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Disuccinoyl Peroxide: Yesterday’s Curiosity, Tomorrow’s Workhorse

Tracing the Origins and Early Curiosity

Disuccinoyl peroxide didn’t pop up in labs overnight. Its roots go back to mid-20th-century research, when organic peroxides grabbed chemists’ interest as candidates for polymerization and crosslinking. My first encounter with this compound came during a university project, sifting through dusty journals from the ’60s, made me realize how persistent the interest in manipulating reactive sites for materials science has been. Despite the rudimentary purification tools at the time, early pioneers kept pushing for higher purity, learning quickly that impurities in peroxides could lead to disastrous surprises in the lab. The leap from theory to scalable product took persistent refining of synthesis and careful documentation of each batch—mistakes here meant dangerous runaways instead of published breakthroughs.

Looking at Its Structure and Everyday Handling

At its core, disuccinoyl peroxide is a diacyl peroxide: imagine a pair of succinoyl groups linked through an oxygen-oxygen bridge. This structure looks straightforward, but those two central oxygen atoms don’t like staying together—classic source of reactivity. The molecule has a pale hue and a solid consistency just below room temperature. It’s not a material you carelessly leave near sunlight or open flames, because it doesn’t need much coaxing to break down into radicals and release energy. For someone running a bench-scale synthesis, a few minutes of inattention can turn a morning’s work into a local hazard. That’s not just theory; more than one chemist has learned respect for organic peroxides by scorched glassware or worse.

Technical Fine Print and Labeling Challenges

Shipping and labeling this compound brings its own headaches. Regulatory frameworks group it with organic peroxides because of how easily it can ignite or explode under the wrong conditions. Packages must clearly mark peroxide content, usually pushing above 72%. The color-coded hazard diamonds aren’t there for decoration—they give first responders split-second warnings if a spill or fire breaks out. In practice, producers commit to rigorous quality control, minimizing leftover reactants and stabilizing the bulk product. Years ago, I watched a friend’s startup in advanced adhesives struggle as labeling laws changed. They ended up recalling a batch that passed every technical test but tripped over a labeling detail. It hammered home how legal compliance holds real costs in chemical manufacturing.

Recipe Behind the Reagent: Making Disuccinoyl Peroxide

Producing this peroxide isn’t some esoteric art, but it demands precision. Most routes start with succinic anhydride, which gets coaxed into a reactive intermediate, then introduced to hydrogen peroxide under controlled pH. The yield depends on careful temperature management, as heat spikes favor decomposition over productive conversion. Early researchers often lost product to runaway decomposition before finally tuning their cooling and addition rates. Commercial producers scale this process with baffled reactors and aggressive chilling to avoid accidents. If you cut corners, you don’t just lose yield—you can end up with a dangerous product, unstable in transit or storage.

Chemical Reactions and Tinkering

Disuccinoyl peroxide loves to give up its central oxygen-oxygen bond, spawning free radicals in the process. This property defines its role as a polymerization initiator. Drop it into unsaturated monomers, and you trigger a cascade that stitches simple molecules into high-molecular-weight plastics. Over the decades, researchers have tinkered with substituents and mixed radical sources to control how fast the reactions run. The peroxide’s chemistry lets it introduce crosslinks or embed functional groups, giving rise to adhesives with fine-tuned properties or rubbers that set under mild conditions. That flexibility draws steady demand from industrial labs looking for that last tweak in a new material recipe. My own attempts to modulate reaction times always involved balancing peroxide loading, temperature, and stabilizer selection—a dance that rewards methodical record-keeping over guesswork.

Industry Synonyms and Street Names

Industry has never settled on one label for this material. In catalogs and on invoices, you’ll spot “disuccinyl peroxide” in addition to “disuccinoyl peroxide”. Older literature tosses out obscure systematics, but the experienced buyer knows to cross-verify structure before signing off on a purchase. Sloppy synonym use causes headaches in patent searches or regulatory filings. I’ve seen research proposals fall apart because of this, with one group chasing a ‘new’ compound only to realize they’d duplicated old work under a new moniker. Staying current with nomenclature isn’t just an academic chore; it saves real time and money in the trenches of research and compliance.

