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Understanding 1,1-Bis(Tert-Butylperoxy)Cyclohexane: More Than Just a Chemical Name

The Road So Far: History, Innovation and the Role of Peroxides

Looking at the bigger picture, the story of 1,1-Bis(Tert-Butylperoxy)Cyclohexane ties closely to the evolution of organic peroxides in the world of chemistry and industry. Organic peroxides, and this compound in particular, didn’t show up overnight. They grew out of a search for better ways to start and control polymerization reactions, which played a huge part in the explosion of plastics in the twentieth century. Laboratories and industrial chemists spent decades tinkering with the structure of peroxides, trying to find the right tool for the right job. As demands shifted—especially for materials with fine-tuned properties—this led to new generations of peroxides that were safer, more stable, and easier to handle. Early peroxide chemistry was a risky game. Explosions and decomposition incidents forced researchers to put safety front and center. That background paved the way for adding diluents and other design tweaks, which reduced the volatility and made transportation and storage far less hazardous.

Physical and Chemical Reality: More Than Just Numbers

Peeking inside a bottle of 1,1-Bis(Tert-Butylperoxy)Cyclohexane, you’ll find a clear or pale liquid. Its smell tends to hit with a slightly sharp, almost medicine-like edge. It doesn’t mix well with water, but finds friends in organic solvents like toluene and certain alcohols. The boiling point comes in above 200°C, but that’s not the important number when it comes to working with peroxides; people keep their eyes on the temperature where it starts to break down and lose its punch, which for this compound lands well below its boiling point. That’s a crucial line—cross it, and you trade reactivity for potential danger. Stability improves with a diluent, often topping 25 percent. This solution tamps down energetic decomposition, giving operators a little more peace of mind.

The Technical Side: Labeling, Handling, and Standards That Matter

Digging into standard practices, the specifics really count. Technical sheets mark out concentration ranges—no more than 27 percent of the active ingredient, and a type A diluent at or above 25 percent. Labels must shout clearly about risks and safe use, since a mistake isn’t just academic; it can mean fires, injury, or worse. Setting up a workspace takes more than just fume hoods and gloves: concrete rules about storage temperature, incompatible substances, and daily inspections anchor the attitude of caution. Over my own time working in labs, I saw how these rules hammered home lessons that kept people safe, even when pressure was high. That said, standards keep tightening, as regulatory groups dig through new research and fire incident logs and try to learn from every mishap. None of these protocols mean much unless companies and workers actually take them seriously, with ongoing safety training and daily discipline baked into routine.

Making It Happen: Preparation and Modification

On the synthetic front, building this molecule means walking the line between efficiency and safety. Chemists usually start with cyclohexanone or cyclohexanol, add tert-butyl hydroperoxide, and lean on acid or base catalysts. Each choice along the route can shift yields, purity, and the energy profile of the mix. The goal isn’t just a higher yield, though—a safer, less exothermic process often ranks just as high. Similar thinking goes into modifications: tweaks in the structure, or exchanging one diluent for another, can tailor the properties for specific downstream uses or regulatory needs, especially where temperature stability or reactivity makes a difference in manufacturing.

Chemical Reactions and the World Beyond the Bottle

The true action starts when 1,1-Bis(Tert-Butylperoxy)Cyclohexane enters a polymerization reaction. Here, it kicks off the chain that ties tiny molecules into much bigger ones—an essential step in making plastic resins, elastomers, and even some specialty adhesives. Why use this peroxide over something else? It brings a unique profile: it activates at higher temperatures and works steadily, helping avoid runaway reactions, which is a recurring headache in plastics production. It also slots neatly into processes that need high heat, and where other peroxides might fizzle out or break down too soon. Some modifiers and side reactions can extend its shelf life, or slow its rate of breakdown so it fits specialized manufacturing needs.

Names and Labels: Navigating Chemical Synonyms

This compound hides behind a number of names, which can trip up even seasoned chemists. In different catalogs you’ll see listings like “Peroxyketal,” “Diperoxide,” or longer systematic names based on IUPAC conventions. These synonyms lead to confusion, especially among folks jumping between product sheets and academic literature. That tangle of names often slows down practical work, causing missed shipments or regulatory delays if the paperwork doesn’t line up. Over time, industry groups and standards bodies worked to nail down clearer naming conventions, but the old aliases crop up in surprising places, especially in international trade.

