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Cobalt(III) Cyanide: Examining Science, Safety, and Future Potential

Historical Development

Cobalt compounds have played a role in the evolution of chemistry well before their full potential was understood. In the 19th century, researchers discovered the rich chemistry of cobalt, while the structure of cyanide complexes puzzled even the brightest scientists of the time. In my early days as a student, textbook examples of classic coordination compounds often referenced cobalt’s ability to form stable complex ions. Chemists like Alfred Werner, who laid the foundation for coordination chemistry, experimented with compounds much like cobalt(III) cyanide to figure out how metals interacted with ligands. The systematic understanding and isolation of cobalt(III) cyanide came out of this scramble to categorize and map out transition metal chemistry, often motivated by curiosity more than application. Even though cobalt(III) cyanide never landed in the headlines the way other industrial chemicals did, the work done to understand its bonding and behavior helped set the stage for the field of inorganic chemistry.

Product Overview

Cobalt(III) cyanide, a seldom spoken-about coordination complex, brings together cobalt's variable oxidation states and the potent chemistry of cyanide ligands. As a reddish-brown solid, it’s not a household name but shows up in specialized chemical applications and research laboratories. Most people won’t run into it outside of textbooks or chemical supply catalogs. It stands as a challenge for those working to balance the opportunities of coordination complexes with the need for responsible handling.

Physical & Chemical Properties

Cobalt(III) cyanide, with its deep color and crystalline appearance, doesn’t look much different from many other metal complexes at a glance. It resists solubility in water, illustrating the stable bonds formed by cobalt in the +3 oxidation state. The odorless, stable material sits comfortably at room temperature, but exposes its true nature under strong acids or heat, releasing hydrogen cyanide—a potent reminder of the chemical’s hazards. Its stability under neutral conditions builds on the tight coordination bond, an important property leveraged by chemists hoping to harness or modify its structure for complexation reactions.

Technical Specifications & Labeling

Details matter in chemical handling, and cobalt(III) cyanide requires precise attention. A label only does so much; the compound itself demands respect from anyone using it. Laboratories that use cobalt(III) cyanide often require detailed training and adherence to local and international safety protocols, underlining how regulatory and ethical standards are woven into everyday practice. From my experience, knowing exactly what’s in a bottle, understanding compatible storage materials, and safeguarding access goes beyond any sticker or document—these steps help prevent accidents and ensure responsible stewardship of potent chemicals.

Preparation Method

Synthesizing cobalt(III) cyanide doesn’t read like a casual recipe. Historically, chemists reacted cobalt compounds with an excess of cyanide under controlled oxidative conditions to get the desired +3 oxidation state. This transformation usually relied on strong cyanide solutions and an oxidizer, often oxygen or a chemical oxidant, to push the cobalt from the +2 to the +3 state. In my time working with transition metal complexes, I always noticed how redox reactions involving cyanides need a slow hand and a protected environment. Purification takes careful filtration and drying, as stray moisture or exposure can undo the product or create unwanted side products.

Chemical Reactions & Modifications

Cobalt(III) cyanide doesn’t like to stay peaceful when exposed to acids. Introduce strong acids, and the complex snaps apart, with cyanide ions reacting to form hydrogen cyanide gas—a deadly hazard in itself. On the flip side, under mild conditions, researchers use cobalt(III) cyanide’s relative inertness to probe the electronic structures and binding affinities of related complexes. Methods for substituting ligands without shattering the entire complex draw on decades of fine-tuning reaction conditions, solvent choices, and temperature control. Studying these modifications deepens our understanding of how metals and nitrogen-based ligands interact, nudging inorganic chemistry forward with each experiment.

Synonyms & Product Names

The scientific habit of naming things in multiple ways shows up clearly with cobalt(III) cyanide. Whether reviewed as cobaltic cyanide, cobalt tricyanide, or by its technical formula, Co(CN)3, the compound appears under several aliases, all pointing to the same tightly bound cyanide-coordinated cobalt core. In research circles, this can sometimes add a layer of confusion, reminding anyone handling chemicals to double-check reagents before use.