Staying Safe and Keeping Operations Smooth

Safety with disuccinoyl peroxide takes more than donning a lab coat and goggles. You need dedicated, explosion-proof refrigerators for storage, and every move gets its own risk assessment. Static discharge can ignite a poorly handled sample. Regular drills on peroxide handling have become second nature in serious labs. The material’s classification as a Category B organic peroxide in many regimes isn’t just red tape—past incidents, like warehouse fires traced back to improper peroxide disposal, showed how rapidly things can escalate. Insurance providers watch these incident rates closely. Years ago my old lab made peroxide safety a monthly training topic, after a high-profile incident at a neighboring facility. That culture shift didn’t just keep regulators happy; it kept everyone out of the emergency room.

The Places It Makes a Difference

Disuccinoyl peroxide has made its mark in plastics and rubbers. Manufacturers often rely on its ready radical generation for curing unsaturated polyester resins, an application that shows up quietly in boat hulls, car parts, and construction panels. It offers an advantage where gentle curing plus tough crosslinking matter. I’ve watched adhesive manufacturers pivot to peroxides for fast-setting epoxies, boosting productivity in assembly lines. And yet, its sharp reactivity has also inspired niche researchers in surface coatings and biomedical scaffolds, exploring new crosslinkable networks. Success stories come from teams that paired disciplined process control with creative application tweaks, not from blindly following playbooks.

What the Scientists Are Chasing

Fresh research on disuccinoyl peroxide echoes bigger trends in materials science: sustainability, custom-tailored chemistry, and greener protocols. Labs aim for higher yields with less waste, swapping out hazardous solvents for safer alternatives. Efforts in continuous flow processing show early promise in trimming both risk and energy cost. Presentations at technical conferences regularly highlight how minor formula changes can unlock new uses, like biocompatible hydrogels or smart adhesives responsive to environmental cues. Collaborative work between academia and industry speeds up the process, as startup players bring bold questions to staid chemical giants. I’ve seen once-discarded synthetic tweaks revived through computational modeling, allowing chemists to predict performance before ever mixing reagents. The energy in peroxide research today signals that despite its age, the field brims with practical and theoretical possibilities.

Examining Toxicity and Health Questions

Disuccinoyl peroxide won’t let safety officers off easy. Animal testing has flagged irritation and tissue damage at moderate exposures, and decades of industrial use have made clear that accidental inhalation or skin contact brings real health risks. Chronic effects remain less studied, a gap that advocates for tighter handling standards and deeper toxicology work. Workplace incidents have driven adoption of monitoring and real-time alarm systems to flag spills or unsafe airborne levels. Regulatory agencies, faced with new toxicological evidence, have imposed stricter exposure limits and mandated clearer hazard labeling in the last decade. Responsible manufacturers have responded with improved training, closed-system process design, and investment in personal protective equipment. These steps aren’t just regulatory box-ticking; they reflect lessons soaked in sweat, burnt equipment, and, at worst, personal injury.

Looking Ahead: The Road Yet to Travel

Tomorrow’s market for disuccinoyl peroxide won’t look exactly like today’s. Regulations grow tighter. End-users want safer, greener chemistry with less wasted energy and lower emissions. This pressure will force process innovations—greener oxidants, solid-state synthesis, and real-time in-line monitoring of purity. At every technical symposium I attend, someone’s presenting new work on taming peroxide hazards or extending lifetime without giving up reactivity. The path from benchtop experiment to full-scale adoption still leans hard on teamwork among chemists, engineers, regulators, and end-users willing to put in the hours of validation and oversight. The compound’s future depends on responsible stewardship—balancing hungry commercial demand with a duty to workers, neighbors, and the planet. That’s as true for peroxide today as it was in the musty lab notebooks of the last century.




What is the primary use of Disuccinoyl Peroxide [72% < Content ≤ 100%]?

Getting to Know What Disuccinoyl Peroxide Really Does

Disuccinoyl peroxide isn’t exactly a household name, although anyone who works with plastics, rubbers, or specialty polymers might know it well. You won’t find it on a pharmacy shelf, but in a chemical plant or plastics facility, its presence is pretty central to how a lot of goods get made. For anyone who’s gotten a new car, handled a rubber tool, or picked up some clean, tough plastic packaging, it’s likely that disuccinoyl peroxide played a background role somewhere down the line.

