, collect in labeled containers for disposal, ventilate the area thoroughly, wash spill site after cleanup
Safe Handling Recommendations: Avoid dust formation, handle only with adequate ventilation, do not eat, smoke or drink during use, wash hands after exposure, keep container tightly closed
Storage Conditions: Store in original, clearly labeled container in a cool, dry, well-ventilated area, away from food, drink, animal feed, and direct sunlight
Incompatibilities: Avoid strong oxidizers, acids, and alkalis, prevent contamination with other agrochemicals
Special Storage Advice: Secure from unauthorized access, keep out of reach of children, protect from frost and humidity
Exposure Limits: No established occupational exposure limits; minimize exposure to dust and vapor
Engineering Controls: Use local exhaust, general ventilation, and enclosed processes
Personal Protection: Chemical-resistant gloves (nitrile, neoprene), goggles or face shield, long-sleeved work clothing, NIOSH/MSHA-approved respirator (for high dust areas), boots
Hygiene Measures: Avoid skin and eye contact, change contaminated clothing, maintain good industrial hygiene practices
Appearance: Off-white to light beige crystalline powder
Odor: Slight chemical odor
Melting Point: 143.8°C
Boiling Point: Decomposes before boiling
Solubility: Low in water (0.61 g/L at 20°C), moderate in polar organic solvents
Vapor Pressure: 3.7 × 10-9 mmHg at 20°C
Partition Coefficient (log Kow): 0.57
Density: 1.54 g/cm3 at 20°C
pH Value: 7.1 (1% aqueous suspension)
Stability: Stable under recommended storage, sensitive to light and alkaline conditions
Chemical Stability: Stable under normal storage and handling conditions
Conditions to Avoid: Exposure to excessive heat, moisture, strong sunlight, alkaline environments
Incompatible Materials: Strong oxidizing agents, strong acids, strong bases
Hazardous Decomposition: Chlorine, nitrogen oxides, carbon monoxide, hydrogen chloride released during thermal decomposition or fire
Reactivity: Negligible under standard conditions, avoid mixing with incompatible materials
Acute Oral Toxicity: LD50 (rat): 450 mg/kg
Acute Dermal Toxicity: LD50 (rat): >5,000 mg/kg
Acute Inhalation Toxicity: LC50 (rat, 4h): >2.1 mg/L
Skin Irritation: Mildly irritating to skin
Eye Irritation: Causes eye irritation
Sensitization: Not considered a skin sensitizer
Chronic/Long-term Effects: Studies show thyroid and liver impact in animals at high doses; not classified as carcinogenic by IARC
Target Organs: Central nervous system, thyroid gland
Other Information: High risk of poisoning via ingestion; symptoms may include headache, dizziness, confusion, nausea
Toxicity to Aquatic Organisms: Very toxic to aquatic invertebrates and fish (EC50: 0.037 mg/L for Daphnia magna)
Toxicity to Birds: Slightly toxic (LD50 quail: 152 mg/kg)
Toxicity to Bees: Highly toxic to honeybees (oral LD50: 0.0037 μg/bee)
Persistence: Moderately persistent in soil (soil half-life: 39-997 days, depending on conditions)
Bioaccumulation: Low potential for bioaccumulation in terrestrial and aquatic systems
Mobility: May leach to groundwater in sandy soils
Degradation: Mainly by microbial and photolytic processes
Other Hazards: Runoff and misapplication cause environmental concerns around nontarget insects and watercourses
Product Disposal: Dispose of in accordance with local, regional, and national regulations, preferably by incineration in an authorized facility, do not allow to contaminate waterways or open land
Container Disposal: Triple-rinse containers, puncture to prevent reuse, dispose through hazardous waste programs
Waste Codes: May be classified as hazardous waste, refer to environmental legislation
Special Precautions: Avoid release to environment, do not reuse empty containers for any purpose
UN Number: 3077
Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s. (contains imidacloprid)
Transport Hazard Class: 9 (Miscellaneous dangerous substances)
Packing Group: III
Marine Pollutant: Yes
Special Transport Precautions: Protect against physical damage, keep packaging intact, comply with all local and international transport regulations, emergency notification for spillage or leakage in transit
Regulatory Status: Subject to regulation under national pesticide laws
US EPA Registration: Registered under FIFRA; specific label requirements apply
EU Classification: Approved active substance, subject to Annex III regulations
Label Elements: Signal word, hazard statements, pictograms, precautionary statements must appear clearly
Community Right-to-Know: Listed under SARA Title III Section 313 (if in US jurisdiction)
Other Regulations: Compliance required under applicable worker protection, environmental, and chemical safety rules
Additional Information: Product labeling must include hazard, environmental, and disposal guidance, and emergency phone numbers