Safety & Operational Standards

Cobalt(III) cyanide serves as a glaring example of why safe handling in chemistry isn’t optional. Cyanide-containing compounds require facilities with sealed fume hoods, specialized training, and clear access to safety equipment. I’ve seen new researchers underestimate small quantities of these materials, overlooking the real dangers. Regulatory agencies issue strict guidelines on storage, labeling, and disposal, reflecting decades of tragic incidents involving similar compounds. Toxicity isn’t just a theoretical risk; inhalation of released cyanide can be fatal in minutes. Locking up supplies, monitoring air quality, and holding drills for exposure emergencies aren’t bureaucratic oversteps—they respond directly to real risks. Laboratories must enforce these standards if we hope to unlock valuable scientific insights without risking human lives.

Application Area

For those not involved in cutting-edge research, it might not be obvious where cobalt(III) cyanide fits into the world. Its value emerges in advanced materials science, catalysis studies, and as a reference compound in analytical chemistry. Researchers hunting for new catalysts often use complexes like this one as benchmarks, learning how bond structure influences reactivity. The unique electronic properties of cobalt(III) cyanide sometimes serve as models for larger biological systems, including enzyme mimics. While not a mainstream industrial chemical, its presence in both practical experiments and theoretical investigations justifies the rigorous care devoted to its management.

Research & Development

Research pushes cobalt(III) cyanide beyond the realm of simple curiosity. Chemists eager to design novel coordination polymers or networks look at such stable complexes as templates. The push to find sustainable catalysts for reactions like water splitting or organic synthesis grows fiercer each year, and transition metal cyanides stand out for their stability and tuneable properties. I’ve watched teams try to tweak ligands, oxidation states, and reaction conditions to find more effective, less hazardous alternatives to precious-metal catalysts. At the heart of good research lies the balance of potential benefit with cost, safety, and complexity. Cobalt(III) cyanide offers a sturdy foundation for those daring to explore radical new directions in coordination chemistry.

Toxicity Research

Exposure risks from cobalt(III) cyanide place it among the more hazardous compounds stocked by research facilities. The dangers of cyanide poisoning are well documented, from acute exposure symptoms to lingering long-term effects. Toxicology studies have mapped out not just immediate respiratory and cardiac collapse, but also chronic impacts from low-level cobalt exposure, running the gamut from allergic reactions to occupational asthma. Every time researchers propose a new use or experiment, safety remains central. Reliable procedures for clean-up and rigorous air monitoring help reduce but never completely remove the danger, driving ongoing studies into improved antidotes, detection methods, and safer analogs. There's a hard-won respect among the professional community for the sheer seriousness of handling such material.

Future Prospects

Chemistry moves fast, but the balance between innovation and responsibility shapes the future. Cobalt(III) cyanide could inspire safer, more effective coordination complexes for catalysis if the next generation of scientists can work out how to harness its properties without exposing workers or the environment to unnecessary risk. Advances in ligand design, safer synthetic shortcuts, or more reliable detection methods offer hope. I have seen interest in using alternative ligands to replicate the electronic structure and reactivity of classic cyanide complexes, reducing hazard while retaining function. Whether as a stepping stone to advanced materials, a reference in electronic structure research, or as a cautionary tale, cobalt(III) cyanide’s story shows how deeply technical progress depends on practiced safety, thoughtful regulation, and plain human wisdom.




What is Cobalt(III) Cyanide used for?

Digging into Specialty Chemistry

Most folks don’t bump into cobalt(III) cyanide in daily life, but that doesn’t mean it’s unimportant. Cobalt compounds, including this one, play their part in the world of chemistry and industry, though they make fewer headlines than battery metals or vitamins. Chemistry teachers like me have seen their fair share of colorful transition metal complexes, but some, like cobalt(III) cyanide, serve as more behind-the-scenes players.

Chemical Synthesis and Catalysis

Researchers turn to cobalt(III) cyanide when they need a source of highly oxidized cobalt. In the lab, it steps up as a key building block for synthesizing other compounds. Certain organic reactions rely on metals to push electrons around, with cobalt complexes helping speed things up. Some chemists experiment with it to spark reactions in pharmaceuticals, dyes, and specialized plastics.

Cobalt(III) cyanide can also act as a precursor for making other cyanide-based catalysts or coordination compounds. Its molecular shape lets chemists tinker with its structure by swapping out pieces, something essential to exploring new medicines or specialty materials.