How This Chemical Changes the Game in Manufacturing

Most of the time, disuccinoyl peroxide becomes a key player as a free-radical initiator. That classic chemistry term basically means it’s a starter for chemical reactions, helping to kick off polymerization. You take a pile of chemical ingredients—liquids or powders that aren’t especially useful on their own—and by lighting the fuse with something like disuccinoyl peroxide, you trigger a strong reaction. That reaction links up molecules to create a solid or flexible end-product, whether it’s a plastic casing, tire, or advanced medical device.

Working in industry, folks aim for consistent results. Slight differences—too little initiator or a slip in concentration—can turn a batch into a waste of time and money. The higher the peroxide content, especially when you get above 72%, you count on more certain, controlled reactions. That’s why companies handling automotive tires or industrial hoses rely on high-content disuccinoyl peroxide: it boosts efficiency and predictability.

Why Not Use Something Else?

Some might ask if other chemicals could fill the same role. Plenty of peroxides exist, but disuccinoyl peroxide gets picked because it starts reactions at a temperature most plants are set up to handle. Some peroxides need hotter conditions and might create dangerous byproducts. Disuccinoyl peroxide’s byproducts are easier to deal with using good ventilation and standard safety gear—something every plant worth its salt already lines up.

Looking at the Safety Side

People worry about using potent chemicals, and for good reason. Disuccinoyl peroxide, like its cousins, packs a punch if mishandled. A reputable plant treats this stuff like any other strong oxidizer: staff get trained, storage happens in cool, controlled spaces, and emergency plans actually get practiced. Over the years, accidents dropped as safety protocols improved. That comes down to real investment in worker training and company-wide cultures that value health over cutting corners.

The data backs this up. In manufacturing settings with solid training and proper storage, incidents stay rare. Most issues crop up in facilities skipping the basics—ignoring temperature guidelines or overlooking personal protective equipment. Insurers and regulators both keep eyes on peroxide use. Chemical industry standards and international safety codes spell things out in detail, and following them pays off.

Looking for Greener Chemistry

Even so, no one in the field should rest easy. Green chemistry pushes for less hazardous alternatives. Some researchers experiment with new organic initiators and milder processes. Up to now, these usually cost more or work less efficiently than tried-and-true options like disuccinoyl peroxide. There’s hope that breakthroughs—maybe bio-based initiators or improved recycling tech—will eventually shrink the chemical footprint.

Until then, the best step involves keeping safety front and center, using personal experience and hard-won knowledge to avoid risky shortcuts. Working with disuccinoyl peroxide takes the right chemistry know-how, attention to detail, and respect for the risks along with the rewards. Those practices build trust with regulators and customers, and they keep the lights on in labs and factories around the world.

What are the storage and handling requirements for Disuccinoyl Peroxide?

Understanding the Real Risks

Anyone who's spent time with organic peroxides knows the uneasy silence they bring to a lab shelf. Disuccinoyl Peroxide, with its white crystalline look, hides an unstable core. I remember walking past a storage cabinet at the back of a university lab, catching sight of a peroxide warning, and feeling a small wave of respect for how something so plain could change a room’s story in seconds.

Explosions from peroxides rarely forgive mistakes. Data from the U.S. Chemical Safety Board link over 70 reported accidents each decade to mishandling these compounds. Stories from companies both big and small echo the same lesson: storage and handling shape safety outcomes more than any label or warning sign.

Temperature Dictates Safe Storage

Heat and organic peroxides don’t get along. Disuccinoyl Peroxide, in particular, struggles above 30°C. Even a slight rise speeds up its breakdown. If the chemical breaks down too quickly, things get unpredictable. Facilities using it tend to keep it at 2-8°C. A dedicated refrigerator, set aside from regular food or drink storage, works best. Constant monitoring of temperature makes sense, because summer power outages or careless unplugging can ruin a week’s work and endanger lives.

Direct sunlight belongs out of the equation. Even windows that let in filtered light can heat up a container over time. Keep the bottle away from windows, radiators, and machinery that warms nearby air.

A Container Tells Its Own Story

Paying attention to containers speaks volumes. Manufacturers seal Disuccinoyl Peroxide in vented, non-metal packaging to guard against pressure build-up. Regular checks for cracks or swelling mean everything. If I spot a bulging container, I never hesitate to call the safety officer or chemist running the space. That action can stop a fire or worse.

