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Material Safety Data Sheet for 1,2-Ethylenediamine

Identification

Product Name: 1,2-Ethylenediamine
Chemical Formula: C2H8N2
Synonyms: Ethylenediamine, EDA
CAS Number: 107-15-3
Recommended Use: Industrial and laboratory chemical, chelating agent, polymerization accelerator, fuel additive
Manufacturer: [Company contact information, including emergency phone numbers]
Product Description: A colorless to yellow, hygroscopic liquid with an ammonia-like odor; completely soluble in water and miscible with many organic solvents

Hazard Identification

Physical State: Liquid
Hazard Classifications: Flammable liquid (Category 3), Acute toxicity by inhalation (Category 3), Acute toxicity by dermal (Category 4), Skin irritation (Category 1), Eye damage (Category 1), Sensitizer (Category 1)
Signal Word: Danger
Hazard Statements: Flammable liquid and vapor. Harmful if swallowed or inhaled. Causes severe skin burns and eye damage. May cause respiratory irritation and allergic skin reaction.
Precautionary Statements: Keep away from heat, sparks, and open flame. Wear protective gloves, clothing, and eye/face protection. Use only outdoors or in well-ventilated areas. Avoid breathing vapors or mist. Wash hands thoroughly after handling.

Composition / Information on Ingredients

Chemical Name: 1,2-Ethylenediamine
Concentration: 99-100%
CAS Number: 107-15-3
Impurities/Additives: Minor water content (<1%), trace amines

First Aid Measures

Inhalation: Move exposed person to fresh air. If breathing has stopped, perform artificial respiration. Seek immediate medical attention.
Skin Contact: Remove contaminated clothing. Wash skin thoroughly with large amounts of water for at least 15 minutes. Get medical care. Wash clothes before reuse.
Eye Contact: Rinse eyes immediately with plenty of water, lifting upper and lower eyelids occasionally. Seek prompt medical care.
Ingestion: Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Obtain medical help immediately.
Acute Symptoms: Burning sensation, coughing, wheezing, headache, nausea
Delayed Effects: Blistering, corneal injury, severe respiratory tract irritation

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, alcohol-resistant foam, dry chemical, carbon dioxide
Specific Hazards: Vapors may form explosive mixtures with air. Heating can cause expansion or decomposition leading to violent rupture of containers.
Protective Equipment: Firefighters should use self-contained breathing apparatus and full protective gear.
Special Procedures: Fight fire from upwind. Cool containers with flooding quantities of water until well after fire is out. Avoid inhalation of toxic fumes.
Hazardous Combustion Products: Nitrogen oxides, ammonia, carbon monoxide, carbon dioxide

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel. Provide adequate ventilation. Avoid breathing vapors and avoid contact with eyes, skin, and clothing. Eliminate ignition sources.
Environmental Precautions: Prevent spillage from entering drains, waterways, or soil. Alert authorities if product has caused environmental contamination.
Containment and Cleanup: Absorb with inert material (sand, vermiculite). Sweep up and place in suitable container for disposal. Ventilate area and wash spill site after material pickup.

Handling and Storage

Safe Handling: Handle with care. Use only in locations with proper ventilation. Avoid all contact with skin and eyes. Do not breathe vapor or mist.
Storage Requirements: Store in tightly closed containers in a cool, dry, well-ventilated place, away from sources of ignition, oxidizers, acids and moisture. Keep container upright and away from sunlight. Use explosion-proof electrical equipment.
Incompatible Materials: Strong oxidizers, acids, copper, brass, zinc, halogenated compounds
Transfer Precautions: Employ grounding and bonding to prevent static discharge.

Exposure Controls and Personal Protection

Occupational Exposure Limits: ACGIH TLV: 10 ppm TWA (skin), OSHA PEL: 10 ppm TWA (25 mg/m³)
Engineering Controls: Mechanical ventilation, fume hood in laboratory settings, local exhaust
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), flame-retardant lab coat and pants, chemical splash goggles, face shield, respirator (NIOSH-approved if needed for vapor)
Hygiene: Wash thoroughly after handling; do not eat, drink, or smoke in work areas.

Physical and Chemical Properties

Appearance: Colorless to pale yellow liquid
Odor: Ammonia-like, pungent
Odor Threshold: 1 ppm
Melting/Freezing Point: 8.5 °C
Boiling Point: 116 °C
Flash Point: 38 °C (closed cup)
Evaporation Rate: Not readily available
Flammability: Flammable liquid
Vapor Pressure: 11 mmHg @ 20°C
Vapor Density: 2.2 (air = 1)
Solubility: Completely soluble in water
Partition Coefficient (log Kow): -1.23
Auto-ignition Temperature: 385 °C
Decomposition Temperature: Not established
Viscosity: 1.2 mPa·s at 20°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: Reacts exothermically with acids, oxidizers, acid chlorides
Hazardous Reactions: May react violently with oxidizing agents and carbonyl compounds
Decomposition Products: Nitrogen oxides, ammonia, carbon monoxide
Polymerization: Will not occur under standard conditions

Toxicological Information

Routes of Exposure: Skin and eye contact, inhalation, ingestion
Acute Toxicity: LD50 (oral, rat): 968 mg/kg; LD50 (dermal, rabbit): 730 mg/kg; LC50 (inhalation, rat): 38 ppm (4h)
Effects of Overexposure: Severe irritation and burns to skin, eyes, and respiratory tract. Vapors may cause drowsiness, headache, nausea, breathing difficulty.
Carcinogenicity: No evidence of carcinogenicity based on available data
Mutagenicity: Not classified as mutagenic
Reproductive Toxicity: Not classified as reprotoxic
Other Effects: Sensitizer of skin and respiratory tract

Ecological Information

Ecotoxicity: Highly toxic to aquatic life. EC50 (Daphnia magna): 4.3 mg/L (48h). NOEC (algae): 2.5 mg/L (72h)
Environmental Fate: Readily biodegradable in the environment. Risk of bioaccumulation low due to log Kow. Volatile and may enter atmosphere.
Mobility in Soil: High mobility. May contaminate groundwater if released in large quantities.
Persistence and Degradability: Degrades by hydrolysis and microbial activity.
Other Environmental Risks: Releases of large quantities may cause fish kills and affect water quality.

Disposal Considerations

Disposal Methods: Dispose through a licensed hazardous waste disposal contractor. Incineration in approved facility preferred.
Container Disposal: Triple rinse with water and destroy container safely as hazardous waste.
Precautions: Follow all local, state, and federal regulations regarding disposal.
Avoid: Release into environment, landfill, and sewage systems.
Contaminated Packaging: Treat packaging as hazardous material.

Transport Information

UN Number: UN 1604
Proper Shipping Name: Ethylenediamine, aqueous solution
Transport Hazard Class: 8 (Corrosive), 3 (Flammable liquid)
Packing Group: I (high danger)
Hazard Labels: Corrosive, Flammable liquid
Special Provisions: Use corrosion-resistant, tightly sealed containers. Transport in compliance with local laws.
Environmental Hazards: Marine pollutant; take steps to avoid spillage into marine systems

Regulatory Information

TSCA Status: Listed on Toxic Substances Control Act inventory
OSHA: Regulated hazardous substance
SARA Title III Sections 302, 304, 313: Subject to reporting
RCRA Status: Classified as hazardous waste
EU Regulations: Classified under CLP Regulation; requires hazard warning labels
Canadian WHMIS: Classified D1B (toxic), D2B (irritant), B2 (flammable)
Other National Inventories: Listed on AICS, IECSC, Japanese ENCS, Korean ECL
Restriction Notices: Use strictly controlled for certain consumer and professional applications