Materials Science and Magnetic Research

People who work in materials science use cobalt compounds to explore new types of magnets or even superconductors. Though cobalt(III) cyanide doesn’t headline the process, it contributes as a model compound for studying how molecules bond and react. These investigations help design better sensors, electronic devices, and even coatings that resist wear.

Environmental and Safety Concerns

Cyanide in any form demands respect. Cobalt(III) cyanide stands out as toxic—both from its cyanide ions and the heavy metal itself. In high school chemistry classes, safety comes before curiosity, and this stuff stays locked away except for the occasional demonstration at a university. Factories and labs that use it should track and contain waste properly, because spills spell real trouble for people and for waterways.

Regulators keep an eye on compounds like this due to environmental and occupational hazards. Most large-scale applications steer clear of it, which explains why it hasn’t found its way into commercial batteries or electronics in the way cobalt oxide has. In the rare moments cobalt(III) cyanide appears outside research labs, teams handle it in tightly controlled settings.

Alternatives and Safer Solutions

As the chemical industry moves forward, a lot of work focuses on safer, greener pathways. Synthetic chemists now look for catalysts that don’t carry such risks. Milder, less poisonous cobalt sources can swap in for basic research, and modern electronics stick with more stable cobalt forms that don’t pack toxic punch.

Some universities support “green chemistry” initiatives, where students and researchers avoid the use of hazardous cyanides wherever possible. They aim to deliver new materials or reactions without the risk, benefiting both the environment and those who work with these chemicals every day.

Staying Informed and Responsible

The bottom line: cobalt(III) cyanide fills a specialized role that’s hard to replace in certain experiments, but never without thought for safety and disposal. I’ve seen the difference clear guidelines and training make—safe usage hinges on respecting a compound’s power, not just its promise. As technology and research signatures change, so should our approach to managing hazards. That’s the only way to keep advancing while protecting health and the world outside the lab.

Is Cobalt(III) Cyanide toxic?

Understanding the Threat Behind the Formula

Cobalt(III) cyanide might not pop up in everyday conversation, but anyone working in labs or dealing with chemicals will likely recognize the formula. This compound combines two names that already carry hefty reputations: cobalt and cyanide. Mix them together, and what you have isn’t the stuff of science fiction, but rather a chemical needing real respect and careful handling.

Toxicity: Fact, Not Hype

Few words get a faster reaction than “cyanide.” There’s a reason for that. Cyanide, whether it’s tied up in potassium cyanide or lurking in other forms, blocks cells from using oxygen. That shuts things down quickly at a cellular level, leading to symptoms ranging from dizziness and confusion to complete loss of consciousness. It only takes a few milligrams to create a medical emergency. Cobalt(III) cyanide contains the same infamous CN- groups. Even without sniffing a technical data sheet, anyone familiar with cyanide’s effect will see the risk jump out right away.

But it’s not just the cyanide part that brings trouble. Cobalt isn’t a friendly metal, either. Swallowing, breathing in, or even touching cobalt compounds can irritate, and in the long term, chronic exposure connects with lung issues, heart problems, and the possibility of cancer. The International Agency for Research on Cancer (IARC) rates cobalt and cobalt compounds as possible carcinogens. This double punch – cobalt's chronic risks joined with cyanide’s acute dangers – means there’s no safe shortcut with this stuff.

Lessons from History and Lab Life

Accidents involving inorganic cyanides keep showing up in news stories. A small spill, a missed label, or poor ventilation can end a workday badly or with a hospital trip. Stories circulate among chemists: even a whiff of volatile cyanide compounds mixed into the air flashes warning signs – headache, rapid heartbeat, a sense of terror. Lab veterans learn fast to check the fume hood, double up on gloves, and keep emergency protocols close. Cobalt(III) cyanide, while less familiar than potassium cyanide, deserves equal caution. Safety data sheets highlight the same danger icons: toxic, environmental hazard, avoid release to the environment.

Why Public Awareness Matters

Most people probably won’t encounter pure cobalt(III) cyanide outside specialized fields. But products that include cobalt or cyanide byproducts can wind up closer to home. Industrial pollution, accidental leaching, and improper disposal can let traces get into soil or waterways. A study from the U.S. Environmental Protection Agency warns that both cobalt and cyanide persist in the environment, affecting not only water supplies but also food chains. Even tiny concentrations, over time, can cause trouble for fish, wildlife, and people. Long-term monitoring, responsible chemical management, and community education all help reduce these risks.

