© 2026 Sinochem Nanjing Corporation,
All Right Reserved
Product Name: Allyltrichlorosilane
Chemical Family: Organosilicon Compound
Synonyms: Trichloroallylsilane, Silane, Allyltrichloro-
Recommended Use: Industrial and laboratory reagent, intermediate in chemical synthesis
Manufacturer: Contact details listed on original packaging or supplier documentation
CAS Number: 107-37-9
Emergency Phone: Refer to local or national poison center contact number
Address: Refer to manufacturer's data for address details
GHS Classification: Acute Toxicity (Inhalation), Skin Corrosion, Eye Damage, Specific Target Organ Toxicity – Single Exposure
Signal Word: Danger
Hazard Statements: Harmful if inhaled, causes severe burns to skin and eyes, may cause respiratory irritation
Pictograms: Corrosive, Exclamation Mark, Health Hazard
Precautionary Statements: Avoid breathing vapors, use only outdoors or in a well-ventilated area, wash thoroughly after handling, wear protective gloves and eye protection, in case of inadequate ventilation wear respiratory protection
Potential Health Effects: Rapid tissue damage in contact with skin or eyes, coughing, chest tightness, risk of burns to respiratory tract if inhaled
Chemical Name: Allyltrichlorosilane
Concentration: Typically >97%
Stabilizers: Minute quantities of proprietary stabilizers (for transport and storage control)
Impurities: None above established regulatory thresholds
Other Components: Trace by-products may form on decomposition, details available via manufacturer
Inhalation: Move to fresh air, seek medical attention immediately, ensure airway is open, administer oxygen if available and trained to do so
Skin Contact: Remove contaminated clothing immediately, rinse affected area with large amounts of water for at least 15 minutes, seek immediate medical attention
Eye Contact: Rinse eyes with plenty of water for at least 15 minutes holding eyelids open, consult a physician urgently
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical advice, never give anything by mouth to an unconscious person
Acute Symptoms: Severe burning pain, blistering, shortness of breath, possible delayed pulmonary effects
Suitable Extinguishing Media: Dry chemical, carbon dioxide, alcohol-resistant foam, use water spray only to keep containers cool
Unsuitable Extinguishing Media: Do not use water jet directly on chemical as violent reaction may occur
Special Hazards: Reacts with water to produce toxic and corrosive gases including hydrochloric acid, may emit silicon oxides under fire conditions
Protective Equipment: Self-contained breathing apparatus, protective suit resistant to corrosive chemicals
Specific Methods: Approach from upwind, prevent run-off entering drains, stay clear of vapor clouds
Personal Precautions: Evacuate unprotected personnel, ventilate area, restrict access, wear appropriate personal protective equipment including respirator and chemical-resistant clothing
Environmental Precautions: Prevent entry into waterways, drains, or soil, contain any spillage with inert absorbent material
Methods for Containment and Cleaning Up: Absorb liquid with sand or non-combustible material, collect material in a suitable container for disposal under strict supervision, neutralize residues using dilute sodium bicarbonate solution, ensure proper disposal following local regulations
Decontamination: Wash spill site thoroughly once clean-up is complete
Precautions: Handle only in a chemical fume hood or well-ventilated area, avoid all personal contact, ground all equipment to prevent static discharge, keep away from all sources of moisture
Safe Handling Advice: Use dedicated and compatible transfer equipment, do not mix with acids or bases, ensure emergency eyewash and safety shower are accessible
Storage Conditions: Store in tightly closed containers under dry inert gas, segregate from acids, bases, strong oxidizing agents, moisture, and incompatible chemicals
Storage Environment: Keep in a cool, dry, well-ventilated space, avoid direct sunlight and temperature extremes
Storage Containers: Use materials resistant to corrosion such as glass or lined steel
Occupational Exposure Limits: No specific OSHA/ACGIH exposure limits, keep airborne concentrations below recommended thresholds using engineering controls
Engineering Controls: Local exhaust ventilation, closed handling systems, explosion-proof equipment design preferred
