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Product Name: Ferric Citrate Dihydrate
Chemical Formula: C6H5FeO7·2H2O
CAS Number: 6042-05-1
Synonyms: Iron(III) citrate dihydrate
Recommended Use: Pharmaceutical applications, laboratory research, water treatment, dietary supplements
Manufacturer Information: Any reputable chemical supplier that offers direct sourcing and technical support
Emergency Contact: Refer to the manufacturer’s 24/7 emergency hotline for immediate assistance
GHS Classification: Not classified as hazardous under GHS criteria for most laboratory and commercial handling
Pictograms: None considered mandatory based on current evidence
Signal Word: None
Hazard Statements: Prolonged inhalation or ingestion may cause negative health effects; may irritate eyes or skin with excessive contact
Precautionary Statements: Avoid dust formation, keep out of reach of children, practice standard laboratory hygiene
Other Hazards: Individuals with iron metabolism disorders may have increased sensitivity; always maintain good ventilation
Chemical Identity: Ferric Citrate Dihydrate
Concentration: Greater than 95%
Other Components: Possible trace impurities from synthesis, water content as expected in dihydrate form
Chemical Family: Coordination complex – ferric salt
Ingredient Purity: Confirmed by supplier lot analysis and certificate of analysis documentation
Inhalation: Move to fresh air; consult physician if respiratory irritation develops; provide oxygen if breathing becomes difficult
Skin Contact: Wash skin thoroughly with soap and water; remove contaminated clothing and shoes; seek medical attention if irritation persists
Eye Contact: Rinse immediately with water for at least 15 minutes; lift eyelids occasionally; seek prompt medical attention
Ingestion: Rinse mouth thoroughly; drink water; do not induce vomiting; seek medical attention, especially if large quantities swallowed
Symptoms/Effects: May cause stomach upset, mild irritation to eyes or skin, no evidence of acute toxicity at low concentrations
Notes for Physician: Treat symptomatically, be aware of chronic iron toxicity possibilities in at-risk populations
Suitable Extinguishing Media: Use water spray, dry chemical, CO2, or foam; avoid high-pressure streams which spread dust
Special Hazards: Combustion releases irritating and toxic vapors including oxides of iron and carbon, possibly minor organic byproducts
Fire-Fighter Protective Equipment: Full protective gear including self-contained breathing apparatus
Advice for Firefighters: Control runoff to prevent contamination of waterways, remove containers from fire area if safe
Personal Precautions: Wear approved mask, gloves, protective clothing; avoid generating airborne dust
Environmental Precautions: Prevent product from entering drains, soils, and watercourses untreated
Methods for Cleaning Up: Collect powder mechanically into sealable containers; use wet cleaning methods to reduce dust; dispose following local regulations
Decontamination: Wash area with water and mild detergent, ventilate area thoroughly before reuse
Handling Precautions: Avoid contact with eyes, skin, and clothing; use in well-ventilated areas; minimize dust generation; wash hands after use
Safe Storage: Store tightly closed in cool, dry, well-ventilated area; keep away from food, acids, reducing agents
Storage Stability: Protect from moisture and incompatible materials to extend shelf life
Incompatibilities: Reacts with strong oxidizers and acids, avoid contact with reducing agents and strong bases
Engineering Controls: Employ local exhaust ventilation or fume hood in larger-scale or repeated use scenarios
Personal Protective Equipment: Chemical safety goggles, nitrile or latex gloves, lab coat, dust mask or respirator for high dust potential
Exposure Limits: No OSHA PEL or ACGIH TLV established for this compound; rely on best available guidance for nuisance particulates
Hygiene Measures: Do not eat, drink, or smoke during use; wash thoroughly before breaks and at end of shift
Physical State: Fine crystalline powder
Color: Orange to red-brown
Odor: Practically odorless
Molecular Weight: 301.97 (including water of hydration)
Melting Point: Decomposes before melting
Solubility: Soluble in water, slightly soluble in alcohol, practically insoluble in most organic solvents
pH (1% Solution): Slightly acidic, typically in the range of 2.5–3.5
Boiling Point: Not applicable (decomposes)
Density: Approximately 1.8 g/cm³
Vapor Pressure: Not applicable to solid
Flash Point: Not flammable
Partition Coefficient: Not measured
Chemical Stability: Stable under normal temperatures and recommended storage conditions
Decomposition: Releases carbon oxides and iron oxides upon strong heating
Hazardous Reactions: Strong acids and bases alter the structure; reacts vigorously with strong oxidizers
Conditions to Avoid: Excess heat, moisture, prolonged exposure to air that increases risk of product degradation
Hazardous Decomposition Products: Iron oxide, carbon dioxide, minor organic acids under severe heating
Routes of Exposure: Ingestion, inhalation, skin and eye contact
Acute Toxicity: Data from animal studies suggest low acute oral and dermal toxicity; symptoms may include gastrointestinal distress
Chronic Effects: Large or frequent ingestion has potential to contribute to systemic iron overload; people with hemochromatosis require special caution
Irritation/Corrosivity: May cause mild irritation to skin or eyes, no corrosive effects in standard exposure scenarios
Sensitization: No evidence suggests sensitization potential
Carcinogenicity/Mutagenicity: Not listed as a human carcinogen; animal studies have not flagged significant risk
Reproductive Effects: Current evidence does not show direct effects on reproductive health in recommended use ranges
Ecotoxicity: No strong data for aquatic toxicity; potential for iron compounds to impact aquatic environments if released in significant amount
Persistence and Degradability: Iron salts generally persist in environment but can undergo natural complexation and precipitation
Bioaccumulation: Little tendency for bioaccumulation in aquatic species due to poor uptake of iron complexes
Mobility in Soil: May migrate if dissolved in water; binds to soil particles, which helps limit broad migration
Other Information: Spills should be contained and cleaned to minimize impact on water and soil ecosystems
Waste Treatment Methods: Collect for disposal in accordance with local, regional, and national regulations; incineration or landfilling permitted where approved
Uncontaminated Product: Can be disposed as non-hazardous inorganic waste in most jurisdictions
Packaging: Rinse and recycle or dispose of according to applicable regulations; avoid release of dust to air
Special Instructions: Consult local environmental and safety authorities for guidance that matches specific disposal scenario
UN Number: Not classified as dangerous for transport under current rules
Proper Shipping Name: Ferric Citrate Dihydrate
Transport Class: Not regulated
Packing Group: Not assigned
Marine Pollutant: No
Special Precautions: Secure packaging to avoid breakage and minimize dust in transit
International Requirements: Not restricted under IMDG, IATA, or ADR guidelines
TSCA Status: Listed or exempt
SARA Title III: Not subject to reporting; does not contain extremely hazardous substances
REACH Registration: Pre-registered or exempt as “substance of known and controlled use” in certain sectors
Canadian DSL: Present or application for inclusion valid for industrial use
Labeling: Standard hazard and precautionary labeling encouraged for laboratory and commercial users
Other Requirements: Maintain documentation of supply chain, safety training, and workplace risk assessment according to OSHA or local safety standards