Solutions: Real Steps, Not Just Precautions

Sweeping chemical risks under the rug won’t cut it. Labs and plants experiment with greener alternatives, but for now, cobalt(III) cyanide and similar substances need real oversight. That means training workers to spot hazards, using protective gear, and keeping antidotes for cyanide poisoning on hand. Emergency teams must know how to tackle both cobalt and cyanide exposures, since the treatment is not identical for both. Strong labeling, secure storage, and waste controls play a role too. Regulations already demand these steps, but real safety comes down to people carrying out those guidelines every time.

Health isn’t just on paper – it’s something kept up by knowledge, vigilance, and a refusal to cut corners. Cobalt(III) cyanide stands as another reminder of that simple rule.

What is the chemical formula of Cobalt(III) Cyanide?

Getting to the Core: What’s the Formula?

Chemistry can look like a game of matching puzzles, but there is always a logic behind those subscripts and superscripts. If you’ve ever wondered about Cobalt(III) cyanide, it carries the chemical formula Co(CN)3. One cobalt ion, which carries a +3 charge, joins up with three cyanide ions, each with a -1 charge, resulting in a neutral compound overall. In everyday lab work, you see chemistry classes exploring how transition metals like cobalt balance out their charges with ligands — in this case, with cyanide’s nasty reputation for toxicity.

Why Does the Formula Matter?

Every compound’s formula tells more than just the ratio of ingredients — it sets off a chain of implications for how the substance reacts, how it acts in the environment, and how it’s handled by people. Cobalt(III) isn’t just a random oxidation state — it changes how cobalt interacts with other chemicals, making it more likely to participate in redox reactions. Cyanide, on its end, binds tightly to metals, which is part of why it’s so dangerous in mining and industrial wastewater.

Fact Check: Real-World Impact of Cobalt and Cyanide

Cobalt slips into daily life in electric vehicle batteries and as a blue pigment in glass, but safety always sits high on the list with cyanides around. Cyanides show up in gold mining, electroplating, and chemical synthesis, and mishandling them has led to serious environmental disasters. Back in the lab, handling cobalt(III) compounds means using gloves, masks, and good ventilation because even small spills can cause headaches, dizziness, or worse. That risk isn’t just theoretical — according to the World Health Organization, cyanide poisoning is responsible for thousands of accidents worldwide each year, many tied to mining or poor storage practices.

More Than a Hazard: Possibility and Responsibility

Cobalt(III) cyanide matters for its unique electronic structure — chemists explore its properties for insights into everything from catalysis to complex ion formation. Cobalt ions switch between different oxidation states, and those shifts allow for experiments you simply can’t do with something inert like sodium chloride. But that same activity is what makes it a double-edged sword. Cyanides can form tight bonds with metals, which is useful in chemistry, but those same bonds are what lock up oxygen in living cells, leading to deadly results when mishandled. This dual nature means a lot of responsibility falls on the shoulders of the storage, disposal, and accident management teams.

Innovation, Regulation, and Safer Chemistry

Work in science doesn’t stop at discovering new compounds. Regulations from agencies like OSHA in the US or REACH in the EU focus not just on safe handling, but also on finding cleaner alternatives if possible. Chemists spent years developing less toxic alternatives to cyanide-based processes, like using thiosulfate for gold recovery instead of straight cyanides. Battery makers scramble for ways to get cobalt out entirely, not just over its toxicity but also because of supply chain and ethical concerns — major mining sites in the Democratic Republic of Congo involve significant social and environmental issues.

Finding a Smarter Path Forward

Chemical formulas condense a world of complexity into a handful of symbols. Practice in the lab, industry, and classroom shows that it’s not enough to memorize them — understanding how and why they work leads to better safety, smarter use, and sometimes even breakthroughs that make the planet healthier. Mastering something like Co(CN)3 means learning what the formula does both on paper and in the real world.

How should Cobalt(III) Cyanide be stored safely?