Working Safely: The Standards and Real-World Challenges

If you’ve worked in an industrial or research setting, you’ll know that safety around peroxides isn’t just about reading the right section of the safety data sheet. For this compound, exposure means wearing more than the usual lab coat. Goggles, thick nitrile gloves, and extra shields where pressure vessels come into play form the baseline. Training counts, but so does respect for the small stuff—logbooks, double-checks before doing even minor transfers, and treating even trace spills as major events. Regulatory rules set legal baselines for flammable materials, storage temperatures, and reporting thresholds. Occupational standards still change in response to new data about chronic exposure and acute incidents. Being lax, or assuming nothing has changed, creates the kind of opening that turns small errors into disasters.

Where It All Ends Up: Applications That Drive Demand

Demand for 1,1-Bis(Tert-Butylperoxy)Cyclohexane lives mostly in plastics and rubber, especially where temperature control and exact product outcomes matter. Manufacturing sectors use it to produce wide-ranging materials—think tennis shoes, auto parts, electrical insulation, and toughened plastics. Certain adhesives and cross-linked foams also depend on the unique reactivity that this peroxide brings. These uses matter, since the materials go into goods that touch millions of lives every day. That connection between the lab bench and the products in shops often gets missed, but it’s real: getting the chemistry right keeps costs down, raises quality, and boosts confidence in finished materials.

Research, Development, and Unlocking Safer Chemistry

Over the last decade, R&D teams dug into questions about greener alternatives, thermal stability, and the search for peroxides with fewer safety headaches. Research published in journals focused keenly on finding ways to curb accidental decomposition and dial in the activation temperature to tighter tolerances. The bulk of modern innovation comes from process tweaks: new catalysts, purer starting materials, smarter diluents, and continuous flow reactors all play a role. Some labs also circle back to core toxicity questions, building better animal models or more precise in vitro techniques so companies and regulators get a clear picture on chronic and acute hazards. In the background sit industry groups, academic researchers, and health agencies, arguing over the best methods for testing, reporting, and managing risks. It’s a tug-of-war between innovation and safety, and neither side has shown signs of backing off.

Toxicity, Exposure, and Gaps in the Safety Net

On toxicity, data from published studies point to moderate hazard profiles. Skin and eye irritation can show up fast on direct contact, and inhaling vapors in closed spaces brings respiratory risks. Chronic exposure questions take more digging—a lot depends on workplace practices, local rules, and the strength of reporting. Strict exposure thresholds exist in many regions, but enforcement and monitoring vary widely. The gap between lab risk and field reality often shows up in factories with older systems or looser supervision. State-of-the-art monitoring tools, such as gas sensors and wearable detectors, help spot vapor leaks early, but plenty of work remains to standardize best practices in smaller plants. Toxicologists still push for expanded long-term exposure testing, since high production volumes mean millions could get exposed over the years, even if indirect.

Outlook: Where Might We Go From Here?

1,1-Bis(Tert-Butylperoxy)Cyclohexane may not become a household name, but its future depends on ongoing innovation. Market shifts toward high-performance plastics could grow demand for safer, more effective peroxides. Regulators worldwide get stricter about transportation, storage, and environmental release, nudging the industry to modernize. Research into more stable or biodegradable alternatives seems likely to speed up, especially as sustainability claims become critical for big buyers. Education and cross-border cooperation around safety and best practices could shrink the gap between data-rich labs and risk-prone production floors. Safer work environments, better products, and clearer communication with all stakeholders should drive how this compound gets handled in the coming years.




What are the main uses of 1,1-Bis(Tert-Butylperoxy)Cyclohexane [Content ≤27%, Type A Diluent ≥25%]?

Powering Polymer Chains

Manufacturers face tough choices in the search for dependable initiators in the plastics and rubber industry. Some chemicals just outshine others for specific jobs, and 1,1-Bis(Tert-Butylperoxy)Cyclohexane stands out as a workhorse in bringing polymers to life. Its main job is to jumpstart the transformation of raw chemicals into the long, tough plastics and rubbers in demand today.

