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Material Safety Data Sheet: Cadmium Nitrate

Identification

Product Name: Cadmium Nitrate
Chemical Formula: Cd(NO3)2·4H2O
CAS Number: 10022-68-1
Synonyms: Nitric acid, cadmium (2+) salt, tetrahydrate; cadmium dinitrate
Recommended Use: Laboratory reagent, pigment manufacturing, electroplating, catalyst for organic synthesis
Manufacturers: Various international chemical suppliers and laboratory supply companies
Emergency Contact: In-country emergency services and local poison control centers

Hazard Identification

GHS Classification: Acute toxicity (oral and inhalation, Category 2), Carcinogenicity (Category 1B), Germ cell mutagenicity (Category 2), Specific target organ toxicity (repeated exposure, Category 2), Hazardous to the aquatic environment (acute and chronic Category 1)
Signal Word: Danger
Hazard Statements: Fatal if swallowed, Fatal if inhaled, Causes damage to organs through prolonged or repeated exposure, May cause genetic defects, May cause cancer, Very toxic to aquatic life with long-lasting effects
Precautionary Statements: Avoid breathing dust or fumes, Use only outdoors or in a well-ventilated area, Wear protective clothing, gloves, and eye protection, Do not eat, drink, or smoke while using
Routes of Entry: Inhalation, ingestion, skin contact

Composition / Information on Ingredients

Chemical Name: Cadmium Nitrate Tetrahydrate
Percentage by Weight: Typically above 98%
Impurities: May contain trace metals, possibly lead, or other nitrates
CAS Number: 10022-68-1
Molecular Weight: 308.49 g/mol
Component Analysis: No stabilizers, diluents, or added binders

First Aid Measures

Inhalation: Remove from exposure area to fresh air immediately, seek medical attention even if no symptoms are present; if breathing is difficult, qualified personnel should provide oxygen
Ingestion: Rinse mouth, do not induce vomiting, seek urgent medical care, never give anything by mouth to an unconscious person
Skin Contact: Remove contaminated clothing, rinse skin with copious amounts of water and mild soap, seek medical attention if irritation develops or persists
Eye Contact: Flush eyes for at least 15 minutes with running water, lifting upper and lower eyelids, obtain immediate medical attention
Symptoms of Exposure: Headache, cough, dizziness, shortness of breath, nausea, vomiting, potential kidney or liver damage, long-term carcinogenic risk

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, carbon dioxide, foam
Unsuitable Media: Do not use halogenated extinguishing agents; avoid direct water stream on material to prevent contaminated runoff
Special Hazards: Releases toxic fumes including cadmium oxides and nitrogen oxides at high temperatures
Protective Equipment: Firefighters must wear full protective gear and self-contained breathing apparatus
Explosion Risk: Strong oxidizer, enhances combustion of other materials, can increase fire intensity in contact with organic matter
Specific Methods: Use water spray to cool unopened containers surrounding the fire zone

Accidental Release Measures

Personal Protection: Evacuate unnecessary personnel, restrict entry, wear respiratory protection and full chemical-resistant clothing
Spill Cleanup: Do not touch spilled material, contain spill with inert absorbent, avoid creating dust, scoop up carefully and place in appropriate waste containers
Environmental Precautions: Prevent from entering drains, water courses, soil, and sewers, notify environmental authorities in case of large releases
Decontamination: Clean area with plenty of water and non-reactive soap, ventilate the area thoroughly
Disposal: Dispose of waste in accordance with local, regional, and national regulations

Handling and Storage

Precautions for Safe Handling: Avoid contact with skin, eyes, and clothing, do not inhale dust or fumes, use only in designated chemical fume hoods, handle with extreme care
Storage Conditions: Store in tightly sealed containers, in a dry, cool, well-ventilated area away from incompatible substances such as reducing agents, strong acids, and organics
Segregation: Keep away from heat sources and combustible materials, segregate from foods and animal feeds
Hygiene Measures: Wash hands and face thoroughly after handling, remove contaminated clothing and wash before reuse, do not eat, drink, or smoke when working with this material

