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Cyclohexanone Peroxide [Paste, Content ≤ 72%]: A Hard Look at Its Past, Present, and the Road Ahead

Historical Development: From Laboratory Curiosity to Industrial Powerhouse

Cyclohexanone peroxide didn’t arrive overnight. Back in the early days of organic chemistry, researchers started noticing the energetic properties of peroxides. Around the mid-twentieth century, when the chemical industry grew hungry for new catalysts and curing agents, scientists turned their attention to cyclic ketone peroxides. Making cyclohexanone peroxide wasn’t glamorous at the start—it took years of trial and error, plenty of ruined glassware, and even more patience. Chemists realized early on that this compound, by forming bridged peroxide bonds, offered a blend of potency and manageability hard to find in other industrial peroxides. Since then, this chemical found its place in companies running composite production lines, cure shops, and polymer modifications.

Product Overview: An Unassuming Paste, Packing a Punch

Everybody imagines giant drums of liquid or barrels of powder when thinking about industrial chemicals, but cyclohexanone peroxide usually comes as a paste, often stabilized, and rarely exceeding 72% content for safety reasons. It doesn’t look all that remarkable—white, sticky, and often giving off faintly pungent fumes. Still, this unremarkable appearance hides substantial energy. In resin curing and composite manufacture, low viscosity lets the paste blend well into unsaturated polyester resins. Years on the factory floor have shown me that even seasoned operators treat each drum of this stuff with respect; a little can go a long way. Factor in its reactivity, and you’ve got a substance that, while controlled in form, delivers impressive results down the production line.

Physical & Chemical Properties: Dangerous Charm in a Sticky Form

Cyclohexanone peroxide, especially in paste up to 72% content, brings a special mix of volatility and convenience. The paste looks fairly innocuous to the untrained eye—thick, white, or off-white, with a somewhat greasy touch. The odor stings the nose a bit, hinting at its reactive oxygen content. Volatility and sensitivity don’t just exist on paper. Work crews know if you heat it or knock it around, that sticky paste can turn dangerous fast. Stability drops off as content climbs, which means suppliers tend to keep the active concentration on a short leash. Store it in a cool spot—preferably in small batches—because temperatures above 30°C increase the risk of runaway decomposition. Even left alone, contact with iron or copper speeds things up; it starts reacting, sometimes violently, so experience led to using tools and drums free of those metals.

Technical Specifications & Labeling: Labels Protect More Than Just the Law

You won’t see this stuff shipped casually. Transport labels warn about peroxide content, paste form, batch date, and recommended storage. Regulations set strict thresholds. Most regions call for clear hazard diamonds, warnings about explosive risk, and chemical-resistant packaging. These labels do more than tick regulatory boxes—they remind handlers, truckers, and warehouse staff that a paste now can become a projectile under the right (or wrong) conditions. Handling instructions based on hard-won experience carry equal weight to the legal phrasing: “Keep cool. Use only with proper PPE. Keep away from sparks and heat.” Many a seasoned plant manager’s signature has hung on a training document because ignoring those labels always leads to stories best left untold.

Preparation Method: Practical Chemistry Meets Industry

Production rarely gets talked about outside chemical engineering circles. Cyclohexanone peroxide comes from a reaction of cyclohexanone with hydrogen peroxide, often in the presence of an acid catalyst. Stirring the mixture under controlled temperature forms a range of oligomeric peroxides, many of which blend into a thick paste. It sounds straightforward, but controlling side products and runaway reactions demands expert knowledge. Temperature spikes, contamination, and concentration errors all spell danger. Working shifts in industrial chemistry, I saw more than one scaled-up batch go sideways due to impatience or shortcutting standard practice. The extra time spent on stringent pH controls and laddered dosing of peroxide makes a real difference, not just to paperwork but to tangible safety and end product performance.

Chemical Reactions & Modifications: More Than Just a Curing Agent

While cyclohexanone peroxide’s primary job involves initiating radical polymerizations, especially for curing polyesters and other synthetic resins, its chemistry opens up wider doors. Peroxides act as strong oxidizers and, with the right tweaks, handle other synthetic transformations, although commercial use in this area stays rare due to cost and danger. Modifications often occur at the supplier stage, blending the paste with phlegmatizers or stabilizing compounds to drop its sensitivity. Technicians know every formulation tweak impacts speed, strength, and finish when working in composite manufacturing or resin shops. While research tries to dial up selectivity, the core recipe—strong, reactive, and hard to tame—hasn’t shifted much since its initial adoption.