This compound’s detailed profile, with a content of up to 27% and an added Type A diluent at no less than 25%, makes it safe to handle and more controllable during storage and shipping. Safety regulations take center stage in any industrial application. Using a diluted product instead of the full-strength material helps manufacturers sidestep many headaches tied to transportation and on-site handling.

Driving the Crosslinking Process

Crosslinking sits right at the core of turning rubber and plastics from mere chains of repeating units into sturdy, useable materials. As a peroxide, 1,1-Bis(Tert-Butylperoxy)Cyclohexane shines in curing and crosslinking tasks. Its major calling arrives in polyethylene and ethylene propylene diene monomer (EPDM) rubber production. Crosslinking bridges the molecular chains, turning basic plastic sheets into tough pressure pipes, electrical insulation, and car parts. Every time I hold a flexible cable or encounter a sink drain made from high-performance plastic, I remember the invisible chemistry behind the scenes. This initiator ensures products keep their shape, resist temperature swings, and last far longer than their uncrosslinked kin.

Toughness for Industry

Not every initiator can deliver the slow, controlled curing needed in thick parts or weather-resistant coatings. High temperature stability of 1,1-Bis(Tert-Butylperoxy)Cyclohexane opens the door to production environments where other chemicals fall short. Storage stability matters for processors handling hundreds of liters at a time—the less risk of decomposition, the safer the workplace. I’ve seen how processors lean on this chemical in hot-cure rubber, running production lines smoothly from gaskets to footwear. There’s no one-size-fits-all with initiators, but plants keep returning to safer, easy-to-blend options with predictable performance.

Fact-Based Industry Acceptance

Organizations like OSHA and the European Chemicals Agency press for transparency and robust risk management. A diluted form represents a careful balance between strength and safety. Manufacturers have to report detailed composition and ensure workers know proper storage and personal protection. Several reports highlight this chemical’s reliability and track record; less hazard, with reliable crosslinking. More than ever, end-users don’t want hidden risks baked into their consumer goods.

Looking Ahead: Smarter, Safer Chemistry

Companies keep searching for improvements—less energy spent on processing, fewer emissions, and lower waste. Some research groups experiment with bio-based peroxides or lower-toxicity mixes. Still, for now, 1,1-Bis(Tert-Butylperoxy)Cyclohexane continues to be a dependable force. People in the know pay attention to regulatory changes and technical bulletins, always adjusting plants and safety systems around new data.

This initiator will keep supporting key sectors that rely on rugged rubbers and plastics. As we lean into demanding applications—medicine, clean energy, critical infrastructure—dependable crosslinking tools remain essential. I keep an eye on these chemical workhorses, knowing that small tweaks in formulation ripple out into real-world goods people count on every day.

What are the recommended storage conditions for this product?

Protecting What You Paid For

Every time we spend money on a product, we expect it to do its job. Storage plays a bigger role in this than most people realize. Store something the wrong way and the promises on the label start to slip away. Vitamins lose their strength, food grows stale, adhesives crust over before their time. No one likes wasting hard-earned cash on something that doesn’t perform as expected.

Understanding the Enemies: Heat, Moisture, Light, and Air

Ask any pharmacist, chef, or handyman and you’ll hear the same names: heat, moisture, light, and air. These are the main things that wear products down too soon. Heat speeds up chemical reactions, which can break down ingredients. This happens with everything from medication to electronics—leave a bottle of cough syrup in a hot car, and it may separate or lose its punch. Keep batteries in a sweaty garage, and corrosion shows up faster than you’d think.

Moisture creates its own trouble. Powdered goods absorb water and harden up. Electronics and metal parts pick up rust unseen until they fail. Foods attract mold, even in the short term, if there’s humidity. If you’re keeping flour, spices, or supplements in the kitchen, a dry cupboard that limits exposure to steam beats a spot near the stove or sink.

Light, especially sunlight, speeds up breakdown in many ingredients. Most pharmaceutical bottles use amber-colored glass for a reason—it blocks UV rays. Not every container gives such protection, so sticking sensitive items in a shaded spot keeps them working longer.

Temperature: More Than a Number

We see a lot of “store in a cool, dry place” advice. With medicine or perishable food, the stakes get higher. Insulin goes bad if it sits above 30°C for very long, antibiotics become less effective, and protein shakes spoil. Those guidelines aren’t just legal disclaimers—they keep people safe.