Why This Compound Calls for Care

Cobalt(III) cyanide isn’t something you want lying around the house or classroom shelves. On paper, it’s a brick-red powder, but its risk stretches far beyond color. The cyanide piece brings danger even professionals respect. A lot of chemists, me included, have wrangled with these kinds of substances during projects. The thing you never forget – one slip with a cyanide compound and you’re dealing with poisoning, possible fatal mistakes, and huge regulatory headaches. So talking safety isn’t fearmongering; it’s a real obligation.

Understanding Real Dangers

The chemistry behind cobalt(III) cyanide gives away the risk. Cyanide ions, in contact with acids or acids in the air, can release hydrogen cyanide gas. Anyone in the vicinity breathes this in, you have an emergency. Less obvious: the compound also doesn’t age well. Light, heat, or stray water push it out of its stability zone fast. The American Chemical Society spells out the bad news in their guidelines – laboratory storage of even tiny cyanide reserves attracts watchful eyes from regulatory bodies and safety inspectors.

Solid Steps That Actually Work

Relying on makeshift cabinets, sticky labels, or “everyone-knows-where-it-is” systems just won’t fly. Lockable cabinets built for poisons or toxins keep unsupervised hands off the jars. Chemical-resistant shelves made from polyethylene or coated metal do better than wood or particle board that can soak up spills. Storing this compound means looking at ventilation just as much as lockdown – good airflow lets you vent away any accidental traces of hydrogen cyanide. I've worked in labs where a fume hood, kept switched on, sits above the storage zone. This gives another barrier between you and a chemical accident.

Direct sunlight and warm rooms break down the compound, so keeping the storage area shaded and air-conditioned buys safety. Humidity sneaks up in labs, too, so keeping desiccants right next to the storage container can stop atmospheric moisture from triggering a disaster. A lot of serious research spaces have environmental monitors now, so you get an alert before things drift into a red zone.

Personal Protective Gear Isn’t Just Optional

Working with cobalt(III) cyanide doesn’t care if the clock says “end of shift” or if it’s still sealed in a bottle. Nitrile gloves, goggles, and chemical aprons are as standard as using pipettes. The one time someone thinks they're too careful to worry about splashing, trouble starts. In my academic lab days, new research assistants more often got tripped up by chemical dust than outright spills. Steady habits, not heroics, have saved lives.

Training and Documentation

Inventory audits and training aren’t “tick the box” jobs. Chemical safety depends on everyone understanding what dangerous really means – not just reading about toxicity, but rehearsing what to do if something leaks or spills. Safety sheets stay taped to cabinet doors, and every emergency number hangs right beside. Anyone using the compound logs it. This doesn’t only prevent mistakes; it builds a mindset that safety is part of the job, not a speed bump.

Better Alternatives and Waste Handling

It’s worth asking if safer chemicals will do the same job. Most publications and university guidelines suggest limiting how much of any cyanide you order at once. Less stock means less risk and less waste. Getting rid of old cobalt(III) cyanide follows strict hazardous waste procedures—sewage systems offer no shortcut. Licensed chemical disposal firms collect, log, and incinerate the material safely. A memory: colleges lose funding and licenses fast if waste gets mishandled. By prioritizing safe storage and smart disposal, everyone who works with these risks lowers more than just their own stress—they keep accidents off the front page too.

What precautions are necessary when handling Cobalt(III) Cyanide?

Understanding the Stakes

Some folks might only hear “cyanide” and think of spy movies. In reality, Cobalt(III) cyanide balances delicate laboratory work with a serious health risk. My years in research taught me a few things—chief among them is that there are rules you don’t bend, especially around compounds that mix heavy metals with cyanide. One wrong move, and it’s not just a setback on the experiment; it can be a trip to the ER or worse.

Exposure Can Be Deadly

Cyanide blocks cells from using oxygen, which leads to suffocation at a cellular level. Cobalt brings its own nasty tricks, including causing lung and heart problems over time. The combo is not something to treat lightly. I recall a story from grad school—someone cracked a vial without consulting the safety data. We spent the next few hours getting medical clearance instead of finishing thesis work. No lab report is worth that risk.

Personal Protective Equipment Is Not Optional

You want gloves—nitrile or rubber, not cheap latex. Splash goggles and a sturdy lab coat stand between you and a hasty hospital run. I’ve seen nitrile gloves buckled by sharp shards, so before handling, check for punctures. A face shield guards against splashes, which is a real risk mixing solutions. Anyone can forget for a split second; the gear makes sure mistakes don’t become tragedies.