Synonyms & Product Names: Too Many Names for Just One Compound

Commercial chemistry breeds names faster than rabbits—cyclohexanone peroxide goes by several, depending on supplier, country, or intended use. Several distributors stick to simple trade names referencing “ketone peroxides” or “cyclohexanone paste,” with regulatory sheets listing synonyms to match customs codes or shipping registries. Chemists and safety officers on the shop floor learn the key: different names often signal minor formulation tweaks rather than new molecules. Experienced workers rarely trust a label alone—instead, they read the fine print on active content and stabilizer package. Rebranding doesn’t fool the safety protocols built on decades of blood, sweat, and training room lectures.

Safety & Operational Standards: Lessons Written in Hard Experience

Safety standards for cyclohexanone peroxide reflect harsh lessons. Talk to anyone who spent time in curing, resin prep, or polymer labs—they’ve all seen what happens when rules get skipped. PPE isn’t a box to tick, it’s how operators keep their skin, lungs, and eyesight. Spills get immediate attention, and storage rooms stay locked, ventilated, and cooled, day in, day out. The compound reacts violently with reducing agents or certain metals; standards insist on plastic or stainless tools and specialized containment trays. Local and regional safety boards don’t mince words, requiring operator training and cleanup drills. Incidents and near-misses often lead factories to upgrade their local rules beyond legal minimums. I remember seeing equipment checks and evacuation plans practiced more faithfully after even a minor leak; nothing politics safety rules like near-disaster.

Application Area: More Than Just a Niche Product

Most people outside the composites world think cyclohexanone peroxide is some rare specialty, but it earns its keep across industries. Walk down any factory that makes bathtubs, boat hulls, or large plastic containers, you’ll see its fingerprints in the polyester and vinyl ester curing stages. Its reactivity helps convert resins into finished products over tight production windows, and no small-scale or hobbyist alternative matches performance at commercial scale. Some specialty polymers, coatings, and adhesives find this peroxide paste essential for controlled crosslinking. Safety issues keep its use out of the hands of small operators, but, for major manufacturers, it remains a staple—provided best practices get followed to the letter.

Research & Development: Still Chasing Safer, Smarter Solutions

Research teams don’t rest in this field. At technical conferences, chemists debate new stabilizer combinations and attempts to lower the hazards without losing kick. The next leap seems close, but testing safer substitutes always runs up against reliability problems or raw material costs. In recent years, universities have published studies on microencapsulating the active compound, aiming for greater stability and easier dosing. While new processes offer promise, scaling them from lab bench to industrial floor still takes time and millions in investment. Knowledge-sharing between manufacturers and researchers has sharpened risk assessments and emergency protocols. Many shops invest in smarter delivery systems—closed-loop mixing stations and real-time monitoring—turning raw chemistry into user-driven safety improvements.

Toxicity Research: Real Risks Demand Real Respect

Nobody in the chemical world pretends cyclohexanone peroxide is harmless. Toxicity research underscores why strict protocols rule every step from delivery to disposal. Contact with skin or inhalation of vapors brings real harm, triggering burns or triggering respiratory issues. Lab animals exposed to the substance developed clear dose-dependent effects, and environmental studies show its breakdown byproducts aren’t benign. Those findings aren’t academic; every MSDS and emergency procedure reflects years of toxicology research, making sure no operator faces surprises. Waste handling changed markedly after environmental agencies flagged soil and water threats from improper disposal. All told, hard lessons—sometimes tragic—keep companies and regulators alert, driving ongoing safety culture, not mere compliance.

Future Prospects: Bridging Innovation and Responsibility

Looking forward, cyclohexanone peroxide sits at a crossroads. Industry needs its effectiveness, but public scrutiny and toughening regulations drive constant review. Many labs focus on safer derivatives and delivery systems; demand for composites and advanced polymers keeps rising, especially in renewable energy, construction, and transportation. Smart operators know staying ahead means adopting newer, safer blends and investing in staff training. Regulatory change could squeeze traditional paste formulations, edging companies toward more stringently stabilized blends or whole new chemistries. Whoever leads that innovation walks a tightrope between breakthrough and backlash; only a mix of science, hands-on experience, and transparency prevents repeating the hard lessons of the past.