I learned the hard way with a bottle of wood glue left in a freezing shed over winter. In spring, it poured out like cottage cheese, nowhere near smooth. If something’s meant for refrigeration, a regular fridge (between 2°C and 8°C) usually works. For freezing, stick close to -18°C, since anything warmer lets ice crystals form and break down texture or structure.

Packaging: Don’t Assume It’s Airtight

I used to think product packaging would handle all the heavy lifting, but most containers only slow down spoilage. Opening a package speeds up the decline. Coffee grounds, for example, start losing their aroma within days if kept in a loose bag. A tightly sealed jar or vacuum-packed bag avoids that problem. The same goes for paint, oils, and supplements.

Solutions Anyone Can Use

People don’t need to reinvent storage—it comes down to basics. For almost everything: store away from heat and light, keep containers shut tightly, and use dry shelves or cupboards. In some cases, invest in materials like silica gel packs or food-safe air-tight containers. Check labels often and don’t ignore advice specific to a product, especially for safety-critical goods like medicine or chemicals.

Following these rules means fewer ruined products, safer households, and better value for your money. Consistent storage habits, backed by science and real-world experience, help everyone get the most from their purchases.

Is 1,1-Bis(Tert-Butylperoxy)Cyclohexane hazardous, and what safety precautions should be taken?

What Makes This Peroxide Important—and Risky

I’ve handled chemicals ranging from simple solvents to hard-hitting organic peroxides, and my experience tells me to take each one seriously. 1,1-Bis(Tert-Butylperoxy)Cyclohexane isn’t just another industrial chemical. This one carries the reputation of being a strong oxidizing agent, with a knack for spontaneous decomposition. That can spell trouble if it’s not handled right.

Let’s break it down. Chemically, this compound releases lots of energy if nudged in the wrong way—heat, shock, friction, or even massing it up in high concentrations. The result can be fires or explosions, not to mention the risk of breathing in peroxide decomposing byproducts. Workers in manufacturing, labs, or transport learn quickly that this kind of molecule won’t forgive mistakes.

Health and Environmental Risks

The health risks come from contact and inhalation. The chemical irritates skin, eyes, and mucous membranes. Accidental splashes or inhaled vapors lead to burning eyes, sore throats, or itchy rashes. In one incident I followed, a technician ignored a small drip on their glove. Within minutes, red, irritated skin cropped up. If that exposure had reached the eyes, forget trying to finish the day—emergency eyewash and a trip to the doctor would be in order.

Environmental hazards matter, too. Spills threaten water sources and soil organisms. Once peroxide leaks into a drain or soil, it breaks down but sometimes leaves behind harmful breakdown products that influence plant and animal health. These chemicals don’t evaporate safely into thin air; they travel and linger.

Safety Measures That Work

Dealing with this chemical starts well before it leaves a bottle. Sounds obvious, but I’ve seen rooms poorly ventilated or storage cabinets crammed too tightly. The best defense is good housekeeping—store this peroxide in cool, dry, strictly ventilated areas, well away from sun, sparks, and incompatible materials. Lock up acids, metals, and strong reducing agents elsewhere.

Personal protective equipment must not just sit on shelves. Chemical-resistant gloves, snug goggles, and lab coats make the difference between an ordinary workday and a trip to the emergency room. I once wore thin household gloves by mistake—chemical burned right through and taught me to stick with the recommended nitrile or neoprene. Respiratory protection might sound excessive, but any hint of vapor buildup makes air-purifying respirators worth the trouble.

Spill response and emergency plans need clear steps and frequent practice. Emergency showers and eyewash stations always stay within reach. The team stays sharp through regular safety drills and monthly inspections. I’ve seen accidents get smaller just because folks lacked confusion about who to call or what to grab.

Transport brings another layer. Regulations demand specific labeling, temperature control, and licensed carriers. Skipping paperwork or trying to fudge the rules only invites fines or, worse, an accident en route. Certification and up-to-date safety data sheets should be checked and verified every time—the rules grew out of real disasters, not somebody’s guesswork.

Building a Safer Culture

People forget how often human error slips in. Distraction, shortcuts, or overconfidence breaks down even the neatest protocols. Open communication, clear job roles, and empowering everyone to stop work if they spot a hazard, keep teams safe. Education can’t be a quick slideshow, either. Hands-on demonstrations, real-life case studies, and feedback loops keep everyone engaged and safe rather than just ticking boxes.

