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Material Safety Data Sheet – Cadmium Oxide, Non-Pyrophoric

Identification

Product Name: Cadmium Oxide, Non-Pyrophoric
Chemical Formula: CdO
Synonyms: Cadmium Monoxide, Cadox, Brown CdO
CAS Number: 1306-19-0
Recommended Use: Electroplating, pigment manufacture, laboratory chemical, semiconductor fabrication
Supplier Information: [Manufacturer contact details, emergency phone number]

Hazard Identification

Classification: Acute Toxicity (Oral, Inhalation, Dermal) Category 2, Carcinogenicity Category 1B, Specific Target Organ Toxicity-Repeated Exposure Category 2, Hazardous to the aquatic environment – Acute Category 1
Signal Word: Danger
Hazard Statements: Fatal if inhaled or swallowed, suspected of causing cancer, causes damage to organs through prolonged or repeated exposure, very toxic to aquatic life
Pictograms: Skull and crossbones, health hazard, environment
Precautionary Statements: Avoid all contact with skin, eyes, clothing; prevent dust formation and inhalation

Composition / Information on Ingredients

Chemical Name: Cadmium Oxide
CAS Number: 1306-19-0
EC Number: 215-146-2
Concentration: ≥99% by weight
Impurities: May contain trace cadmium metal, chlorides, or less than 1% water

First Aid Measures

Inhalation: Remove to fresh air immediately, keep airway clear, provide oxygen if breathing is difficult, begin artificial respiration if not breathing and seek emergency medical attention
Skin Contact: Take off contaminated clothing, wash with plenty of water and soap, do not reuse clothing until properly cleaned, seek medical evaluation if irritation develops
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek immediate medical advice
Ingestion: Do not induce vomiting, rinse mouth, give water to dilute if person is conscious, get medical help without delay
Most Important Symptoms: Coughing, breathlessness, chest pain, nausea, abdominal pain, signs of kidney or liver stress, possible delayed symptoms
Medical Attention: Immediate response, consider risk of delayed pulmonary edema and kidney effects

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, or carbon dioxide; avoid using water streams directly on product
Specific Hazards: May release toxic cadmium fumes and oxides during combustion
Protective Equipment: Self-contained breathing apparatus, full protective suit, respiratory protection
Firefighting Instructions: Move containers away from fire if safe, contain runoff to prevent contamination, keep unauthorized personnel away

Accidental Release Measures

Personal Precautions: Evacuate area, provide adequate ventilation, use appropriate PPE including respirator with approved filter for particulates
Environmental Precautions: Prevent further leakage or spillage if safe to do, avoid discharge into drains or waterways
Containment and Clean Up: Scoop or vacuum up using non-sparking tools, avoid dust generation, collect in labeled, sealed containers for hazardous waste disposal, thoroughly decontaminate affected area, confirm complete removal with wipe tests if possible

Handling and Storage

Handling: Use with local exhaust or enclosed systems, avoid skin and eye contact, prevent formation of dust, wash thoroughly after use, do not eat, drink, or smoke around product
Storage: Store in a tightly closed container, in a dry, cool, well-ventilated place, away from acids, strong oxidizers and reducing agents, label storage container clearly, restrict access to trained personnel only
Hygiene Measures: Separate from foodstuffs, avoid cross-contamination with personal items, ensure availability of emergency showers and eye-wash stations

Exposure Controls and Personal Protection

Occupational Exposure Limits: OSHA PEL: 0.005 mg/m³ (as Cd), NIOSH REL: 0.002 mg/m³ (as Cd, fume or dust), ACGIH TLV: 0.01 mg/m³ (inhalable fraction, as Cd)
Engineering Controls: Fume hoods, glove boxes, local exhaust with HEPA filtration
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), respirators (P100 or better for dust, supplied air for higher concentrations), approved safety goggles, full lab coat or suit
Environmental Controls: Use closed systems for transfers, monitor workplace air, implement spill containment plans

Physical and Chemical Properties

Appearance: Brownish-red crystals or powder
Odor: Odorless
Melting Point: 900°C
Boiling Point: 1550°C (sublimes)
Density: 8.15 g/cm³
Solubility: Insoluble in water, soluble in acids
Vapor Pressure: Negligible at room temperature
Particle Size: Variable; often micron or sub-micron for technical grades
pH: Not applicable
Flash Point: Not flammable
Partition Coefficient: Not applicable
Auto-Ignition Temperature: Not self-igniting

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: Reacts violently with strong acids, forming cadmium salts and hydrogen
Incompatible Materials: Strong oxidizers, strong acids, acetylenic compounds, sulfur, selenium
Polymerization: No hazardous polymerization
Decomposition Products: Cadmium oxides, toxic metal fumes if heated intensely

Toxicological Information

Acute Toxicity: Inhalation, oral, and dermal exposures can be fatal
Chronic Toxicity: Persistent inhalation or ingestion leads to kidney, bone, and lung damage
Carcinogenicity: IARC Group 1 (carcinogenic to humans), NTP listed human carcinogen, evidence for increased risks of lung cancer among exposed workers
Routes of Exposure: Inhalation of dust/fumes, ingestion, skin absorption (minor)
Symptoms of Exposure: Cough, chest pain, headache, nausea, vomiting, kidney/liver function loss over time
Sensitization: Not a known sensitizer
Target Organs: Lungs, kidneys, bones
Other Effects: Reproductive toxicity, possible teratogenic effects

Ecological Information

Ecotoxicity: Highly toxic to aquatic organisms, persistent bioaccumulation in aquatic food chains
Mobility: Low mobility in soil, tends to bind tightly to particulate matter
Persistence and Degradability: Does not degrade naturally, remains in environment as metal/oxide
Bioaccumulative Potential: Readily accumulates in aquatic organisms, biomagnification up food webs
Other Environmental Effects: Toxic to algae, fish, invertebrates; risk of long-term ecosystem disruption

Disposal Considerations

Waste Treatment Methods: Treat as hazardous waste using approved incineration or secure chemical landfill, handle according to local, state, and federal regulations
Precautions for Disposal: Never dispose of in municipal waste streams or by pouring into drains, minimize dust generation during handling, retain waste in sealed, labeled containers
Contaminated Packaging: Dispose of containers as hazardous material after decontaminating or ensure complete emptying and sealing
Disposal Standards: U.S. RCRA D006 (Hazardous Waste by Characteristic of Toxicity), EU Waste Codes for heavy metals

Transport Information

UN Number: UN 2570
Proper Shipping Name: Cadmium Compound
Hazard Class: 6.1 (Toxic Substances)
Packing Group: II
Labels Required: Toxic substance, Environmental hazard
Marine Pollutant: Yes
Special Precautions: Prevent packaging rupture, reinforce containers, restrain shipments to avoid vibration or impact
Transport Regulations: Comply with IATA, IMDG, ADR, and local requirements

Regulatory Information

U.S. Regulations: OSHA regulated, SARA Title III Section 313 Toxic Chemical, RCRA hazardous waste, CERCLA reportable quantity: 10 pounds (4.54 kg)
TSCA Status: Listed
EU Regulations: REACH registered, subject to restriction under Annex XVII (Cadmium compounds), classified SVHC (Substance of Very High Concern), subject to workplace air monitoring and reporting under Directive 2004/37/EC
Canada: WHMIS Category D1A (Very Toxic), Schedule 1 List, Environmental Release Guideline
International: IARC Group 1 Carcinogen, subject to Rotterdam and Stockholm Conventions for hazardous chemicals
Label Requirements: Clearly marked as carcinogenic, acutely toxic, and aquatic hazard in accordance with GHS and local directives