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Material Safety Data Sheet for Furametpyr

Identification

Product Name: Furametpyr
Chemical Family: Pyridine derivative
Recommended Use: Agricultural fungicide
Chemical Formula: C13H10Cl2N2O
CAS Number: 119730-20-8
Manufacturer: Contact details available from regulatory sources
Emergency Phone: National chemical emergency response center

Hazard Identification

GHS Classification: Acute toxicity (oral) category 4, skin and eye irritant
Hazard Statements: Harmful if swallowed, causes skin and eye irritation, may cause respiratory irritation
Signal Word: Warning
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing dust, wash hands thoroughly after handling, use protective gloves and eye protection, do not eat, drink or smoke when using
Other Hazards: Avoid release to the environment, may contaminate water sources

Composition / Information on Ingredients

Active Ingredient: Furametpyr (≥95%)
Impurities: Organic solvents (trace), technical-grade stabilizers (trace)
Synonyms: 2-[2-(2,4-dichlorophenyl)-3-pyridyl]oxyacetaldehyde oxime
Formulation: May appear in emulsifiable concentrate or wettable powder, depending on commercial product

First Aid Measures

Eye Contact: Rinse cautiously with water for at least 15 minutes, seek medical advice promptly
Skin Contact: Remove contaminated clothing and thoroughly wash skin with soap and water, seek medical attention for irritation
Inhalation: Move the person to fresh air, keep comfortable, consult a physician if symptoms persist
Ingestion: Rinse mouth, never give anything by mouth to an unconscious person, seek medical help immediately
Advice for Physicians: Treat symptomatically, monitor respiratory, hepatic and renal function

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, foam, dry chemical, or carbon dioxide
Specific Hazards: Combustion can generate toxic gases such as hydrogen chloride, nitrogen oxides, and carbon monoxide
Special Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing
Additional Information: Evacuate area, prevent fire-fighting water from entering drains or watercourses

Accidental Release Measures

Personal Precautions: Wear protective equipment including gloves, goggles, and suitable mask to prevent inhalation
Environmental Precautions: Prevent uncontrolled release, do not let product enter waterways or open soil
Cleanup Methods: Contain and collect spilled material using absorbent inert material, dispose in suitable containers, keep away from ignition sources
Decontamination: Wash area thoroughly with water and detergent after material picked up

Handling and Storage

Handling: Use in well-ventilated environments, avoid contact with skin, eyes, clothing, and inhalation of dust or fumes, wash hands after use
Storage: Store in cool, dry, original tightly closed containers, keep away from foodstuffs, incompatible chemicals, and out of reach of animals and children
Specific Requirements: Avoid exposure to sunlight and heat, maintain product integrity by controlling moisture and temperature

Exposure Controls and Personal Protection

Engineering Controls: Ensure effective local exhaust ventilation, provide eye wash stations and emergency showers onsite
Respiratory Protection: Wear suitable mask if ventilation insufficient
Hand Protection: Wear chemical-resistant gloves approved for pesticide use
Eye Protection: Use safety goggles or face shield
Skin Protection: Wear protective clothing, boots, and prevent prolonged contact
Hygiene Measures: Remove work clothing before leaving site, do not smoke or eat in work zone, wash hands and face thoroughly after handling

Physical and Chemical Properties

Appearance: Off-white to light brown crystalline powder
Odor: Slight, characteristic
pH (1% dispersion): 6 to 8
Melting Point: 79-83°C
Boiling Point: Data not available for technical product
Flash Point: Not flammable in formulated state
Solubility: Slightly soluble in water, soluble in organic solvents like acetone, ethanol
Vapor Pressure: Very low at room temperature
Partition Coefficient (Log Kow): 2.4–3.1
Decomposition Temperature: Tends to break down at elevated temperatures

Stability and Reactivity

Chemical Stability: Stable under recommended handling and storage conditions
Incompatible Materials: Strong oxidizers, acids, bases
Thermal Decomposition: Produces hazardous gases including hydrogen chloride, nitrogen oxides
Reactivity: May react with other reactive organic compounds, avoid mixing with unapproved chemicals
Conditions to Avoid: Avoid high temperatures, direct sunlight, moisture ingress

Toxicological Information

Acute Oral Toxicity: LD50 rat 500–2000 mg/kg (harmful if swallowed)
Acute Dermal Toxicity: LD50 rat >2000 mg/kg (low dermal toxicity)
Acute Inhalation Toxicity: LC50 rat 2.7 mg/L/4h (irritant, not highly toxic by inhalation)
Skin Irritation: Moderate irritant
Eye Irritation: Causes moderate eye irritation
Chronic Effects: No conclusive evidence of long-term carcinogenicity, mutagenicity, or reproductive toxicity in available animal studies
Other Health Effects: May cause pulmonary, renal and hepatic stress after repeated exposure

Ecological Information

Toxicity to Aquatic Organisms: Toxic to certain aquatic invertebrates, moderate toxicity to fish (LC50 1–10 mg/L)
Toxicity to Birds/Bees: Low to moderate risk, take measures to protect pollinators
Persistence and Degradability: Slowly degraded in soil and aquatic environments, risk of bioaccumulation in aquatic systems
Mobility in Soil: Relatively low mobility, tends to bind to soil particles
Other Adverse Effects: Potential environmental hazard if large spills occur, strict control of run-off from treated fields necessary

Disposal Considerations

Product Disposal: Incinerate or dispose of through licensed hazardous waste contractor, do not discharge to environment
Container Disposal: Triple rinse, puncture and dispose of containers according to local regulations
Environmental Precautions: Avoid contamination of water bodies, soil, and sewers, follow all local environmental protection rules for agrochemicals

Transport Information

UN Number: 3077
UN Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s. (contains Furametpyr)
Transport Hazard Class: Class 9
Packing Group: III
Marine Pollutant: Yes
Special Transport Precautions: Protect packaging from rupture, segregate from food items, follow hazardous goods labeling laws and specialist carrier protocols

Regulatory Information

Labeling Requirement: GHS-compliant symbols and warning statements, hazard and precautionary details in local languages
Regulatory Status: Registration under agricultural chemical regulations in many countries, subject to strict use controls
Occupational Exposure Limits: Not established, general dust exposure standards apply
Worker Protection Standards: PPE mandated for handlers and applicators, restricted entry intervals after use
Environmental Regulation: Covered by environmental protection laws, specific guidance for storage, use and disposal from agricultural agencies
Other Requirements: Safety data sheet must stay accessible at usage site, report poisoning or spill incidents to relevant authorities