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Material Safety Data Sheet (MSDS) – Calcium Resinate

Identification

Product Name: Calcium Resinate
Synonyms: Calcium Soap of Resin Acids, Resinates, Calcium Salts
Chemical Formula: Variable, typically C20H29CaO4
CAS Number: 9007-13-0
Recommended Use: Varnishes, Paint Driers, Adhesives, Printing Inks
Supplier Details: Manufacturer or distributor contact information, company address, emergency contact phone numbers

Hazard Identification

Hazard Classification: Not classified as hazardous according to OSHA, GHS, or EU CLP
Physical Hazards: Combustible solid, may generate dust
Health Hazards: May cause mild irritation to eyes, skin, respiratory system due to dust
Environmental Hazards: Overexposure to aquatic systems may cause harm due to insolubility and persistence
Pictogram: None mandated
Signal Word: None
Hazard Statements: Dust may cause mechanical irritation
Precautionary Statements: Avoid breathing dust, wash after handling, avoid release to environment

Composition / Information on Ingredients

Main Ingredient: Calcium Resinate
Chemical Description: Calcium salt of rosin acids
Concentration: Typically >95%
Impurities: Small amounts of unreacted rosin acids, water, inorganic salts
Other Components: No hazardous impurities present in concentrations requiring reporting

First Aid Measures

General Advice: Remove individual from exposure, keep at rest
Inhalation: Move to fresh air, seek medical attention for persistent symptoms
Skin Contact: Wash skin thoroughly with soap and water, remove contaminated clothing, seek medical advice if irritation persists
Eye Contact: Flush eyes gently with plenty of water for at least 15 minutes, lift eyelids to ensure thorough rinsing, consult physician if irritation continues
Ingestion: Rinse mouth with water, do not induce vomiting, seek immediate medical assistance if large quantities swallowed or if discomfort develops

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray (fog), foam, dry chemical, carbon dioxide
Unsuitable Media: Direct water stream due to possible product spread
Combustion Products: Carbon monoxide, carbon dioxide, irritating fumes
Protective Equipment: Full protective clothing, self-contained breathing apparatus
Special Hazards: Dust may form explosive mixtures with air, product is combustible under intense heat

Accidental Release Measures

Personal Precautions: Ventilate area, avoid inhalation of dust, use appropriate PPE (gloves, goggles, mask)
Environmental Precautions: Prevent entry into sewers, waterways, or soil
Spill Response: Sweep or vacuum up material, avoid dust generation, place in appropriate container for disposal
Disposal: Handle according to local, regional, and national regulations

Handling and Storage

Handling Precautions: Work in well-ventilated area, avoid creating dust, wash thoroughly after use, keep away from open flame and hot surfaces
Storage Conditions: Store in cool, dry, well-ventilated location away from heat, strong oxidizers, and acids
Incompatibilities: Strong acids, oxidizing agents
Storage Life: Stable under recommended conditions for several years

Exposure Controls and Personal Protection

Exposure Limits: No established OSHA or ACGIH exposure limits for this material
Engineering Controls: Local exhaust ventilation recommended for dust-producing operations
Personal Protection: Protective gloves, safety goggles, dust mask or respirator in case of inadequate ventilation
Hygiene Measures: Wash hands after handling, do not eat, drink, or smoke during use, remove contaminated clothing promptly

Physical and Chemical Properties

Appearance: Amber solid, flakes or powder
Odor: Mild resinous
pH: Not applicable (insoluble)
Melting Point: 180–200°C
Boiling Point: Decomposes at high temperatures
Flash Point: >200°C (closed cup)
Autoignition Temperature: Not determined
Explosive Properties: Dust may pose explosion risk
Vapor Pressure: Negligible at room temperature
Density: About 1.03–1.07 g/cm³
Solubility: Insoluble in water, soluble in alcohols, organic solvents
Viscosity: Not applicable
Partition Coefficient: Not available

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling
Conditions to Avoid: Direct sunlight, sources of heat, open flames, generating dust clouds
Incompatible Materials: Strong acids, strong oxidizers
Hazardous Decomposition Products: Carbon oxides, irritating smoke
Hazardous Polymerization: Will not occur

Toxicological Information

Acute Toxicity: Low acute oral and dermal toxicity reported in available data
Skin Corrosion/Irritation: May cause slight irritation after prolonged or repeated contact
Eye Damage/Irritation: Dust may irritate eyes
Respiratory Sensitization: Prolonged exposure to dust can irritate respiratory tract
Carcinogenicity: Not listed as carcinogen by IARC, NTP, OSHA
Chronic Effects: No data on systemic effects from repeated or prolonged exposure
Mutagenicity/Reproductive Toxicity: No evidence available for mutagenic or reproductive effects

Ecological Information

Ecotoxicity: No acute hazard to aquatic life at low concentrations, may persist and accumulate over time
Degradability: Poorly biodegradable due to resin nature
Bioaccumulative Potential: May accumulate in sediments
Mobility in Soil: Low due to insolubility in water
Other Adverse Effects: Spillage to wildlife-sensitive habitats should be avoided

Disposal Considerations

Product Disposal: Dispose through licensed waste disposal contractor, recycle if possible, avoid landfill if regulations forbid
Container Disposal: Containers may be reused or recycled after thorough cleaning
Special Precautions: Do not discharge to natural water bodies or soil, comply with federal, state, and local regulations
RCRA Status: Not classified as hazardous waste under U.S. regulations

Transport Information

UN Number: Not regulated for transport
Proper Shipping Name: Not applicable
Hazard Class: Non-hazardous
Packing Group: None assigned
Marine Pollutant: No
Special Transport Precautions: Protect from excessive heat and moisture, avoid stacking heavy loads

Regulatory Information

OSHA Status: Not classified as hazardous
TSCA Inventory: Listed
SARA Title III: Not subject to reporting
California Proposition 65: Not listed as cancer-causing or toxic
EU Regulations: Not subject to classification or labeling under REACH
Canada WHMIS: Not controlled
Inventory Status: Included in major inventories (TSCA, DSL, EINECS)
Additional Requirements: Observe workplace health and safety regulations and best practices