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Material Safety Data Sheet: Calcium Ascorbate

Identification

Product Name: Calcium Ascorbate
Chemical Family: Vitamin supplements
Molecular Formula: C12H14CaO12
Molecular Weight: 426.32 g/mol
CAS Number: 5743-28-2
Synonyms: Ascorbic acid, calcium salt; Vitamin C calcium salt
Recommended Use: Food additive, dietary supplement
Supplier Contact: Manufacturer or distributor details required for shipment or inquiry
Emergency Contact Number: Emergency response centers or poison control numbers relevant to the region

Hazard Identification

GHS Classification: Not classified as hazardous according to current GHS criteria
Physical Hazards: May cause mild mechanical irritation to eyes and respiratory tract if dust is generated
Health Hazards: Ingestion of excessive amounts may cause gastrointestinal upset or mild laxative effects
Environmental Hazards: No significant risk to the environment under normal handling and usage
Signal Word: None required
Pictograms: Not required
Precautionary Statements: Avoid inhalation of dust; wash thoroughly after handling; practice good hygiene
Other Hazards: High dust concentrations in air can lead to a dust explosion hazard if contact with ignition source occurs

Composition / Information on Ingredients

Chemical Identity: Calcium Ascorbate
Concentration: Pure, typically greater than 97% by weight
Impurities: Small amounts of moisture, trace ascorbic acid, and calcium salts possible depending on supplier
Hazardous Components: This product contains no components classified as hazardous under present legislation

First Aid Measures

Inhalation: Move individual to fresh air; seek medical attention for persistent irritation or discomfort
Skin Contact: Wash exposed skin with soap and water; seek medical advice for rash or persistent discomfort
Eye Contact: Rinse eyes cautiously with water for at least 15 minutes; remove contact lenses if present and easy to do; consult doctor if irritation continues
Ingestion: Rinse mouth with water; drink water to dilute; seek medical help for large amounts swallowed or if feeling unwell
Symptoms/Effects: Dust exposure might cause mild respiratory or eye irritation, especially in poorly ventilated spaces

Fire-Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, dry chemical, foam, water spray
Unsuitable Extinguishing Media: High-pressure water jets may spread burning dust
Special Hazards: Emits carbon oxides when burned; avoid inhaling combustion products
Protective Equipment: Firefighters require self-contained breathing apparatus and full protective gear
Fire/Explosion Hazards: Product is not combustible under typical conditions; dust may form explosive mixtures with air under rare circumstances
Advice for Firefighters: Stay upwind, remove containers from fire area if safe, limit run-off with containment

Accidental Release Measures

Personal Precautions: Avoid breathing dust; ventilate area; wear protective clothing, gloves, and eye protection
Environmental Precautions: Avoid discharge to drains, surface or groundwater
Spill Cleanup Methods: Scoop or sweep up spilled material carefully; avoid raising dust; collect in suitable, labeled containers
Reference to Other Sections: Refer to sections on exposure controls and personal protection for more advice on workplace safety

Handling and Storage

Handling: Avoid dust creation; use local exhaust where dust is generated; wash hands before eating, drinking, or smoking
Hygiene Measures: Keep work areas clean; wash exposed skin before breaks and after finishing work
Storage Conditions: Store in a tightly closed container in a cool, dry, well-ventilated area; keep out of reach of children
Incompatibilities: Avoid contact with strong oxidizing agents or acids
Safe Packaging Materials: Use original packaging or compatible containers that keep contents dry and free from contamination

Exposure Controls and Personal Protection

Control Parameters: No occupational exposure limits established for this compound
Engineering Controls: Use extraction or local ventilation where handling routine creates dust
Respiratory Protection: Dust mask or respirator may be appropriate in dusty conditions
Eye Protection: Safety glasses with side shields or chemical goggles if dust likely
Skin Protection: Gloves recommended when handling bulk product; lab coats or long-sleeve clothing reduce skin contact
Work Practices: Remove contaminated clothing; wash hands thoroughly after handling