Staying on top of chemical hazards isn’t about fearing every drum or beaker. It’s about respect—respect for the science, the risks, and each other’s well-being. The more your team builds a strong safety foundation, the fewer horror stories you hear, and the more time you spend learning and producing without worry.

How should spills or accidental exposure to this product be handled?

Why Safe Cleanup Matters

Most people heading into work at a lab, plant, or even the janitorial closet don't expect to deal with spills or chemical splashes. Those moments catch everyone off guard. I remember early in my career, mopping up a small solvent spill on a busy production floor. My heart pounded faster than logic could keep up—so I get how easy it is to freeze up or reach for shortcuts. If you know the drill ahead of time, you protect your health, your coworkers, and sometimes the very air everyone is breathing.

Immediate Actions Count

A splash on the skin or a lungful of fumes doesn’t give you time to browse the safety manual. Quick thinking makes all the difference. Putting on protective gloves and goggles helps you stay safe from skin burns or eye injuries right from the start. If you spill something hazardous, stop others from coming near, turn off surrounding equipment, and make your work area safer. I once learned the hard way that ignoring these steps can lead to expensive business interruptions or worse, injuries nobody recovers from.

PPE: No One Looks Cool in Goggles—But They Work

I’ve seen a lot of smart people skip eye protection because they felt silly or thought they knew what they were doing. It’s always a mistake. Even minor irritants can send someone to the hospital if they get into the eyes or lungs. Wearing the right respirator or gloves can save you from burns, asthma, or lifelong sensitivity. In my own experience, disposable nitrile gloves beat latex every time for chemical jobs, and splash-proof goggles win over prescription glasses if you love your eyesight.

Containment and Cleanup

Nobody wants a small spill to become an environmental headache or a safety issue for the whole building. Spilled powder or liquid spreads fast, so speed matters. Use absorbent pads or special spill kits kept in plain sight. Granular absorbents work for oils; neutralizers work for acids or bases. Scoop up the mess and get it into a sealed container. If you don’t know if something is safe to touch or inhale, you’re better off calling the internal emergency contact or the local fire department.

Exposure: People Come First

Product safety data tells you what to do, but not everyone has read those sheets cover to cover. If anyone gets something toxic on their skin or eyes, use an emergency shower or eyewash station right away. I’ve guided folks through one of those before: it’s awkward, time-consuming, and humbling. Medical checks can turn a scary incident into a regular day at the clinic instead of a trip to the ER.

Prevention Beats Emergency

Training makes a real difference. Annual drills, visible instructions, and up-to-date labels cut down mistakes better than any policy change. No trick beats regular practice, whether you’re cleaning up bleach at home or breaking down a spill at an industrial site. Leadership shows its true colors by investing in unglamorous basics like spill kits, clear signage, and ongoing education. If budget ever feels tight, remember: one big accident can cost a company or a family more than years of preparation ever will.

What is the shelf life and stability of the product under normal conditions?

Daily Life Relies on Confidence in Products

Every time I pick up a box of crackers or a bottle of pain relief, I expect that what’s inside will work as intended. That trust comes from shelf life and stability. These two words sound simple, but a huge amount of work and science finishes behind the scenes to make sure a product is safe and effective from the day it ships until the day I use the last drop or bite the last piece.

Shelf Life Isn't Guesswork

Companies often set a “use by” or expiration date. That date isn’t a rough estimate. Chemists, food scientists, and pharmacists test products in all sorts of conditions—heat, moisture, sunlight. They watch for color changes, loss of potency, or other warning signs. For example, aspirin slowly breaks down into acetic acid over time, which makes it smell like vinegar. If that process speeds up in a hot, humid storage room, no one wants customers getting less relief than promised. So, the right shelf life date protects people from using a product that’s grown stale or lost its punch.

Understanding Normal Conditions

The concept of “normal” varies by product. For food, most people store it in the kitchen, maybe a pantry at room temperature. Medicine ends up in bathroom cabinets or bedside tables. These locations have their own quirks. Sometimes, a product might survive weeks in a steamy bathroom, sometimes not. Scientists know this, and that’s why they test stability under a range of conditions. Keeping a product stable outside a perfect laboratory gives confidence it will deliver the expected results in the real world.

