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Material Safety Data Sheet (MSDS) for Anhydrous Glucose

Identification

Product Name: Anhydrous Glucose
Chemical Name: D-Glucose, anhydrous
Synonyms: Glucose powder, Dextrose anhydrous
CAS Number: 50-99-7
EC Number: 200-075-1
Manufacturer/Supplier: Listed on label
Recommended Use: Laboratory chemicals, food additive, pharmaceutical production
Contact Information: Emergency telephone number provided by supplier

Hazard Identification

Classification: Not classified as hazardous under GHS/OSHA guidelines
Label Elements: No pictogram or signal word required
Health Hazards: Dust may cause mild irritation of the eyes, nose, and throat; prolonged or repeated exposure to dust may aggravate respiratory conditions
Physical Hazards: Fine powder may form explosive dust-air mixtures
Environmental Hazards: Not considered environmentally hazardous at normal use concentrations

Composition / Information on Ingredients

Chemical Name: D-Glucose, anhydrous
Content: >99% by weight
CAS Number: 50-99-7
Impurities: Trace moisture and ash commonly below 1%
Additives: No additives present and free of hazardous impurities at or above reporting thresholds

First Aid Measures

Inhalation: Move person to fresh air, keep at rest, get medical attention if symptoms persist or worsen
Skin Contact: Wash thoroughly with soap and water
Eye Contact: Rinse eyes cautiously with water for several minutes, remove contact lenses if present and easy to do, get medical attention if irritation continues
Ingestion: Rinse mouth with water; drink water to dilute if needed, seek medical advice for large or symptomatic ingestions
Most Important Symptoms: Mild irritation to eyes, nose, throat from dust
Medical Attention/Special Treatment: Symptomatic treatment

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, carbon dioxide, dry chemical, foam
Unsuitable Extinguishing Media: High-pressure water jets may spread dust
Specific Hazards: Fine particles can form combustible dust clouds; may produce carbon dioxide and carbon monoxide during thermal decomposition
Special Protective Equipment: Firefighters should use self-contained breathing apparatus and personal protective equipment
Explosion Data: Dust may become explosible if suspended in air and exposed to an ignition source

Accidental Release Measures

Personal Precautions: Avoid inhalation of dust, wear suitable respiratory protection if dust is generated
Protective Equipment: Protective gloves, goggles, and a dust mask recommended
Emergency Procedures: Eliminate ignition sources, ventilate area
Methods for Clean-Up: Sweep or vacuum up spilled material using tools and methods that minimize dust generation; wash spill area with water when appropriate
Environmental Precautions: Prevent large spills from entering drains or water courses, collect residues for proper disposal

Handling and Storage

Handling: Handle with care to avoid dust formation, keep away from ignition sources, ensure good ventilation in storage and use areas, avoid inhalation
Hygiene Practices: Do not eat, drink, or smoke when using this material, wash hands after handling
Storage: Store in original tightly closed container in a cool, dry, and well-ventilated location, protect from moisture and incompatible substances, keep away from oxidizing materials
Incompatible Materials: Strong oxidizers, acids

Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits for anhydrous glucose; general dust limits may apply (e.g., OSHA PEL for particulates not otherwise regulated: 15 mg/m³ total dust)
Engineering Controls: Local exhaust ventilation or general dilution ventilation recommended
Personal Protective Equipment (PPE): Safety goggles, gloves, dust mask or approved respirator if dust is generated, work clothing capable of preventing dust contact with skin
Environmental Controls: Procedures to prevent release to the environment in bulk use

Physical and Chemical Properties

Physical State: Solid
Appearance: White crystalline powder or granules
Odor: Odorless
Molecular Weight: 180.16 g/mol
pH (solution): Approx. 6.5 (in water, 10% w/v)
Melting Point: 146°C
Boiling Point: Not applicable
Solubility: Freely soluble in water
Partition Coefficient (log Kow): -3.24 (calculated)
Vapor Pressure: Not volatile
Decomposition Temperature: Decomposes above 180°C
Flash Point: Not relevant for inorganic solids
Flammability: Dust may be combustible
Explosive Properties: Dust explosions possible if dispersed in air and exposed to ignition

Stability and Reactivity

Chemical Stability: Stable under ordinary conditions of use and storage
Conditions to Avoid: Excessive heat, open flames, sources of ignition, moisture
Incompatible Materials: Strong oxidizers, acids
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide may form during thermal decomposition
Polymerization: Will not occur

Toxicological Information

Acute Toxicity: Low toxicity; oral LD50 (rat) > 25000 mg/kg
Inhalation: High dust concentrations may cause mild respiratory irritation
Skin Contact: Not irritating to skin in normal use
Eye Contact: May cause mechanical irritation if dust contacts eyes
Chronic Exposure: No evidence of carcinogenicity, mutagenicity or reproductive toxicity in humans
Sensitization: Not known to cause allergic reactions
Medical Conditions Aggravated: Individuals with pre-existing respiratory allergies or asthma may be more susceptible to dust irritation

Ecological Information

Ecotoxicity: Not classified as dangerous to the environment
Persistence and Degradability: Readily biodegradable in soil and water
Bioaccumulative Potential: Not expected to bioaccumulate (low log Kow)
Mobility in Soil: High, due to water solubility
Other Adverse Effects: Large quantities may contribute to oxygen depletion in aquatic ecosystems if released

Disposal Considerations

Waste Disposal Methods: Dispose of in accordance with local, regional, and national regulations
Contaminated Packaging: Rinse and dispose of containers with care and according to regulation
Special Precautions: Do not discharge to sewer or surface waters in bulk quantities

Transport Information

UN Number: Not regulated
Proper Shipping Name: Not regulated
Transport Hazard Class: Not classified as dangerous goods
Packing Group: Not applicable
Special Precautions: Keep containers tightly closed, avoid formation of airborne dust during transport
Environmental Hazards: Not a marine pollutant

Regulatory Information

International Regulations: Not classified as hazardous under GHS or EU CLP regulation
US Regulations: Not listed as a hazardous substance or toxic chemical under SARA Title III or CERCLA; listed on the TSCA inventory
Canadian Regulations: Listed on DSL/NDSL
Other Regulations: Meets food-grade criteria when appropriate; all additives and impurities are within safe limits; complies with relevant pharmacopoeias where applicable