What are the main uses of Cyclohexanone Peroxide [Paste, Content ≤ 72%]?

Pushing Boundaries in Composite Manufacturing

Cyclohexanone peroxide paste, especially at concentrations up to 72%, plays a key part in the manufacturing world. My time in a boatyard gave me a real appreciation for the effect of small chemical compounds like this. Even a single teaspoon mixed wrong could shape the outcome of an entire fiberglass hull. In composite workshops—making boats, car bodies, or advanced sporting goods—the paste finds its place as a potent curing agent. It starts the hardening process for polyester and vinyl ester resins, locking fiberglass and other reinforcements together.

Manufacturers rely on this compound because it gets the reaction moving at temperatures lower than many other hardeners. That saves energy. Veteran machinists reach for cyclohexanone peroxide paste when they want quick, predictable curing—even when ambient conditions shift, like a chilly morning or a humid afternoon. That kind of reliability often keeps whole production lines marching forward.

Sculpting the Building Blocks for Modern Infrastructure

Fiberglass pipes running through power plants or wastewater systems owe much of their strength to this peroxide. Construction teams choose the paste for its strong kick, shaping tough, corrosion-resistant pipes without the need for heavy heat. This approach means less downtime on big projects and fewer headaches for engineers worried about brittle seams a decade down the line.

Wind turbine blades—those massive, elegant arms on wind farms—often depend on cyclohexanone peroxide paste. Technicians trust it to cure thick composite layers and reduce bubbles or weak spots. In such work, real-world experience counts, and workers learn quickly how a good hardener can make or break a project meant to last through storms and high winds.

Risks and Realities in Factory Settings

Chemical safety teams talk about cyclohexanone peroxide paste with no small amount of respect. The concentrated form carries a punch—touching it without proper gloves or letting it splash on skin can bring burns. In poorly ventilated rooms, fumes build up. That spells a direct threat to the lungs. I’ve watched coworkers follow strict checklists, always storing the containers in cool, stable places, separated from acids or flammable solvents. These steps aren’t just rules; they’re habits born out of the harsh lessons that come from accidents on the shop floor.

Some plant owners invest in automated mixing and dispensing systems. This takes the guesswork out of measuring and limits the need for direct human contact. But not every shop can afford big investments, so training stands as the main shield. Safety posters, spill kits, fire extinguishers, and constant reminders around storage areas help keep everyone focused.

Balancing Innovation and Responsibility

Cyclohexanone peroxide paste drives industries that shape how cities grow and how people travel. But with this power comes a need for strict discipline. Following safety data sheets, providing ongoing education, and giving workers a voice in planning—these are the things that keep production steady and workplaces safe.

Better packaging, clearer labeling, and reliable supply chains can shield smaller workshops from surprise shortages or handling mistakes. Research into alternative curing agents could ease some hazards, but so far, few match the paste’s combination of speed and strength. That makes smart, careful use an ongoing priority, especially for teams who build the backbones of modern infrastructure.

What safety precautions should be taken when handling this product?

Understanding the Real-Life Risks

Walking into a storeroom filled with barrels, bottles, and boxes of chemicals always reminds me of how serious safety really is. Growing up, I spent summers helping out in my uncle’s auto shop, and more than once, he told stories about someone getting careless with degreasers or solvent tanks. He always drilled into us—never trust a container just because it’s closed, never skip gloves because “it’s just a wipe.” Many workplace accidents tie back to shortcuts or assumptions, not equipment failure.

Reading Labels Isn’t Optional

Every container comes marked up for a reason. Those labels hold the chemical names, the dangers, and the emergency info you hope never to need. Back in college, we had a neighbor who mixed up cleaning products, ended up coughing from the fumes all night. He never read the labels, just wanted the job done fast. People don’t always realize how dangerous everyday items become if mixed or handled carelessly. The label is there to protect you and the folks standing nearby.

The Importance of the Right Gear

One lesson people often learn the hard way: gloves, goggles, and masks aren’t just for show. I helped in a paint shop briefly—without safety glasses, paint thinners burned my eyes worse than cutting onions. Nitrile gloves and heavy boots save skin from nasty burns and keep feet dry if something spills. For anything caustic or volatile, putting on the right protective gear takes less than a minute but can save months of recovery time or a trip to the ER. OSHA and the CDC document cases every year where simple safety steps get skipped, leading to hospital visits that most of us can easily avoid.