Health and Safety Come First

I once bought a can of soup on sale, not noticing it was a week past its date. Odd smell, odd taste—straight into the trash. Food-borne illness is serious business. According to the CDC, every year 48 million people in the US get sick from contaminated food. Shelf life decisions aren’t red tape; they keep food and medicines from harming families. Stability testing for drugs saves lives. For instance, insulin that degrades in heat can put people with diabetes in danger. So, reliable shelf life information means fewer health scares.

Waste Ties into Shelf Life

Short shelf life products go bad fast, leading to a lot of waste. The Food and Agriculture Organization reports that about a third of all food produced in the world gets lost or wasted. Some of this comes from spoilage. Smarter packaging, better chemical formulations, and honest labeling help reduce unnecessary waste. People also need clear storage instructions. A yogurt that claims it lasts for weeks but spoils in three days if left unrefrigerated isn’t doing anyone a favor. Transparent labeling, powered by real science, makes it easier for everyone to make better choices.

Responsible Solutions and Accountability

Brands can help customers by sharing exactly how they’ve determined shelf life—laying out test conditions, storage advice, and even offering support if something goes wrong. Investing in improved packaging or tamper-proof seals shows care for quality and longevity. As consumers, asking questions or reporting surprises when products seem off helps keep companies accountable. Regulators and watchdog groups play a part by setting minimum standards for testing and labeling, but it’s up to producers to rise above the bare minimum.

Shelf life and stability may look technical, but they go straight to the heart of trust between people and the brands they support. Honest testing and open communication help everyone stay safe, save money, and waste less.

1,1-Bis(Tert-Butylperoxy)Cyclohexane [Content ≤27%, Type A Diluent ≥25%]
Names
Preferred IUPAC name 1,1-Bis(tert-butylperoxy)cyclohexane
Other names Peroxide, 1,1-bis(tert-butylperoxy)cyclohexane, <27%, type A diluent
1,1-Bis(tert-butylperoxy)cyclohexane (containing not more than 27% as a solution, mixture or in its diluent, type A)
Pronunciation /wʌn wʌn bɪs tɜrt ˌbɜːrksɪ ˌsaɪkloʊˈhɛksein/
Identifiers
CAS Number [3006-82-4]
Beilstein Reference 1201118
ChEBI CHEBI:30081
ChEMBL CHEMBL3722421
ChemSpider 85751
DrugBank DB16574
ECHA InfoCard 03b588125ca7-45d5-9c98-06ac806c10ad
EC Number 217-570-8
Gmelin Reference 394172
KEGG C19105
MeSH D006759
PubChem CID 10129799
RTECS number SY9475000
UNII UNII-8IA74Z3H5A
UN number UN3105
Properties
Chemical formula C16H32O4
Molar mass 338.5 g/mol
Appearance Colorless transparent liquid
Odor Slightly pungent
Density 0.93 g/mL at 25 °C
Solubility in water insoluble
log P 6.18
Vapor pressure <0.01 kPa (20°C)
Basicity (pKb) 1.2
Magnetic susceptibility (χ) -7.3e-6 cm³/mol
Refractive index (nD) 1.4500
Viscosity 9.6 mPa·s at 20°C
Dipole moment 1.94 D
Thermochemistry
Std molar entropy (S⦵298) 561.932 J/mol·K
Std enthalpy of formation (ΔfH⦵298) -471.7 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -1398 kJ/mol
Hazards
GHS labelling GHS02, GHS07, GHS08
Pictograms GHS02, GHS05, GHS07, GHS08
Signal word DANGER
Hazard statements H242, H302, H315, H317, H319, H335, H411
Precautionary statements P210, P220, P234, P235, P240, P241, P242, P243, P261, P264, P270, P271, P273, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P308+P313, P312, P321, P330, P337+P313, P370+P378, P403+P235, P410, P411+P235, P420, P501
NFPA 704 (fire diamond) 2-4-4-OX
Flash point 80°C
Autoignition temperature 220°C (428°F)
Lethal dose or concentration LD₅₀ Oral Rat: >5000 mg/kg
LD50 (median dose) >300<500 mg/kg
NIOSH NA9019
PEL (Permissible) Not established
REL (Recommended) 5 mg/m³