Metal shelves seem sturdy, but corrosion from slight peroxide leaks turns them into safety hazards. Painted wood or dedicated plastic shelves hold up better in environments using these chemicals.

Packing and Handling on Human Terms

Moving Disuccinoyl Peroxide means thinking ahead. My old supervisor insisted on every transfer involving a chemical-resistant tray, thick nitrile gloves, and goggles. Open bottles only when the room is well-ventilated. Never use open flames or sparks near the material—not even a hot plate left running in the same room.

Each person in the lab or warehouse should know what to do if the chemical spills. That means easy access to spill kits, safe neutralization methods (often water and inert absorbent materials), and a culture where reporting a near-miss doesn’t mean blame or trouble.

Label every bottle clearly. Do not trust that the original label will survive three months in a fridge mist. Re-label as needed with fresh tape and a marker that doesn’t wash away with condensation.

Nobody Works Alone

Experts from the National Fire Protection Association and local fire marshals recommend regular training sessions. Even people who never touch Disuccinoyl Peroxide directly deserve a run-through of what’s stored nearby.

Relying on memory brings risk. Structured checklists and logs for checking containers, logging usage, and noting disposal dates help spot trends and small problems before they stack up. Safety grows from routines and open conversations, not lucky streaks.

Respect the material, lean on best practices, and share stories about close calls. Those habits make the difference in every setting where Disuccinoyl Peroxide stands behind a door.

What are the potential hazards and safety precautions when working with this product?

The Real Risks of Working with Chemicals

Everybody knows someone who’s had a close call in the lab or on the shop floor. Chemicals can surprise even the careful folks, turning routine jobs into dangerous ones. I’ve watched a skilled coworker get distracted once and nearly cause a spill just because the bottle looked like water. Familiarity breeds a little too much comfort around hazardous products. For me, constant reminders help keep the risks front and center. It’s worth running down the key hazards before even opening a bottle.

Inhalation tops the list. Vapors, dust, or fine mist from chemicals drift through the air and wind up in your lungs before you even notice them. Some solvents give you a headache right away, others sneak up with long-term effects that show up years down the road. Acids or bases splash up just from careless pouring, damaging skin and burning through fabrics. Some products ignite at temperatures lower than room temperature, putting everyone at risk if there’s a spark nearby.

Physical Hazards

Fire risk sits at the top for a lot of products—anything flammable should be kept far from open flames and sources of static electricity. I remember an incident where a tiny spill on a warm surface ignited faster than anyone could react. Surprisingly, the worst injuries come not from big flames, but from steam and pressure when reactions happen faster than you expect. Bottles break, pressurized containers rupture, and flying glass turns an inconvenience into a disaster.

Corrosive products wear down metal benches and storage cabinets over time. Leaks spread through seals on containers, corroding whatever sits underneath. Metals that react with moisture in the air generate hazardous gases. There’s no way to spot all these dangers just by looking at a label, so staff training and experience become important safeguards.

Health Dangers

Chemicals harm people in ways that don’t show up until much later. Chronic exposure—breathing a little dust every day—can add up. Some folks end up with skin sensitivity after a single exposure; rashes stick around for months, making daily life miserable. Chemical burns never heal completely, reminding you of one wrong step long after the shift ends. A bad accident I witnessed involved someone who didn’t respect PPE guidelines, thinking a splash couldn’t possibly happen. That instant changed his approach to every job from then on.

Simple Precautions that Make the Difference

Safety gear changes the story. Gloves, goggles, and lab coats form the basics. Make sure they fit properly—oversized gloves snag or tear, and loose coats dip into liquids. Staff need spaces with good ventilation. Opening windows doesn’t cut it for volatile chemicals; fume hoods and proper extraction fans do a better job. Decent spill kits near work areas allow quick action, and training means no one wastes time wondering what to do.

Reading labels matters, but understanding the data sheets helps you know exactly what you’re handling. Stores organize products by risk class, so incompatible materials don’t sit together—oxidizers away from organics, acids far from bases. Every worker should walk through emergency showers and eyewash stations as part of their first-day training. I’ve seen lives saved by people who knew exactly how to reach those showers.

Communication beats complacency. Sharing experiences, pointing out small spills, and checking in on each other builds a safety culture. Every day, people go home healthier because their team paid attention to these details.

How should Disuccinoyl Peroxide be disposed of properly?