Physical and Chemical Properties

Appearance: White to pale yellow crystalline powder
Odor: Odorless or faint, slightly acidic smell
Odor Threshold: Not applicable
pH (5% sol.): Close to neutral, usually between 6.0 and 8.0
Melting Point: Decomposes above 190°C
Boiling Point: Not applicable
Flash Point: Not available/not determined
Evaporation Rate: Not relevant
Flammability: Not flammable under normal use
Vapor Pressure: Not applicable
Vapor Density: Not applicable
Solubility: Freely soluble in water; slightly soluble in alcohol
Partition Coefficient (n-octanol/water): Not established
Decomposition Temperature: Starts decomposing at elevated temperatures
Viscosity: Not applicable
Particle Size: Finer grades increase dusting risk

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: Will not react violently with water or air
Conditions to Avoid: Excessive heat, moisture, open flames, and strong oxidizers
Incompatible Materials: Strong oxidizing agents, acids
Hazardous Decomposition: Releases carbon oxides and calcium oxide at high temperatures
Polymerization: Will not occur
Other Information: Exposure to light or air over time could decrease potency but does not create a new hazard

Toxicological Information

Likely Routes of Exposure: Inhalation, ingestion, skin and eye contact
Acute Toxicity: LD50 (oral, rat) > 5000 mg/kg (essentially non-toxic)
Skin Corrosion/Irritation: Mild irritation possible for sensitive individuals
Serious Eye Damage/Irritation: May cause slight mechanical eye irritation, especially in powder form
Respiratory Sensitization: Dust may cause temporary irritation
Carcinogenicity: Not recognized as carcinogenic by IARC, NTP, or OSHA
Reproductive Toxicity: No evidence or indication of reproductive harm at dietary exposures
Repeated Dose Toxicity: High amounts over extended periods may affect kidney function due to calcium burden, but not at commonly used doses
Symptoms: Occasional mild gastrointestinal upset if unusually high amounts are consumed

Ecological Information

Ecotoxicity: Not anticipated to be harmful to aquatic or terrestrial organisms at normal levels
Persistence and Degradability: Degrades naturally in the environment, mainly by oxidation
Bioaccumulation Potential: Low, given rapid metabolism and natural occurrence
Mobility in Soil: Readily soluble in water; will partition to soil moisture
Other Adverse Effects: No known endocrine disrupting effects or long-term hazards at realistic exposures
Precaution for Environment: Avoid unnecessary release to surface waters to limit nutrient load and water clouding

Disposal Considerations

Waste Disposal Methods: Dispose of unused or contaminated material in line with local, state, and national regulations; avoid pouring in drains or natural water sources
Packaging Disposal: Clean, empty containers can go to recycling or landfill in accordance with regulations
Unused Product: Send to authorized waste facility, where chemicals can be incinerated or treated
Special Considerations: Keep spill response and contaminated cleanup materials out of regular trash where rules require

Transport Information

UN Number: Not regulated for transport
UN Proper Shipping Name: Not classified as dangerous goods
Transport Hazard Class(es): Not applicable
Packing Group: Not assigned
Special Precautions for User: Avoid damage or leaks during handling and shipping; keep container dry and sealed
Environmental Hazards: Not a marine pollutant
Transport in Bulk: Ship in suitable clean containers; prevent cross-contamination with hazardous goods

Regulatory Information

Safety, Health & Environmental Regulations: Product complies with major food and pharmaceutical regulations if purity grades are met
OSHA Status: Not hazardous according to US OSHA GHS rules
TSCA Inventory: Listed
DSL/NDSL (Canada): Listed
EU Reach: Exempt as a food additive or dietary supplement
Other Listings: Approved for use in food under FDA 21 CFR regulations; EC List Number: 227-682-1
Label Requirements: Use hazard-free statements where required in accordance with applicable laws
Additional Guidance: Review country-specific workplace and exposure guidance; reference updates regularly to stay compliant