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Product Name: 2-Bromoaniline
Chemical Formula: C6H6BrN
Molecular Weight: 172.02 g/mol
CAS Number: 615-36-1
Synonyms: o-Bromoaniline, ortho-bromoaniline
Recommended Use: Laboratory chemical or intermediate for synthesis
Supplier Details: Contact chemical distributor or provider for specific address and emergency numbers
Emergency Contact: Provided on original container label
Classification: Acute toxicity, Category 3 (oral); Skin irritation, Category 2; Eye irritation, Category 2A
GHS Label Elements: Hazard pictograms showing skull and crossbones, exclamation mark
Signal Word: Danger
Hazard Statements: Toxic if swallowed, causes skin and eye irritation
Precautionary Statements: Avoid breathing dust or vapors, wash thoroughly after handling, do not eat or drink during use, wear protective gear
Other Hazards: May cause central nervous system effects, toxic to aquatic life with long-lasting effects
Chemical Name: 2-Bromoaniline
Content: Greater than 98%
Impurities: No significant impurities causing additional hazards identified
EINECS Number: 210-431-7
Eye Contact: Rinse eyes thoroughly with plenty of water for at least 15 minutes, lift eyelids to ensure thorough flushing, remove contact lenses if present and easy to do, seek immediate medical attention
Skin Contact: Remove contaminated clothing, wash skin with soap and water, seek medical advice if irritation persists
Inhalation: Move to fresh air, support breathing if necessary, seek medical help if symptoms develop, provide oxygen if breathing is difficult
Ingestion: Rinse mouth with water, do not induce vomiting, seek medical attention immediately
Most Important Symptoms and Effects: Nausea, vomiting, headache, dizziness, possible cyanosis; prompt medical care recommended
Advice to Physician: Symptomatic and supportive care
Suitable Extinguishing Media: Use dry chemical, carbon dioxide, foam or water spray
Hazards from Combustion Products: May emit toxic fumes like nitrogen oxides, hydrogen bromide
Special Protective Equipment: Firefighters need self-contained breathing apparatus and full body suit
Specific Hazards: Combustible, dusts may form explosive mixtures with air under some conditions, vapors heavier than air can travel to ignition source
Advice for Firefighters: Isolate area, avoid inhaling smoke, move containers from area if safe, cool containers with water
Personal Precautions: Wear protective clothing including gloves and safety goggles, avoid inhalation and contact with skin or eyes, keep unprotected individuals away
Environmental Precautions: Prevent release to environment, do not let product enter drains, spills could cause harm to aquatic life
Cleanup Methods: Absorb spill with inert material such as sand, transfer to a closable chemical waste container for disposal, ventilate area, wash spill site after material pickup
Precautions for Safe Handling: Handle in chemical fume hood or with adequate ventilation, avoid inhaling vapors or dust, avoid contact with skin, eyes, and clothing, do not eat, drink, or smoke while working with substance
Safe Storage Conditions: Store tightly closed in a cool, dry, and well-ventilated area, keep away from incompatibles such as oxidizing agents and acids, protect from humidity and sunlight, recommended storage temperature 2-8°C
Exposure Limits: No official workplace exposure limit available, minimize exposure as much as possible
Engineering Controls: Local exhaust ventilation, use only in chemical fume hood
Personal Protective Equipment: Chemical-resistant gloves (nitrile recommended), safety goggles or face shield, lab coat or protective clothing, in case of inadequate ventilation use approved respiratory protection
Hygiene Measures: Wash hands thoroughly after handling, remove contaminated clothing and wash before reuse
Appearance: Pale yellow to brown liquid or solid at room temperature
Odor: Characteristic unpleasant amine odor
pH: Not available (not soluble in water)
Melting Point: 23-27°C
Boiling Point: 240–243°C
Flash Point: 110°C (closed cup)
Evaporation Rate: Not available
Upper/Lower Flammability Limits: Not determined
Vapor Pressure: 0.18 mmHg at 25°C
Vapor Density: 5.95 (air = 1)
Solubility: Slightly soluble in water, soluble in benzene, ether and alcohol
Specific Gravity: 1.6 (water = 1)
Partition Coefficient (n-octanol/water): Not determined
Auto-ignition Temperature: 535°C
Decomposition Temperature: Not specified
Chemical Stability: Stable under recommended storage conditions, avoid exposure to air and moisture for long periods
Possibility of Hazardous Reactions: Reacts with strong oxidizing agents, possible explosion hazard from dust-air mixtures
Conditions to Avoid: Heat, flames, sparks, incompatible materials
Incompatible Materials: Strong oxidizing agents, acids, acid chlorides, acid anhydrides
Hazardous Decomposition Products: Nitrogen oxides, hydrogen bromide, carbon monoxide, carbon dioxide
Acute Toxicity (Oral LD50, rat): Approximately 345 mg/kg
Skin Irritation: Causes irritation, prolonged or repeated contact increases risk
Eye Irritation: Causes serious eye irritation, may damage corneal tissue
Inhalation Toxicity: Harmful if inhaled, repeated exposure may irritate respiratory tract
Chronic Effects: Prolonged exposure may affect liver, kidneys, central nervous system, may cause methemoglobinemia
Carcinogenicity: Not listed by IARC, NTP, or OSHA as carcinogen
Other Information: May cause sensitization by skin contact in some individuals, no comprehensive long-term toxicity reports available
Ecotoxicity: Highly toxic to aquatic life, may cause long-term adverse effects in aquatic environments
Persistence and Degradability: Expected to be persistent based on structure, biodegradation not rapid
Bioaccumulation: Potential to bioaccumulate in aquatic organisms
Mobility in Soil: Low mobility due to partial water solubility
Other Hazardous Effects: Do not allow release to waterways or soil
Waste Treatment Methods: Must be handled as hazardous waste, incineration in an approved facility is preferred
Container Disposal: Rinse containers thoroughly before disposal, follow regulations for chemical residues
Environmental Precautions: Prevent entry into sewers, surface waters, or soil
Regulatory Compliance: Dispose in accordance with local, state, and federal requirements
UN Number: 2810
UN Proper Shipping Name: Toxic liquids, organic, n.o.s. (contains 2-Bromoaniline)
Transport Hazard Class(es): 6.1 (Toxic substances)
Packing Group: III
Marine Pollutant: Yes
Special Precautions: Ensure secure packaging, appropriate labeling, documentation reflecting toxicity and environmental risk
Regulatory Transport Label: Toxic, marine pollutant
TSCA Status: Listed on the US Toxic Substances Control Act inventory
REACH Status: Subject to registration in European Union, check supplier for particulars
SARA Title III: Section 311/312 hazard categories: Acute Health Hazard, Chronic Health Hazard
California Proposition 65: Not listed
Canadian DSL/NDSL List: Appears on DSL
Other Relevant Regulations: Subject to workplace safety and chemical hygiene rules, local authorities may have stricter guidelines