Ventilation Keeps You Breathing Easy

Working with products that give off strong fumes turns a closed space dangerous fast. I remember helping refinish floors in an old building—one guy ignored the open window policy and went home with a splitting headache that lingered for days. Proper airflow matters. Most safety data sheets spell out ventilation needs, and anyone handling chemicals inside should jump at the chance to open a window, set up exhaust fans, or work outdoors whenever possible. Respirators help, but clean air beats filter masks every time.

Storing Products With Common Sense

Not every hazard comes from the product itself—sometimes it’s about where and how things get stored. Stacking heavy drums loosely, leaving them near heat or direct sunlight, or storing acids and bases next to each other creates a recipe for disaster. My high school chemistry teacher made us memorize what not to keep side by side. One mistake with storage, and you may face pressure buildups, leaks, or explosions. Fire-proof cabinets and secondary containment trays keep households, schools, and businesses from facing unplanned emergencies.

Knowing What to Do in a Pinch

Cleaning up a spill feels stressful, especially if harsh chemicals burn through gloves or stain the floor. Keep spill kits within arm’s reach. Know where rinsing stations or eyewash fountains sit. Emergency contact numbers for poison control or local clinics belong right on the wall, close to where risks run high. Training sessions might seem repetitive, but forgetting how to respond during an emergency wastes precious seconds. According to the National Safety Council, workplaces with regular drills report far fewer serious injuries.

Better Habits Mean Fewer Accidents

Relying on routines, double-checking before pouring, and respecting every warning label helps keep everyone safe. Small precautions—like washing hands after handling bottles or following storage charts—don’t take extra time once they become habit. Every near miss and scraped knuckle I’ve seen in shops or labs could have been prevented by slowing down for safety. Sharing stories, staying vigilant, and never becoming complacent around hazardous products keeps the workplace steady and people healthy.

How should Cyclohexanone Peroxide [Paste, Content ≤ 72%] be stored?

Everyday Responsibility with a Powerful Chemical

Cyclohexanone peroxide in paste form sits in a class above many chemicals found at work or in research labs. A maximum content of 72% puts it into a high-risk category. A mistake here rarely brings minor issues—it can mean real, lasting harm. I’ve worked in labs and factories where a slip in chemical storage cost weeks of production, even sent people to the hospital. These problems rarely come from ignorance; most-times the small shortcuts or “I’ll-put-it-back-later” attitudes set disaster in motion.

Understanding What We’re Working With

At this concentration, cyclohexanone peroxide reacts violently with heat, friction, or contamination. There is nothing forgiving about it. Mixing up this paste with a less volatile substance gets people into trouble and puts property at risk. In my experience, memory lapses and poorly labelled containers remain the biggest sources of danger. So, right from the outset, clear labelling and separated storage space play the most important roles in safety.

Choosing the Right Storage Space

The best way to store cyclohexanone peroxide paste means two things: controlled temperature and strict isolation. Direct sunlight or even general warmth from a furnace near a shelf turns this material lethal. On construction sites or in university workrooms, I’ve come across too many chemicals sharing dark, muggy closets behind old equipment. That sets up conditions for slow decomposition and possible explosion. Good practice calls for a cool, dry location—somewhere between 2°C and 8°C. Many facilities keep temperature logs beside storage for this reason. Checking those logs once or twice a day proves far more convenient than dealing with an insurance claim or hospital report.

Security Can’t Slip

Access control doesn’t just protect the chemical—it protects everyone nearby. Chemists and managers should keep paste like this in a locked area. Only trained staff should sign out materials, and every departure logged. I’ve seen security breaches from unlocked storage, and half the time the people inside didn’t realize what they’d done until the damage started. Sign-in sheets and locked cabinets sound basic because they work. At places I trust, double-keyed storage remains the norm.

Containers Matter

Original, UN-approved containers with clear hazard markings stop many cross-contamination issues before they even start. Transferring the paste, except where absolutely necessary, invites trouble. My earliest years in a production lab taught me how reused or ill-fitting lids lead to slow leaks, paste drying onto the outside and, eventually, secondary reactions on contact with metal or rags tossed in trash bins. After one serious accident, our team switched to rigid routines: always store in dedicated containers; never improvise with what’s at hand.