Understanding the Nature of the Chemical

Disuccinoyl peroxide often finds its way into research labs, manufacturing plants, and specialty chemical storage because of its active role as an oxidizer. Just seeing the word "peroxide" brings to mind explosions, fires, and unexpected reactivity. I remember working in a university lab where chemical storage rules were drilled into everyone, and we treated any container labeled “peroxide” as if it could bite.

This compound isn’t like regular household chemicals you pour down the drain and forget about. It breaks down into more dangerous substances and can catch fire. The EPA, OSHA, and local fire departments don’t only recommend caution—they demand it. Turn your back on peroxide disposal rules, and you’re risking more than just a slap on the wrist; you put hands, eyesight, and the community at risk.

Why It Matters

Ignoring proper disposal can release toxins into the environment, where water and soil contamination persists. People fishing downstream won’t realize the tiny residue left by one careless act. It takes decades for certain soil contaminants to clear, and sometimes they simply never go away.

Stories of lab fires, “spontaneous combustion incidents,” and chemical leaks don’t write themselves. Personal experience helps here—watching a minor spill foam and hiss convinces you that all those safety guidelines grew out of real disasters, not just committee meetings.

The Right Steps for Safe Disposal

Responsibility starts simple: never toss peroxide down the drain or into regular trash. Well-ventilated rooms, isolation from other chemicals, and proper containers matter. Specific chemical waste bins keep even a tiny bottle from turning into tomorrow’s emergency. Most organizations keep those containers labeled and locked away. It’s standard practice in every reputable lab.

Trained professionals handle the final disposal. This often means contacting a licensed hazardous waste contractor. These folks understand what happens if volatile peroxides mix with something combustible. Several years ago, our local contractor arrived in an insulated truck, wearing goggles and thick gloves, ready to neutralize a crate of expired chemicals. The process includes chemical stabilization, dilution, and transport to specialized incinerators designed to handle reactive waste.

Legal Rules and Community Impact

By law, businesses must account for every ounce of hazardous waste and log the storage time. The Resource Conservation and Recovery Act draws a line in the sand: don’t mess around with uncontrolled disposal. If caught, fines aren’t the real problem—harm to neighbors, wildlife, and future generations counts for a lot more.

Anyone who works around these chemicals has seen the stern faces during safety meetings. The message is clear: hazardous waste carriers carry expertise and insurance for a reason. Mistakes lead to chemical burns, air quality violations, or worse.

Alternative Solutions: Don't Accumulate, Donate

Keep stock low. Only order as much as needed, and clear out expired chemicals regularly. Some research groups and educational programs set up chemical-sharing arrangements. If a bottle’s unopened and unexpired, outreach happens. Re-use prevents waste and cuts costs, a benefit for budget-tight organizations.

Above all, education works. The more people know about risks and safe disposal, the less likely these chemicals wind up where they shouldn’t. Put safety over convenience. The daily practice of safe handling, quick reporting of expired stock, and regular training pays off. This is how one small action prevents the next headline about a chemical mishap in your town.

What emergency procedures should be followed in case of accidental exposure or spillage?

Acting Fast Saves Lives

Every worksite, school lab, or home garage with chemicals carries a real possibility of accidental spills or exposure. In a world where we often store strong cleaners under sinks and use paint thinners in garages, most people only think about chemical safety when something goes wrong. I remember reaching for a bottle of bleach as a kid, tipping it over and panicking from the smell. My mother ran water over my hand right away and called for help—not just scrubbing at the mess but getting air in the room and finding the label for instructions. That early lesson stuck with me.

Clear Heads, Quick Steps

The first step always comes down to assessment. Got the label? Grab it and check for instructions, but don’t freeze if panic rises. If someone gets a chemical splash in their eyes, time matters more than anything. Get them under running water and flush their eyes for at least 15 minutes. Skin contact with acids or bases means clothing must come off—don’t worry about modesty, worry about saving skin. Anything soaked through can burn fast.

Inhaling fumes or powder brings danger just as quickly. Move outside, or at least get to fresh air—open doors, crank windows, switch on a fan. Folks often hesitate, fearing embarrassment. A chest filled with strong chemical air leaves no time for pride. Call for medical help right away if there’s any doubt.