Personal Protective Equipment: Chemical-resistant gloves, full face shield, tightly fitting goggles, long-sleeved lab coat, impervious apron, respiratory protection (NIOSH-approved full-face respirator or supplied-air respirator for high exposures)
Hygiene Measures: Wash hands and face before eating or drinking, remove contaminated clothing before entering clean areas, regular inspection and maintenance of PPE
Appearance: Colorless to pale yellow liquid
Odor: Pungent, acrid odor similar to hydrochloric acid
Odor Threshold: Not established
pH: Not applicable (reacts with water)
Melting Point/Freezing Point: -94 °C
Boiling Point: 112 °C at 760 mmHg
Flash Point: 30 °C (closed cup)
Evaporation Rate: Not available
Flammability: May form flammable vapors in air
Vapor Pressure: 23 mmHg at 20 °C
Vapor Density: ~5.6 (air = 1)
Relative Density: 1.10 at 20 °C
Solubility: Reacts violently with water
Partition Coefficient (n-octanol/water): Not determined
Autoignition Temperature: Not available
Decomposition Temperature: Not established
Viscosity: Not available
Chemical Stability: Stable under recommended storage conditions and inert atmosphere
Reactivity: Reacts vigorously with water, alcohols, amines, acids, and bases
Hazardous Reactions: Contact with water liberates highly corrosive and toxic gases (hydrogen chloride, siloxanes)
Conditions to Avoid: Exposure to humidity, moisture, incompatible chemicals, elevated temperatures
Incompatible Materials: Water, strong oxidizing agents, acids, bases, alcohols, amines, strong reducing agents
Hazardous Decomposition Products: Hydrogen chloride gas, silicon oxides, other chlorinated compounds
Routes of Exposure: Inhalation, ingestion, skin contact, eye contact
Acute Toxicity: Causes severe respiratory and dermal injuries, acute pulmonary edema possible from inhaling vapors, rapid burning and blistering of tissues in contact with liquid
Chronic Effects: Prolonged or repeated exposure may cause damage to respiratory system, possible skin sensitization
LD50 (Oral, Rat): Not precisely established; highly toxic by estimation
LD50 (Dermal, Rabbit): Data not available; expected to be extremely toxic
Symptoms of Overexposure: Burning eyes, coughing, severe skin and eye damage, shortness of breath, delayed lung injury
Ecotoxicity: Highly toxic to aquatic life due to acute corrosive effects, risk of long-term damage in environmental settings
Persistence and Degradability: Rapid hydrolysis in presence of water, forms persistent chlorinated by-products
Bioaccumulative Potential: Potential for bioaccumulation of breakdown products under certain settings
Mobility in Soil: Expected to hydrolyze and bind to soil particles, can migrate through moist soils
Other Adverse Effects: Listed as hazardous to water supplies, should never be released untreated into ecosystem
Waste Disposal Methods: Collect all residues and contaminated materials for certified hazardous waste incineration, avoid discharge to sewers, waterways, or open environment, never mix with incompatible wastes
Container Disposal: Triple-rinse containers under controlled conditions, puncture and dispose at licensed hazardous waste facility
Relevant Legislation: Dispose of in accordance with regional, national, and local regulations governing hazardous chemical waste
Precautions: Personnel involved in disposal operations should use full personal protective equipment
UN Number: 2977
UN Proper Shipping Name: Allyltrichlorosilane, Stabilized
Transport Hazard Class: 6.1 (Toxic substances), 8 (Corrosive substances)
Packing Group: I (great danger)
Labels Required: Toxic, Corrosive
Special Transport Precautions: Keep container upright, away from moisture, never ship with incompatible materials, detailed safety and emergency response information must accompany shipment
TSCA (US): Listed in Toxic Substances Control Act inventory
EU REACH: Registered as a regulated substance; safety data subject to change based on periodic evaluations
OSHA Classification: Hazardous chemical with stringent workplace controls
WHMIS (Canada): Classified as D1A (Very Toxic Material), E (Corrosive Material)
Other National Regulations: Subject to strict management under air and water pollution prevention statutes, extra labeling and storage notices required by some regional authorities
Special Notes: Workers must receive annual training for handling and emergency response, safety documentation must remain accessible at all operating sites