Preparedness Makes a Real Difference

Emergency plans around the storage location help too. Every facility where I have worked keeps spill kits and fire extinguishers fitted for peroxide-type fires close at hand. Nearby, emergency phone numbers hang on the wall, not buried in a book. An open conversation among staff, regular safety drills, and practical training in cleanup changed attitudes more than any memo. These steps grow culture; they aren’t a nuisance, they end up saving lives and time.

What are the potential hazards associated with this chemical?

Chemicals in Daily Life

Chemicals run the show everywhere we look—from bleach under the sink, to gasoline at the gas station. A lot of folks use things like paint thinner or cleaning agents every week, not thinking about the warning signs on the label. The problem is, even the products people trust can have pretty real risks. For instance, take something common like ammonia—breathing it in stings your nose and can trigger a nasty cough. Forget to crack a window, and your eyes start to burn or water. If someone mixes ammonia with bleach, a toxic gas forms almost instantly, which can cause lung damage or leave a person gasping for air.

Serious Health Risks

Getting chemicals on your skin might seem like a minor annoyance, but too much exposure can cause serious burns or trigger allergies. A bit of gasoline splashed on your hands may dry out the skin or cause redness, but long exposure or breathing vapors in a closed garage can harm the nervous system or even put your kidneys at risk. Back at school, I saw kids learn the hard way that missing gloves or goggles could turn a quick science project into a trip to the nurse’s office. Safety instructions matter for a reason—a moment’s carelessness can have long-term consequences.

Inhalation and Chronic Exposure

Working around chemicals for months or years brings a different challenge. Regular exposure to small quantities—think dry cleaning, car repair, or agriculture—can slowly break down lung function or trigger asthma attacks. The National Institutes of Health reports that chemicals like benzene, found in fuels and solvents, link to higher risks of leukemia and immune system disorders. On farms, pesticide drift can land in neighboring yards, endangering children and animals far from the original field.

Environmental Impact

Spill a chemical in the backyard or pour leftovers down the drain, and the effects show up far beyond the initial mess. Fertilizers and weed killers often end up in rivers, feeding algae blooms that choke out fish and foul up drinking water. After storms, storm drains carry runoff straight into lakes and reservoirs. It’s not just some issue for scientists far away—families nearby rely on those water sources every day.

Simple Ways to Stay Safe

Paying attention to labels and directions makes a real difference. Gloves, masks, and good ventilation remain basic but often skipped steps. Anyone handling strong chemicals should think twice about tossing rags or empty jugs in the trash where they could spark fires or leak fluids. Community drop-off days for hazardous waste keep toxic leftovers out of landfills. Schools now push safety drills before letting kids touch so much as a test tube, which cuts down on injuries and smelly disasters.

Real Solutions Need Respect and Knowledge

Staying safe with chemicals shouldn’t be a guessing game. People trust companies and public agencies to give clear, honest information through safety sheets, recall notices, and classroom training. Doctors and emergency workers push for better education on what to do in case of spills or exposure. Knowing the facts gives families control over their own safety. Sharing those lessons at home, at work, and in schools means fewer accidents and better long-term health—without giving up the benefits that chemicals bring to modern life.

How do you properly dispose of Cyclohexanone Peroxide [Paste, Content ≤ 72%]?

The Risks Behind Cyclohexanone Peroxide Paste

Cyclohexanone peroxide paste takes top marks on the “handle with care” list. Topping out at 72% concentration, this chemical reacts easily and packs a punch in terms of stability risks. I’ve seen jars of this stuff labeled with every hazard sticker you can imagine. If you ever spill it, call the fire department — that’s how unpredictable it proves.

Good management of chemicals like this doesn’t just protect lab coats or expensive flooring. It guards against injuries and keeps local environments safe. Real talk: I’ve heard of folks suffering serious injuries just trying to clean up a spill because they underestimated how volatile this paste behaves. Industrial accidents involving organic peroxides like this compound, especially those cited by the U.S. Chemical Safety Board, often have roots in poor disposal and storage decisions.