Never Work Alone with Cyanide Salts

A buddy system isn’t just overcautious. After reading incident reports over the years, I believe nobody should tackle this stuff solo—even on weekends when everyone wants to skip the scheduling headache. It’s basic: have someone else ready with the cyanide antidote kit and phone for help if needed. Good labs keep backup oxygen and antidote kits within arm’s reach.

Good Ventilation Saves Lives

Hoods aren’t a luxury—they’re essential. Working outside a fume hood courts disaster. Cyanide gas creeps up without smell or warning. If the air system in your lab struggles, it’s time for a fix, not a workaround. I’ve seen well-meaning interns try to “get by,” only to regret it as soon as their head swims with the first whiff.

Storage and Waste: No Shortcuts

Don’t just mark a bottle “toxic” and call it done. Lock away cyanide salts—away from acids. Mixing with acid releases hydrogen cyanide, a fast-acting poison. Wherever I’ve worked, the best labs use secure, double-checked cabinets, logged and inspected regularly. Disposal requires certified hazardous waste procedures. Dumping in the drain guarantees trouble. If rules seem tedious, it’s only because the stakes are sky-high.

Training and Respect Save Lives

Every new researcher needs training before they even get close to compounds like this. Too many “old hands” think they can eyeball the risk, but the facts say otherwise. The best safety culture I’ve seen comes down to respect—for the material, the lab mates, and your own future. Read the safety data. Prepare for the worst, hope for the best. Small habits—like checking labels twice—stack up to real protection.

The Bottom Line

Cobalt(III) cyanide demands sharp focus, good habits, and solid backup. Working safely means prepping well, following protocols, and never skipping steps. Facilities that foster respect and put people first keep everyone alive and well—and that beats shortcuts every time.

Cobalt(Iii) Cyanide
Cobalt(Iii) Cyanide
Names
Preferred IUPAC name tricyanidocobalt
Other names Cyanocobalt(III)
Cobalt cyanide
Pronunciation /ˈkoʊ.bælt θri saɪˈænaɪd/
Identifiers
CAS Number 13530-15-5
Beilstein Reference 356622
ChEBI CHEBI:131378
ChEMBL CHEMBL3321939
ChemSpider 22244
DrugBank DB14606
ECHA InfoCard 03e07b58-7c6e-41ec-b90b-acee648693a2
EC Number 208-144-1
Gmelin Reference 78652
KEGG C01455
MeSH D003052
PubChem CID 10485912
RTECS number GF9590000
UNII R43H33044Q
UN number UN1620
CompTox Dashboard (EPA) 6QV310IG6S
Properties
Chemical formula Co(CN)₃
Molar mass 173.96 g/mol
Appearance Dark green crystals
Odor Odorless
Density 2.52 g/cm³
Solubility in water Insoluble
log P -2.6
Vapor pressure Negligible
Acidity (pKa) 5.3
Basicity (pKb) 12.6
Magnetic susceptibility (χ) 'Antiferromagnetic'
Dipole moment 0 D
Thermochemistry
Std molar entropy (S⦵298) 138.1 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -527 kJ/mol
Pharmacology
ATC code V03AB43
Hazards
Main hazards Toxic if swallowed, in contact with skin or if inhaled; contact with acids liberates very toxic gas.
GHS labelling GHS02, GHS06, GHS09
Pictograms GHS06,GHS09
Signal word Danger
Hazard statements H300 + H310 + H330: Fatal if swallowed, in contact with skin or if inhaled.
Precautionary statements P261, P273, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P308+P313, P405, P501
NFPA 704 (fire diamond) 3-2-3-OX
Lethal dose or concentration LD50 oral rat 8.3 mg/kg
LD50 (median dose) LD50 (median dose): Oral-rat LD50: 8.5 mg/kg
NIOSH RN2088
PEL (Permissible) PEL (Permissible Exposure Limit) of Cobalt(III) Cyanide: "0.1 mg/m3
REL (Recommended) 0.02 mg/m3
IDLH (Immediate danger) 25 mg/m3
Related compounds
Related compounds Potassium hexacyanocobaltate(III)
Cobalt(II) cyanide
Potassium hexacyanoferrate(III)
Cobalt(III) fluoride
Cobalt(III) oxide