Exposure Controls and Personal Protection

Occupational Exposure Limits: OSHA PEL: 0.005 mg/m³ (Cadmium, dust and fumes), NIOSH REL: 0.002 mg/m³
Engineering Controls: Local exhaust ventilation, chemical-resistant work surfaces, safety showers, and eyewash stations in proximity
Personal Protective Equipment: NIOSH-approved respirators, chemical-resistant gloves (nitrile, neoprene), impervious lab coats or coveralls, chemical splash goggles, face shield for splash risk
Environmental Controls: Minimize release into the environment by using containment, routinely inspect and maintain ventilation and protective equipment

Physical and Chemical Properties

Appearance: Colorless to slightly reddish, crystalline solid
Odor: Odorless
Melting Point: 59°C (with decomposition)
Boiling Point: Decomposes before boiling
Density: Approximately 2.45 g/cm³ (tetrahydrate)
Solubility: Very soluble in water, soluble in methanol
pH: Acidic aqueous solution, pH depends on concentration
Vapor Pressure: Not significant at ambient temperature
Other Properties: Strong oxidizer, can accelerate combustion

Stability and Reactivity

Chemical Stability: Stable under dry, cool, and well-ventilated storage conditions
Reactive Hazards: Reacts violently with strong acids, reducing agents, combustible materials; generates toxic fumes under fire conditions
Incompatible Materials: Reducing agents, strong acids, sulfides, organic materials, chlorinated hydrocarbons
Hazardous Decomposition: Cadmium oxides, nitrogen oxides, potentially explosive nitrates and nitrites can form in certain conditions
Polymerization: Does not undergo hazardous polymerization

Toxicological Information

Acute Toxicity: Oral LD50 (rat): 300 mg/kg (as cadmium nitrate); Inhalation LC50 (rat): 30 mg/m³/2hr
Chronic Exposure: Implicated in kidney, liver, lung damage, and bone demineralization, classified as a Group 1 carcinogen (IARC)
Sensitization: May trigger allergic skin or respiratory reactions
Mutagenicity: Evidence suggests potential for causing genetic mutations
Health Hazards: Causes severe irritation to eyes, skin, and respiratory tract, can depress central nervous system, implicates reproductive toxicity
Cancer Risk: Confirmed human carcinogen with sufficient evidence from occupational exposure

Ecological Information

Aquatic Toxicity: Very toxic to aquatic organisms with long-lasting effects, cadmium ions bioaccumulate in fish and aquatic life
Persistence/Degradability: Not degradable, cadmium persists and remains mobile in soil and water
Bioaccumulative Potential: High, due to strong binding in aquatic and terrestrial organisms
Mobility in Soil: Can migrate through soil and pose risk to groundwater
Other Environmental Hazards: Disruption of microbial activity in soil, contamination risk for food chains through plant uptake

Disposal Considerations

Waste Treatment Methods: Dispose as hazardous waste in accordance with local, state, and federal requirements, do not release to the environment
Contaminated Packaging: Rinse containers with copious water before disposing, prevent reuse of packaging for other chemicals
Special Precautions: All handling should occur in an authorized hazardous waste facility, employ chemical destruction only under expert supervision
Regulatory Disposal Codes: Refer to RCRA regulations for cadmium compounds: EPA Hazardous waste number D006, subject to strict tracking and control

Transport Information

UN Number: UN 2570
UN Proper Shipping Name: Cadmium compound, n.o.s. (Cadmium nitrate)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: II (medium danger)
Marine Pollutant: Yes, subject to special shipping restrictions
Transportation Precautions: Pack in tightly closed, compatible containers, label clearly with hazard diamonds and warnings, keep separate from foodstuffs and feed
Additional Notes: Comply with IMDG, IATA, DOT shipping regulations

Regulatory Information

OSHA Status: Regulated as a hazardous substance under OSHA Hazard Communication Standard
EPA Regulations: Listed under CERCLA and SARA Title III as extremely hazardous, subject to reporting requirements, RCRA hazardous waste code D006
TSCA: Listed on TSCA Inventory
International Regulations: Covered under EU REACH, subject to registration, restriction, and authorization; CLP hazard classifies cadmium nitrate as toxic
Labelling: GHS and NFPA labelling required, warnings for carcinogenicity and aquatic toxicity
Workplace Requirements: Training and health surveillance mandatory for use in many jurisdictions, medical monitoring for exposed staff