No Shortcuts: Legal and Practical Steps

Tossing cyclohexanone peroxide paste in the garbage or pouring it down the drain isn’t only illegal in many places — it sets up dangerous situations. Ordinary trash crews won’t wear splash goggles and flame-resistant gear. Wastewater treatment plants aren’t built to neutralize this chemical. So this isn’t just a regulatory thing; it’s about not endangering others. If you don’t think it matters, look at the EPA fines handed down for dumping hazardous waste the wrong way.

The key to safe disposal centers on licensed hazardous waste management. There’s no workaround: anyone who handles this chemical regularly, from school labs to big manufacturing plants, should set up an agreement with a qualified hazardous waste handler. These professionals have the equipment to neutralize and destroy compounds like this, usually through methods such as controlled incineration. I’ve relied on waste contractors before, and their experience handling reactive chemicals makes a real difference — they show up in airtight suits, and every step gets logged from pickup to destruction.

Storing Until Disposal Day

Let’s say you’ve got unused peroxide in the back storage. Keep it away from heat, sunlight, and anything made of metal that could spark a reaction. Store the paste in original, vented containers marked with clear hazard labels. Even if disposal happens soon, all employees should know where this material gets stored, and that no one messes with it without proper training. Every year, accidents happen just because someone moves the wrong jar.

Training, Documentation, and Ongoing Safety

Regular safety drills and chemical handling training save more than money. I remember one fire drill where the “worst-case” scenario involved a leaking peroxide container. That practice helped the team keep cool when a real leak happened a year later — and nobody got hurt. Written protocols and Safety Data Sheets (SDS) should always be within reach. Supervisors should keep logs of every time the peroxide gets used, transferred, or disposed of. Regulatory bodies like OSHA require this kind of record keeping, and for good reason.

Answers Don’t Stop at Compliance

People have more questions about hazardous chemicals today, and for good reason. Proper disposal practices don’t just tick off the compliance box; they reflect a mindset that values safety over shortcuts. Consulting with a certified waste disposal contractor remains the rule—not just a suggestion. Stay updated on local and federal rules, and always treat safety protocols as the non-negotiable minimum. Anyone taking on the job of disposing of cyclohexanone peroxide paste owes it to their team, and their community, to do things the right way, every time.

Cyclohexanone Peroxide [Paste, Content ≤ 72%]
Names
Pronunciation /ˌsaɪ.kloʊˈhɛk.səˌnoʊn pəˈrɒk.saɪd/
Identifiers
CAS Number 6846-50-0
Beilstein Reference 107119
ChEBI CHEBI:82808
ChEMBL CHEMBL1201207
ChemSpider 10290033
DrugBank DB11512
ECHA InfoCard ECHA InfoCard: 100.033.693
EC Number 202-877-0
Gmelin Reference Gm. 147404
KEGG C00800
MeSH Peroxides
PubChem CID 6993659
RTECS number GV7875000
UNII 906OED8I95
UN number UN3111
Properties
Chemical formula C6H10O2•xH2O2
Molar mass 114.14 g/mol
Appearance White paste
Odor pungent
Density 1.17 g/cm3
Solubility in water Insoluble
log P 0.7
Vapor pressure 0.1 hPa (20°C)
Magnetic susceptibility (χ) Diamagnetic
Refractive index (nD) 1.495
Viscosity 13.7 mPa.s
Dipole moment 2.66 D
Pharmacology
ATC code D08AX
Hazards
GHS labelling GHS02, GHS05, GHS06, GHS08
Pictograms GHS02,GHS05,GHS06,GHS08
Signal word Danger
Hazard statements H242, H302, H314, H332, H335
Precautionary statements P210, P220, P221, P234, P280, P302+P352, P304+P340, P305+P351+P338, P308+P313, P370+P378, P403+P235, P411+P235, P420, P501
NFPA 704 (fire diamond) 3-4-1-OX
Autoignition temperature 215°C
Explosive limits Explosive limits: 2.3% to 8.0%
Lethal dose or concentration LDLO oral human 357 mg/kg
LD50 (median dose) LD50 (median dose): 200 mg/kg (Rat, oral)
NIOSH SN2192500
PEL (Permissible) PEL (Permissible Exposure Limit): 1 ppm (5 mg/m³)
REL (Recommended) 1 ppm (6 mg/m³)
IDLH (Immediate danger) IDLH: 10 ppm