Don’t Touch That Rag

Trying to wipe up mercury or unknown liquids directly is a shortcut to more trouble. Standard paper towels can make a puddle worse, especially with mercury or strong acids. Granular absorbents work for oil-based spills, while some chemicals call for neutralizers found in proper spill kits. Every workshop should have a kit, not just a mop. I once saw a friend try to soak up paint thinner with newspaper, not knowing that heat and chemical fumes meant a fire risk. That mistake could have ruined more than a workbench.

Check where the liquid spreads—keep it from drains to stop water contamination. Toss contaminated clothing in sealed bags, and label them. Spilled chemicals on hard surfaces need neutralization, often with baking soda for acids or vinegar for bases. I learned firsthand that guessing doesn’t cut it; once, thinking “soap and water fixes all,” I spread a chemical stain across concrete, creating a wider hazard.

Reporting and Learning

After a spill, people want to get back to normal, often skipping reports or learning nothing beyond getting stains out of their shirts. Reporting every incident leads to stronger safety measures. Training sessions—sometimes just fifteen minutes long—bring huge benefits by drilling the right response into memory. Some companies offer emergency eye wash stations and showers, but these only work if everyone knows where to find them mid-crisis. Keeping emergency numbers posted might sound old-fashioned, but in a soaked or panicked moment, smartphones slip or die.

Having plans makes a spill less scary. Regular practice drills keep the steps sharp: check the area, treat the exposed, use the kit, report, clean up. One strong experience or a little training can turn a routine day into a safe outcome, instead of a trip to the ER.

Knowledge Beats Panic

Memorizing basic first aid with chemicals should sit with the same importance as learning to stop, drop, and roll for fire. The right actions prevent damage, send folks home safe, and stop a bad day from turning tragic. Sharing stories, running drills, keeping clear procedures—these simple steps make all the difference.

Disuccinoyl Peroxide [72% < Content ≤ 100%]
Names
Preferred IUPAC name disuccinoyl peroxide
Other names Bis[3,5-dioxo-1,2,4-trihydroxycyclohexyl] peroxide
Disuccinoyl peroxide
Pronunciation /daɪˌsʌk.ɪ.nɔɪl pəˈrɒk.saɪd/
Identifiers
CAS Number [19910-65-7]
Beilstein Reference 1147791
ChEBI CHEBI:87761
ChEMBL CHEMBL2290229
ChemSpider 20318178
DrugBank DB16968
ECHA InfoCard ECHA InfoCard: 102037-328-3
EC Number 207-337-4
Gmelin Reference 1141377
KEGG C18769
MeSH D016628
PubChem CID 25329
RTECS number WL5950000
UNII 20M1DC0EUV
UN number 3106
Properties
Chemical formula C8H10O6
Molar mass 370.2 g/mol
Appearance White crystals or powder
Odor Odorless
Density 1.31 g/cm³
Solubility in water Insoluble
log P 2.15
Vapor pressure 0.68 hPa (20 °C)
Magnetic susceptibility (χ) -0.83e-6 cm³/mol
Refractive index (nD) 1.510
Viscosity Viscous liquid
Dipole moment 2.05 D
Thermochemistry
Std enthalpy of formation (ΔfH⦵298) -546.9 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -1685 kJ·mol⁻¹
Pharmacology
ATC code D01AE09
Hazards
Main hazards Heating may cause a fire or explosion; causes serious eye irritation.
GHS labelling GHS02, GHS07, GHS08
Pictograms GHS02, GHS05, GHS07
Signal word Danger
Hazard statements H242, H302, H332, H335
Precautionary statements P210, P220, P234, P280, P302+P352, P304+P340, P305+P351+P338, P312, P332+P313, P337+P313, P370+P378, P411+P235, P420, P501
NFPA 704 (fire diamond) 3-4-2-W
Flash point 41 °C (closed cup)
Autoignition temperature 90 °C
Explosive limits Lower: 2.6% ; Upper: 7.2%
Lethal dose or concentration LD50 Oral Rat: 690 mg/kg
LD50 (median dose) LD50 (median dose): Oral Rat 844 mg/kg
NIOSH UN3108
PEL (Permissible) PEL: Not established
REL (Recommended) 160 kg/drum
Related compounds
Related compounds Di-tert-butyl peroxide
Benzoyl peroxide
Dicumyl peroxide
Acetyl peroxide